Synthesis and characterization of novel phosphate glass matrix nanocomposites containing polyhedral oligomeric silsesquioxane with improved properties

Kim, Kyoungtae; Alam, Todd M.; Lichtenhan, Joseph D.; Otaigbe, Joshua U.

doi:10.1016/j.jnoncrysol.2017.03.007

Title: Synthesis and characterization of novel phosphate glass matrix nanocomposites containing polyhedral oligomeric silsesquioxane with improved properties

Journal Article · Sat Mar 18 00:00:00 EDT 2017 · Journal of Non-Crystalline Solids

DOI:https://doi.org/10.1016/j.jnoncrysol.2017.03.007· OSTI ID:1497646

Kim, Kyoungtae ^[1]; Alam, Todd M. ^[2]; Lichtenhan, Joseph D. ^[3]; Otaigbe, Joshua U. ^[1]

Univ. of Southern Mississippi, Hattiesburg, MS (United States). School of Polymers and High Performance Materials
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Dept. of Organic Materials Science
Hybrid Plastics, Hattiesburg, MS (United States)

The preparation and characterization of novel tin fluorophosphate glass (Pglass) matrix nanocomposite materials containing nanoscale trisilanolphenyl polyhedral oligomeric silsesquioxane (POSS) prepared via classical glass synthesis was investigated here to accelerate efforts to develop novel hybrid Pglass/POSS nanocomposites with enhanced benefits in suitable diverse applications. The glass transition temperatures (T_g) of the obtained nanocomposites ranged from 121.6° to 147.6 °C to an extent that depends on the nano-POSS concentrations (≤ 10 wt% POSS) in the nanocomposites. The obtained scanning electron microscopy with energy-dispersive x-ray spectroscopy and atomic force microscopy results confirmed the homogeneous molecular level dispersion of the POSS cages in the continuous Pglass matrix of the nanocomposite. Chemical reaction (or bonding) between the constituents of the nanocomposites was confirmed by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and nuclear magnetic resonance spectroscopy. The rheological (storage and loss modulus) and nanomechanical (elastic modulus) properties of the nanocomposites significantly improved with increasing nano-POSS concentrations up to 10 wt% POSS. The molecular dispersion of the POSS and its strong physicochemical interaction with the continuous Pglass matrix can be tailored to satisfy requirements of a number of optomechanical applications where the pure glass is not useable.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Univ. of Southern Mississippi, Hattiesburg, MS (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); National Science Foundation (NSF)

Grant/Contract Number:: AC04-94AL85000; DMR-1360006

OSTI ID:: 1497646

Report Number(s):: SAND2017-1112J; 672223

Journal Information:: Journal of Non-Crystalline Solids, Vol. 463; ISSN 0022-3093

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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References (79)

Review article: Polymer-matrix Nanocomposites, Processing, Manufacturing, and Application: An Overview Hussain, Farzana; Hojjati, Mehdi; Okamoto, Masami Journal of Composite Materials, Vol. 40, Issue 17 https://doi.org/10.1177/0021998306067321	journal	January 2006
Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials Alexandre, Michael; Dubois, Philippe Materials Science and Engineering: R: Reports, Vol. 28, Issue 1-2 https://doi.org/10.1016/S0927-796X(00)00012-7	journal	June 2000
New advances in polymer/layered silicate nanocomposites Schmidt, Daniel; Shah, Deepak; Giannelis, Emmanuel P. Current Opinion in Solid State and Materials Science, Vol. 6, Issue 3 https://doi.org/10.1016/S1359-0286(02)00049-9	journal	June 2002
Polymer/layered silicate nanocomposites: a review from preparation to processing Sinha Ray, Suprakas; Okamoto, Masami Progress in Polymer Science, Vol. 28, Issue 11 https://doi.org/10.1016/j.progpolymsci.2003.08.002	journal	November 2003
Influence of particle properties on the viscosity of polymer–alumina composites Hanemann, T. Ceramics International, Vol. 34, Issue 8 https://doi.org/10.1016/j.ceramint.2007.08.007	journal	December 2008
Fibers from polypropylene/nano carbon fiber composites Kumar, Satish; Doshi, Harit; Srinivasarao, Mohan Polymer, Vol. 43, Issue 5 https://doi.org/10.1016/S0032-3861(01)00744-3	journal	March 2002
Carbon nanotube polymer composites Andrews, R.; Weisenberger, M. C. Current Opinion in Solid State and Materials Science, Vol. 8, Issue 1 https://doi.org/10.1016/j.cossms.2003.10.006	journal	January 2004
Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: A review Ma, Peng-Cheng; Siddiqui, Naveed A.; Marom, Gad Composites Part A: Applied Science and Manufacturing, Vol. 41, Issue 10 https://doi.org/10.1016/j.compositesa.2010.07.003	journal	October 2010
New phosphate glass/polymer hybrids—Current status and future prospects Urman, Kevin; Otaigbe, Joshua U. Progress in Polymer Science, Vol. 32, Issue 12 https://doi.org/10.1016/j.progpolymsci.2007.07.006	journal	December 2007
Structural and electrochemical properties of polyurethanes/polyhedral oligomeric silsesquioxanes (PU/POSS) hybrid coatings on aluminum alloys Lai, Y. S.; Tsai, C. W.; Yang, H. W. Materials Chemistry and Physics, Vol. 117, Issue 1 https://doi.org/10.1016/j.matchemphys.2009.05.006	journal	September 2009
Novel phosphate glass/polyamide 6 hybrids: Miscibility, crystallization kinetics, and mechanical properties Urman, Kevin; Otaigbe, Joshua Journal of Polymer Science Part B: Polymer Physics, Vol. 44, Issue 2 https://doi.org/10.1002/polb.20708	journal	January 2005
Detection of Nanometer-Scale Mixing in Phosphate-Glass/Polyamide-6 Hybrids by ¹ H− ³¹ P NMR Rawal, A.; Urman, K.; Otaigbe, J. U. Chemistry of Materials, Vol. 18, Issue 26 https://doi.org/10.1021/cm0613410	journal	November 2006
Promotion of the γ-phase of polyamide 6 in its nanocomposite with phosphate glass Rawal, A.; Fang, X. -W.; Urman, K. Journal of Polymer Science Part B: Polymer Physics, Vol. 46, Issue 9 https://doi.org/10.1002/polb.21418	journal	January 2008
Rheology of tin fluorophosphate glass/polyamide 12 hybrids in the low concentration regime Urman, Kevin; Schweizer, Thomas; Otaigbe, Joshua U. Journal of Rheology, Vol. 51, Issue 6 https://doi.org/10.1122/1.2789954	journal	November 2007
Development of new sustainable inorganic flame retardant additive system for polyamide 6,6 with improved performance Belyamani, Imane; Otaigbe, Joshua U.; Fielding, William R. Polymer Engineering & Science, Vol. 55, Issue 8 https://doi.org/10.1002/pen.24012	journal	September 2014
Structure and dynamics of phosphate glasses: from ultra- to orthophosphate composition Loong, C. -K.; Suzuya, K.; Price, D. L. Physica B: Condensed Matter, Vol. 241-243 https://doi.org/10.1016/S0921-4526(97)00747-3	journal	December 1997
Review: the structure of simple phosphate glasses Brow, Richard K. Journal of Non-Crystalline Solids, Vol. 263-264 https://doi.org/10.1016/S0022-3093(99)00620-1	journal	March 2000
Ceramic matrix composites containing carbon nanotubes Cho, Johann; Boccaccini, Aldo R.; Shaffer, Milo S. P. Journal of Materials Science, Vol. 44, Issue 8 https://doi.org/10.1007/s10853-009-3262-9	journal	April 2009
Toughening effects quantification in glass matrix composite reinforced by alumina platelets Kotoul, M.; Pokluda, J.; Šandera, P. Acta Materialia, Vol. 56, Issue 12 https://doi.org/10.1016/j.actamat.2008.02.024	journal	July 2008
Assessment of damage induced by thermal shock in SiC- fiber-reinforced borosilicate glass composites Boccaccini, A. R.; Janczak-Rusch, J.; Pearce, D. H. Composites Science and Technology, Vol. 59, Issue 1 https://doi.org/10.1016/S0266-3538(98)00053-0	journal	January 1999
High-strength silicon carbide fibre-reinforced glass-matrix composites Prewo, Karl M.; Brennan, John J. Journal of Materials Science, Vol. 15, Issue 2 https://doi.org/10.1007/BF02396796	journal	February 1980
Mechanical performance and fracture behaviour of glass–matrix composites reinforced with molybdenum particles Cannillo, V.; Leonelli, C.; Manfredini, T. Composites Science and Technology, Vol. 65, Issue 7-8 https://doi.org/10.1016/j.compscitech.2004.12.035	journal	June 2005
Borosilicate glass matrix composites containing multi-wall carbon nanotubes Boccaccini, A. R.; Acevedo, D. R.; Brusatin, G. Journal of the European Ceramic Society, Vol. 25, Issue 9 https://doi.org/10.1016/j.jeurceramsoc.2004.05.015	journal	June 2005
Optically-transparent oxide fibre-reinforced glass matrix composites Desimone, Deborah; Dlouhy, Ivo; Lee, William E. Journal of Non-Crystalline Solids, Vol. 356, Issue 44-49 https://doi.org/10.1016/j.jnoncrysol.2010.05.015	journal	October 2010
Glass–ceramics and composites containing aluminum borate whiskers Lee, H. K.; Zerbetto, S.; Colombo, P. Ceramics International, Vol. 36, Issue 5 https://doi.org/10.1016/j.ceramint.2010.02.039	journal	July 2010
Glass matrix composites from coal flyash and waste glass Boccaccini, Aldo R.; Bücker, Michael; Bossert, Jörg Waste Management, Vol. 17, Issue 1 https://doi.org/10.1016/S0956-053X(97)00035-4	journal	January 1997
Optomechanical glass matrix composites Boccaccini, Aldo R.; Atiq, Shabbar; Helsch, Gundula Composites Science and Technology, Vol. 63, Issue 6 https://doi.org/10.1016/S0266-3538(02)00262-2	journal	May 2003
Sol–gel route to carbon nanotube borosilicate glass composites Thomas, Boris J. C.; Shaffer, Milo S. P.; Boccaccini, Aldo R. Composites Part A: Applied Science and Manufacturing, Vol. 40, Issue 6-7 https://doi.org/10.1016/j.compositesa.2009.04.006	journal	July 2009
Mechanical properties of oxide-fiber reinforced glass matrix composites with BN or SnO2 interfaces Raab, D.; Pfeifer, K.; Hülsenberg, D. Materials Science and Engineering: A, Vol. 417, Issue 1-2 https://doi.org/10.1016/j.msea.2005.11.001	journal	February 2006
Processing and characterisation of model optomechanical composites in the system sapphire fibre/borosilicate glass matrix Boccaccini, A. R.; Acevedo, D.; Dericioglu, A. F. Journal of Materials Processing Technology, Vol. 169, Issue 2 https://doi.org/10.1016/j.jmatprotec.2005.03.011	journal	November 2005
Innovative manufacturing technique for glass matrix composites: extrusion of recycled TV set screen glass reinforced with Al2O3 platelets Minay, E. J.; Desbois, V.; Boccaccini, A. R. Journal of Materials Processing Technology, Vol. 142, Issue 2 https://doi.org/10.1016/S0924-0136(03)00644-7	journal	November 2003
Effect of thermomechanical loads on microstructural damage and on the resulting thermomechanical behaviour of silicon carbide fibre-reinforced glass matrix composites Boccaccini, A. R.; Torre, A. M.; Oldani, C. R. Materials Characterization, Vol. 54, Issue 1 https://doi.org/10.1016/j.matchar.2004.11.001	journal	January 2005
The synthesis, characterization and biocompatibility of poly(ester urethane)/polyhedral oligomeric silesquioxane nanocomposites Wang, Wenshou; Guo, Yan-lin; Otaigbe, Joshua U. Polymer, Vol. 50, Issue 24 https://doi.org/10.1016/j.polymer.2009.05.037	journal	November 2009
POSS related polymer nanocomposites Kuo, Shiao-Wei; Chang, Feng-Chih Progress in Polymer Science, Vol. 36, Issue 12 https://doi.org/10.1016/j.progpolymsci.2011.05.002	journal	December 2011
Developments in nanoscience: polyhedral oligomeric silsesquioxane (POSS)-polymers Phillips, Shawn H.; Haddad, Timothy S.; Tomczak, Sandra J. Current Opinion in Solid State and Materials Science, Vol. 8, Issue 1 https://doi.org/10.1016/j.cossms.2004.03.002	journal	January 2004
Nanostructured Polyurethane/POSS Hybrid Aqueous Dispersions Prepared by Homogeneous Solution Polymerization Nanda, Ajaya K.; Wicks, Douglas A.; Madbouly, Samy A. Macromolecules, Vol. 39, Issue 20 https://doi.org/10.1021/ma060809h	journal	October 2006
Linear Hybrid Polymer Building Blocks: Methacrylate-Functionalized Polyhedral Oligomeric Silsesquioxane Monomers and Polymers Lichtenhan, Joseph D.; Otonari, Yoshiko A.; Carr, Michael J. Macromolecules, Vol. 28, Issue 24 https://doi.org/10.1021/ma00128a067	journal	November 1995
Novel Polyolefin Nanocomposites: Synthesis and Characterizations of Metallocene-Catalyzed Polyolefin Polyhedral Oligomeric Silsesquioxane Copolymers Zheng, Lei; Farris, Richard J.; Coughlin, E. Bryan Macromolecules, Vol. 34, Issue 23 https://doi.org/10.1021/ma0110094	journal	November 2001
In Situ Oxygen-Atom Erosion Study of Polyhedral Oligomeric Silsesquioxane-Siloxane Copolymer Gonzalez, Rene I.; Phillips, Shawn H.; Hoflund, Gar B. Journal of Spacecraft and Rockets, Vol. 37, Issue 4 https://doi.org/10.2514/2.3606	journal	July 2000
Mechanical characterization of polyhedral oligomeric silsesquioxane/polypropylene blends Baldi, Francesco; Bignotti, Fabio; Fina, Alberto Journal of Applied Polymer Science, Vol. 105, Issue 2 https://doi.org/10.1002/app.26142	journal	January 2007
Thermal and mechanical properties of polyhedral oligomeric silsesquioxane (POSS)/polycarbonate composites Zhao, Yiqiang; Schiraldi, David A. Polymer, Vol. 46, Issue 25 https://doi.org/10.1016/j.polymer.2005.09.070	journal	November 2005
Properties of poly(ethylene terephthalate) containing epoxy-functionalized polyhedral oligomeric silsesquioxane Yoon, Kwan Han; Polk, Malcolm B.; Park, Jae Hong Polymer International, Vol. 54, Issue 1 https://doi.org/10.1002/pi.1661	journal	January 2004
Preparation, Thermal Properties, and T _g Increase Mechanism of Poly(acetoxystyrene- c o -octavinyl-polyhedral oligomeric silsesquioxane) Hybrid Nanocomposites Xu, Hongyao; Yang, Benhong; Wang, Jiafeng Macromolecules, Vol. 38, Issue 25 https://doi.org/10.1021/ma0516687	journal	November 2005
Synthesis and properties of poly(isobutyl methacrylate-co-butanediol dimethacrylate-co-methacryl polyhedral oligomeric silsesquioxane) nanocomposites Li, Gui Zhi; Cho, Hosouk; Wang, Lichang Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 2 https://doi.org/10.1002/pola.20503	journal	January 2004
Influence of PMMA-Chain-End Tethered Polyhedral Oligomeric Silsesquioxanes on the Miscibility and Specific Interaction with Phenolic Blends Huang, Chih-Feng; Kuo, Shiao-Wei; Lin, Fang-Ju Macromolecules, Vol. 39, Issue 1 https://doi.org/10.1021/ma051923n	journal	January 2006
Chemical synthesis and characterization of POSS-functionalized poly[3-hydroxyalkanoates] Hany, Roland; Hartmann, René; Böhlen, Christine Polymer, Vol. 46, Issue 14 https://doi.org/10.1016/j.polymer.2005.04.020	journal	June 2005
Quantitative Mapping of the Elastic Modulus of Soft Materials with HarmoniX and PeakForce QNM AFM Modes Dokukin, Maxim E.; Sokolov, Igor Langmuir, Vol. 28, Issue 46 https://doi.org/10.1021/la302706b	journal	November 2012
Nanomechanical properties of solvent cast polystyrene and poly(methyl methacrylate) polymer blends and self-assembled block copolymers Lorenzoni, Matteo; Evangelio, Laura; Nicolet, Célia Journal of Micro/Nanolithography, MEMS, and MOEMS, Vol. 14, Issue 3 https://doi.org/10.1117/1.JMM.14.3.033509	journal	July 2015
Force-distance curves by atomic force microscopy Cappella, B.; Dietler, G. Surface Science Reports, Vol. 34, Issue 1-3 https://doi.org/10.1016/S0167-5729(99)00003-5	journal	January 1999
Modelling one- and two-dimensional solid-state NMR spectra: Modelling 1D and 2D solid-state NMR spectra Massiot, Dominique; Fayon, Franck; Capron, Mickael Magnetic Resonance in Chemistry, Vol. 40, Issue 1 https://doi.org/10.1002/mrc.984	journal	December 2001
Synthesis and characterization of methacrylate phospho-silicate hybrid for thin film applications Kannan, Aravindaraj G.; Choudhury, Namita Roy; Dutta, Naba K. Polymer, Vol. 48, Issue 24 https://doi.org/10.1016/j.polymer.2007.09.050	journal	November 2007
Tin fluorophosphate nonwovens by melt state centrifugal Forcespinning Fang, Yichen; Herbert, Matthew; Schiraldi, David A. Journal of Materials Science, Vol. 49, Issue 24 https://doi.org/10.1007/s10853-014-8534-3	journal	August 2014
Structure and properties of silver phosphate glasses — Infrared and visible spectra Bartholomew, Roger F. Journal of Non-Crystalline Solids, Vol. 7, Issue 3 https://doi.org/10.1016/0022-3093(72)90024-5	journal	April 1972
Phosphate glass dissolution in aqueous solutions Bunker, B. C.; Arnold, G. W.; Wilder, J. A. Journal of Non-Crystalline Solids, Vol. 64, Issue 3 https://doi.org/10.1016/0022-3093(84)90184-4	journal	May 1984
The properties and structure of SnCaPOF glasses Ding, J. Y.; Shih, P. Y.; Yung, S. W. Materials Chemistry and Physics, Vol. 82, Issue 1 https://doi.org/10.1016/S0254-0584(03)00161-5	journal	September 2003
Rare earth phosphate glasses Sun, Kang; Risen, William M. Solid State Communications, Vol. 60, Issue 9 https://doi.org/10.1016/0038-1098(86)90424-2	journal	December 1986
Cyanate Ester/Polyhedral Oligomeric Silsesquioxane (POSS) Nanocomposites: Synthesis and Characterization ^† Liang, Kaiwen; Li, Guizhi; Toghiani, Hossein Chemistry of Materials, Vol. 18, Issue 2 https://doi.org/10.1021/cm051582s	journal	January 2006
Structure of glasses in the system SnPbPFO Anma, Motoya; Yano, Tetsuji; Yasumori, Atsuo Journal of Non-Crystalline Solids, Vol. 135, Issue 1 https://doi.org/10.1016/0022-3093(91)90446-D	journal	October 1991
Structure of SnF2-SnO-P2O5 Glasses York-Winegar, James; Harper, Tristan; Brennan, Carrie Physics Procedia, Vol. 44 https://doi.org/10.1016/j.phpro.2013.04.020	journal	January 2013
Nature of Alumina in Phosphate Glass: II, Structure of Sodium Alurninophosphate Glass Brow, Richard K.; Kirkpatrick, R. James; Turner, Gary L. Journal of the American Ceramic Society, Vol. 76, Issue 4 https://doi.org/10.1111/j.1151-2916.1993.tb05316.x	journal	April 1993
Zinc phosphate glass surfaces studied by XPS Onyiriuka, E. C. Journal of Non-Crystalline Solids, Vol. 163, Issue 3 https://doi.org/10.1016/0022-3093(93)91304-L	journal	December 1993
Oxygen bonding in nitrided sodium- and lithium-metaphosphate glasses Brow, R. K.; Reidmeyer, M. R.; Day, D. E. Journal of Non-Crystalline Solids, Vol. 99, Issue 1 https://doi.org/10.1016/0022-3093(88)90470-X	journal	January 1988
An XPS study of oxygen bonding in zinc phosphate and zinc borophosphate glasses Brow, Richard K. Journal of Non-Crystalline Solids, Vol. 194, Issue 3 https://doi.org/10.1016/0022-3093(95)00500-5	journal	February 1996
X-ray photoelectron spectroscopy study of copper sodium silicate glass surfaces Mekki, A.; Holland, D.; McConville, C. F. Journal of Non-Crystalline Solids, Vol. 215, Issue 2-3 https://doi.org/10.1016/S0022-3093(97)00048-3	journal	July 1997
A New Sol−Gel Route to Aluminum Fluoride Phosphate Glasses: Mechanistic Investigations by NMR Spectroscopy Zhang, Long; de Araujo, Carla C.; Eckert, Hellmut Chemistry of Materials, Vol. 17, Issue 12 https://doi.org/10.1021/cm050066z	journal	June 2005
Covalent Bonds in α-SnF2 Monitored by J-Couplings in Solid-State NMR Spectra Bräuniger, Thomas; Ghedia, Stefan; Jansen, Martin Zeitschrift für anorganische und allgemeine Chemie, Vol. 636, Issue 13-14 https://doi.org/10.1002/zaac.201000176	journal	August 2010
High-field ³¹ P N.M.R. investigations of the chemical shielding and indirect dipolar coupling of polycrystalline fluorophosphates Haubenreisser, Uwe; Sternberg, Ulrich; Grimmer, Arnd-Rüdiger Molecular Physics, Vol. 60, Issue 1 https://doi.org/10.1080/00268978700100111	journal	January 1987
A multinuclear MAS NMR study of the short-range structure of fluorophosphate glass Brow, R. K.; Osborne, Z. A.; Kirkpatrick, R. J. Journal of Materials Research, Vol. 7, Issue 7 https://doi.org/10.1557/JMR.1992.1892	journal	July 1992
Lone-pair effects and structural trends in x SnO (1 x ) P ₂ O ₅ glasses deduced from ³¹ P and ¹¹⁹ Sn nuclear magnetic resonance Holland, D.; Howes, A. P.; Smith, M. E. Journal of Physics: Condensed Matter, Vol. 14, Issue 49 https://doi.org/10.1088/0953-8984/14/49/315	journal	November 2002
Structure and properties of x SnO–(100 – x) P2O5 glasses Bekaert, Émilie; Montagne, Lionel; Delevoye, Laurent Comptes Rendus Chimie, Vol. 7, Issue 3-4 https://doi.org/10.1016/j.crci.2003.12.012	journal	March 2004
Investigation of Structure and Morphology Dynamics in Tin Fluorophosphate Glass − Polyethylene Hybrids Using Solid-State ¹ H, ¹³ C, and ³¹ P MAS NMR Tischendorf, Brad C.; Harris, Douglas J.; Otaigbe, Joshua U. Chemistry of Materials, Vol. 14, Issue 1 https://doi.org/10.1021/cm010670j	journal	January 2002
Silicate-phosphate interactions in silicate glasses and melts: I. A multinuclear ( 27 Al, 29 Si, 31 P) MAS NMR and ab initio chemical shielding ( 31 P) study of phosphorous speciation in silicate glasses Cody, George D.; Mysen, Bjorn; Sághi-Szabó, Gotthard Geochimica et Cosmochimica Acta, Vol. 65, Issue 14 https://doi.org/10.1016/S0016-7037(01)00597-X	journal	July 2001
The preparation and rheology characterization of long chain branching polypropylene Tian, Jinghua; Yu, Wei; Zhou, Chixing Polymer, Vol. 47, Issue 23 https://doi.org/10.1016/j.polymer.2006.09.042	journal	October 2006
Rheology of multi-walled carbon nanotube/poly(butylene terephthalate) composites Wu, Defeng; Wu, Liang; Zhang, Ming Journal of Polymer Science Part B: Polymer Physics, Vol. 45, Issue 16 https://doi.org/10.1002/polb.21233	journal	January 2007
A Theory of the Linear Viscoelastic Properties of Dilute Solutions of Coiling Polymers Rouse, Prince E. The Journal of Chemical Physics, Vol. 21, Issue 7 https://doi.org/10.1063/1.1699180	journal	July 1953
Melt rheology of zinc alkali phosphate glasses Sammler, R. L.; Otaigbe, J. U.; Lapham, M. L. Journal of Rheology, Vol. 40, Issue 2 https://doi.org/10.1122/1.550741	journal	March 1996
Melt Rheology of Tin Phosphate Glasses Adalja, Sunil B.; Otaigbe, Joshua U. Applied Rheology, Vol. 11, Issue 1 https://doi.org/10.1515/arh-2001-0001	journal	February 2001
Imaging surface nanobubbles at graphite–water interfaces with different atomic force microscopy modes Yang, Chih-Wen; Lu, Yi-Hsien; Hwang, Ing-Shouh Journal of Physics: Condensed Matter, Vol. 25, Issue 18 https://doi.org/10.1088/0953-8984/25/18/184010	journal	April 2013
Effect of contact deformations on the adhesion of particles Derjaguin, B. V.; Muller, V. M.; Toporov, Yu. P. Journal of Colloid and Interface Science, Vol. 53, Issue 2 https://doi.org/10.1016/0021-9797(75)90018-1	journal	November 1975

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
tin fluorophosphate glass
polyhedral oligomeric silsesquioxane
melt rheology
nanomechanical properties
glass matrix nanocomposites
molecular silica

Title: Synthesis and characterization of novel phosphate glass matrix nanocomposites containing polyhedral oligomeric silsesquioxane with improved properties

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