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Title: pH effects on the electrochemical reduction of CO(2) towards C2 products on stepped copper

Journal Article · · Nature Communications
 [1];  [1];  [2];  [3];  [1];  [1];  [1];  [1];  [1];  [1];  [4];  [1];  [5];  [6]
  1. Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
  2. Stanford Univ., Stanford, CA (United States); Westlake Univ., Hangzhou (China)
  3. Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States); Guangzhou Univ., Guangzhou (China)
  4. SLAC National Accelerator Lab., Menlo Park, CA (United States)
  5. Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States); Technical Univ. of Denmark, Lyngby (Denmark)
  6. SLAC National Accelerator Lab., Menlo Park, CA (United States); Technical Univ. of Denmark, Lyngby (Denmark)
+ Show Author Affiliations

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1487380
Alternate ID(s):
OSTI ID: 1529394
Journal Information:
Nature Communications, Vol. 10, Issue 1; ISSN 2041-1723
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 362 works
Citation information provided by
Web of Science

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Acetaldehyde as an Intermediate in the Electroreduction of Carbon Monoxide to Ethanol on Oxide-Derived Copper journal December 2015
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Theoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes journal June 2013
Selectivity of CO 2 Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps journal January 2013
Acetaldehyde As an Intermediate in the Electroreduction of Carbon Monoxide to Ethanol on Oxide-Derived Copper journal April 2016
First-principles extrapolation method for accurate CO adsorption energies on metal surfaces text January 2003
Structure and Vibrations of the Vicinal Copper (211) Surface text January 1997
Construction of Pd-Zn dual sites to enhance the performance for ethanol electro-oxidation reaction journal September 2021

Cited By (20)

Electrode Materials Engineering in Electrocatalytic CO 2 Reduction: Energy Input and Conversion Efficiency journal October 2019
Hydroxide Is Not a Promoter of C 2+ Product Formation in the Electrochemical Reduction of CO on Copper journal March 2020
The Crucial Role of Charge Accumulation and Spin Polarization in Activating Carbon‐Based Catalysts for Electrocatalytic Nitrogen Reduction journal March 2020
Hydroxide Is Not a Promoter of C 2+ Product Formation in the Electrochemical Reduction of CO on Copper journal January 2020
The Crucial Role of Charge Accumulation and Spin Polarization in Activating Carbon‐Based Catalysts for Electrocatalytic Nitrogen Reduction journal February 2020
Structure‐Tunable Copper–Indium Catalysts for Highly Selective CO 2 Electroreduction to CO or HCOOH journal August 2019
Computational and experimental demonstrations of one-pot tandem catalysis for electrochemical carbon dioxide reduction to methane journal July 2019
Double layer charging driven carbon dioxide adsorption limits the rate of electrochemical carbon dioxide reduction on Gold journal January 2020
Hydroxide promotes carbon dioxide electroreduction to ethanol on copper via tuning of adsorbed hydrogen journal December 2019
Bio-inspired hydrophobicity promotes CO2 reduction on a Cu surface journal August 2019
Synergistic enhancement of electrocatalytic CO2 reduction to C2 oxygenates at nitrogen-doped nanodiamonds/Cu interface journal January 2020
Two-dimensional copper nanosheets for electrochemical reduction of carbon monoxide to acetate journal April 2019
Designing materials for electrochemical carbon dioxide recycling journal July 2019
Mechanistic study on Cu-catalyzed CO 2 electroreduction into CH 4 at simulated low overpotentials based on an improved electrochemical model journal January 2019
Silicon-doped graphene edges: an efficient metal-free catalyst for the reduction of CO 2 into methanol and ethanol journal January 2019
Atomically dispersed asymmetric Cu–B pair on 2D carbon nitride synergistically boosts the conversion of CO into C 2 products journal January 2020
Advances and challenges in electrochemical CO 2 reduction processes: an engineering and design perspective looking beyond new catalyst materials journal January 2020
Selective reduction of CO to acetaldehyde with CuAg electrocatalysts journal January 2020
Cover Picture: Hydroxide Is Not a Promoter of C 2+ Product Formation in the Electrochemical Reduction of CO on Copper (Angew. Chem. Int. Ed. 11/2020) journal January 2020
Titelbild: Hydroxide Is Not a Promoter of C 2+ Product Formation in the Electrochemical Reduction of CO on Copper (Angew. Chem. 11/2020) journal March 2020

Figures / Tables (5)

Figure 1(p. 5)figure Figure 1
Figure 2(p. 7)figure Figure 2
Figure 3(p. 9)figure Figure 3
Figure 4(p. 11)figure Figure 4
Figure 5(p. 13)figure Figure 5

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY