Compositional and structural insights into the nature of the H-cluster precursor on HydF

Scott, Anna G.; Szilagyi, Robert K.; Mulder, David W.; Ratzloff, Michael W.; Byer, Amanda S.; King, Paul W.; Broderick, William E.; Shepard, Eric M.; Broderick, Joan B.

doi:10.1039/C8DT01654B

Title: Compositional and structural insights into the nature of the H-cluster precursor on HydF

Journal Article · Tue Jun 19 00:00:00 EDT 2018 · Dalton Transactions

DOI:https://doi.org/10.1039/C8DT01654B· OSTI ID:1466185

Scott, Anna G. ^[1];

^[1]; Mulder, David W. ^[2]; Ratzloff, Michael W. ^[2]; Byer, Amanda S. ^[1];

^[2]; Broderick, William E. ^[1]; Shepard, Eric M. ^[1];

^[1]

Montana State Univ., Bozeman, MT (United States)
National Renewable Energy Lab. (NREL), Golden, CO (United States)

Spectroscopic and computational characterization of loaded HydF reveals that the 2Fe subcluster is a coordinatively saturated Fe( i )–Fe( i ) species that contains 4 CO and 2 CN ligands, and is anchored to HydF via coordination to a [4Fe–4S] cluster.

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Research Organization:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC36-08GO28308; AC36-08-GO28308; SC0005404

OSTI ID:: 1466185

Alternate ID(s):: OSTI ID: 1458586

Report Number(s):: NREL/JA-2700-71169; ICHBD9

Journal Information:: Dalton Transactions, Vol. 47, Issue 28; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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