Heavy ion irradiations on synthetic hollandite-type materials: Ba1.0Cs0.3A2.3Ti5.7O16 (A=Cr, Fe, Al)

Tang, Ming; Tumurugoti, Priyatham; Clark, Braeden; Sundaram, S. K.; Amoroso, Jake; Marra, James; Sun, Cheng; Lu, Ping; Wang, Yongqiang; Jiang, Ying. -Bing.

doi:10.1016/j.jssc.2016.04.014

Title: Heavy ion irradiations on synthetic hollandite-type materials: Ba_1.0Cs_0.3A_2.3Ti_5.7O₁₆ (A=Cr, Fe, Al)

Journal Article · Tue Apr 12 00:00:00 EDT 2016 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2016.04.014· OSTI ID:1458922

^[1]; Tumurugoti, Priyatham ^[2]; Clark, Braeden ^[2]; Sundaram, S. K. ^[2]; Amoroso, Jake ^[3]; Marra, James ^[3]; Sun, Cheng ^[1]; Lu, Ping ^[4];

^[1]; Jiang, Ying. -Bing. ^[5]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Alfred Univ., NY (United States). Kazuo Inamori School of Engineering and the New York State College of Ceramics
Savannah River National Lab (SRNL), Aiken, SC (United States). Materials Science and Technology Directorate
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Univ. of New Mexico, Albuquerque, NM (United States). TEM Lab.

The hollandite supergroup of minerals has received considerable attention as a nuclear waste form for immobilization of Cs. Here, the radiation stability of synthetic hollandite-type compounds described generally as Ba_1.0Cs_0.3A_2.3Ti_5.7O₁₆ (A=Cr, Fe, Al) were evaluated by heavy ion (Kr) irradiations on polycrystalline single phase materials and multiphase materials incorporating the hollandite phases. Ion irradiation damage effects on these samples were examined using grazing incidence X-ray diffraction (GIXRD) and transmission electron microscopy (TEM). Single phase compounds possess tetragonal structure with space group I4/m. GIXRD and TEM observations revealed that 600 keV Kr irradiation-induced amorphization on single phase hollandites compounds occurred at a fluence between 2.5×10¹⁴Kr/cm² and 5×10¹⁴ Kr/cm². The critical amorphization fluence of single phase hollandite compounds obtained by in situ 1 MeV Kr ion irradiation was around 3.25×10¹⁴ Kr/cm². The hollandite phase exhibited similar amorphization susceptibility under Kr ion irradiation when incorporated into a multiphase system.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Savannah River National Laboratory (SRNL), Aiken, SC (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5); USDOE National Nuclear Security Administration (NNSA); Kyocera Corp., Kyoto (Japan)

Contributing Organization:: Idaho National Laboratory (INL), Idaho Falls, ID (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Grant/Contract Number:: AC52-06NA25396; AC04-94AL85000; AC02–06CH11357

OSTI ID:: 1458922

Alternate ID(s):: OSTI ID: 1337199

Report Number(s):: LA-UR-15-29651; TRN: US1901522

Journal Information:: Journal of Solid State Chemistry, Vol. 239, Issue C; ISSN 0022-4596

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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Cited By (2)

Atomistic scale investigation of cation ordering and phase stability in Cs-substituted Ba1.33Zn1.33Ti6.67O16, Ba1.33Ga2.66Ti5.67O16 and Ba1.33Al2.66Ti5.33O16 hollandite Wen, Yi; Xu, Yun; Brinkman, Kyle S. Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-22982-7	journal	March 2018
Compositional control of tunnel features in hollandite-based ceramics: structure and stability of (Ba,Cs)1.33(Zn,Ti)8O16 Grote, R.; Zhao, M.; Shuller-Nickles, L. Journal of Materials Science, Vol. 54, Issue 2 https://doi.org/10.1007/s10853-018-2904-1	journal	September 2018

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Title: Heavy ion irradiations on synthetic hollandite-type materials: Ba1.0Cs0.3A2.3Ti5.7O16 (A=Cr, Fe, Al)

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Title: Heavy ion irradiations on synthetic hollandite-type materials: Ba_1.0Cs_0.3A_2.3Ti_5.7O₁₆ (A=Cr, Fe, Al)