Nuclear-spin optical rotation in xenon

Savukov, Igor Mykhaylovich

doi:10.1103/PhysRevA.92.042514

Title: Nuclear-spin optical rotation in xenon

Journal Article · Thu Oct 29 00:00:00 EDT 2015 · Physical Review. A

DOI:https://doi.org/10.1103/PhysRevA.92.042514· OSTI ID:1457251

^[1]

New Mexico Consortium, Los Alamos, NM (United States)

We report that the nuclear-spin optical rotation (NSOR) effect, which has potential applications in correlated nuclear-spin-resonance optical spectroscopy, has previously been explored experimentally and theoretically in liquid Xe. Calculations of the Xe NSOR constant are very challenging because the result is sensitive to correlations, relativistic effects, and the choice of basis, with strong cancellation between contributions from lowest and remaining states. The relativistic configuration-interaction many-body-theory approach, presented here, is promising because this approach has been successful in predicting various properties of noble-gas atoms, such as energies, oscillator strengths (OSs), Verdet constants, and photoionization cross sections. However, correlations become stronger along the sequence of noble-gas atoms and the theoretical accuracy in Xe is not as high as, for example, in neon and argon. To improve the accuracy of the Xe Verdet and NSOR constants, which are calculated as explicit sums over the excited states, theoretical values for the several lowest levels are replaced with empirical values of energies, OSs, and hyperfine structure constants. We found that the Xe Verdet constant is in excellent agreement with accurate measurements. To take into account liquid effects, empirical data for energy shifts were also used to correct the NSOR constant. In conclusion, the resulting Xe NSOR constant is in a good agreement with experiment, although the liquid-state effect is treated quite approximately.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE; National Science Foundation (NSF)

Grant/Contract Number:: AC52-06NA25396; CHE-1404529

OSTI ID:: 1457251

Report Number(s):: LA-UR-15-25337; PLRAAN; TRN: US1901334

Journal Information:: Physical Review. A, Vol. 92, Issue 4; ISSN 1050-2947

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 4 works

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