Vacuum Ultraviolet Photoionization of Complex Chemical Systems

Kostko, Oleg; Bandyopadhyay, Biswajit; Ahmed, Musahid

doi:10.1146/annurev-physchem-040215-112553

Title: Vacuum Ultraviolet Photoionization of Complex Chemical Systems

Journal Article · Wed Feb 24 00:00:00 EST 2016 · Annual Review of Physical Chemistry

DOI:https://doi.org/10.1146/annurev-physchem-040215-112553· OSTI ID:1456939

Kostko, Oleg ^[1]; Bandyopadhyay, Biswajit ^[1]; Ahmed, Musahid ^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division

Tunable vacuum ultraviolet (VUV) radiation coupled to mass spectrometry is applied to the study of complex chemical systems in this paper. The identification of novel reactive intermediates and radicals is revealed in flame, pulsed photolysis, and pyrolysis reactors, leading to the elucidation of spectroscopy, reaction mechanisms, and kinetics. Mass-resolved threshold photoelectron photoion coincidence measurements provide unprecedented access to vibrationally resolved spectra of free radicals present in high-temperature reactors. Photoionization measurements in water clusters, nucleic acid base dimers, and their complexes with water provide signatures of proton transfer in hydrogen-bonded and π-stacked systems. Experimental and theoretical methods to track ion–molecule reactions and fragmentation pathways in intermolecular and intramolecular hydrogen-bonded systems in sugars and alcohols are described. Photoionization of laser-ablated molecules, clusters, and their reaction products inform thermodynamics and spectroscopy that are relevant to astrochemistry and catalysis. Finally, new directions in coupling VUV radiation to interrogate complex chemical systems are discussed.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1456939

Journal Information:: Annual Review of Physical Chemistry, Vol. 67, Issue 1; ISSN 0066-426X

Publisher:: Annual ReviewsCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 46 works

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DELICIOUS III: A multipurpose double imaging particle coincidence spectrometer for gas phase vacuum ultraviolet photodynamics studies Garcia, G. A.; Cunha de Miranda, B. K.; Tia, M. Review of Scientific Instruments, Vol. 84, Issue 5 https://doi.org/10.1063/1.4807751	journal	May 2013
Intramolecular CN Bond Activation and Ring-Expansion Reactions of N-Heterocyclic Carbenes Hemberger, Patrick; Bodi, Andras; Berthel, Johannes H. J. Chemistry - A European Journal, Vol. 21, Issue 4 https://doi.org/10.1002/chem.201406036	journal	November 2014
Unimolecular Reaction Mechanism of an Imidazolin-2-ylidene: An iPEPICO Study on the Complex Dissociation of an Arduengo-Type Carbene Hemberger, Patrick; Bodi, Andras; Gerber, Thomas Chemistry - A European Journal, Vol. 19, Issue 22 https://doi.org/10.1002/chem.201204465	journal	March 2013
Photoionization of cold gas phase coronene and its clusters: Autoionization resonances in monomer, dimer, and trimer and electronic structure of monomer cation Bréchignac, Philippe; Garcia, Gustavo A.; Falvo, Cyril The Journal of Chemical Physics, Vol. 141, Issue 16 https://doi.org/10.1063/1.4900427	journal	October 2014
VUV Photodynamics and Chiral Asymmetry in the Photoionization of Gas Phase Alanine Enantiomers Tia, Maurice; Cunha de Miranda, Barbara; Daly, Steven The Journal of Physical Chemistry A, Vol. 118, Issue 15 https://doi.org/10.1021/jp5016142	journal	April 2014
Mass-Analyzed Threshold Ionization (MATI) Spectroscopy of Atoms and Molecules Using VUV Synchrotron Radiation ^† Kostko, Oleg; Kim, Sang Kyu; Leone, Stephen R. The Journal of Physical Chemistry A, Vol. 113, Issue 52 https://doi.org/10.1021/jp9008338	journal	December 2009
Rovibrational-State-Selected Photoionization of Acetylene by the Two-Color $I R + V U V$ Scheme: Observation of Rotationally Resolved Rydberg Transitions Qian, X. -M.; Kung, A. H.; Zhang, Tao Physical Review Letters, Vol. 91, Issue 23 https://doi.org/10.1103/PhysRevLett.91.233001	journal	December 2003
Autoionizing Rydberg series(np′,nf′)of Ar investigated by stepwise excitations with lasers and synchrotron radiation Lee, Yin-Yu; Dung, Tzan-Yi; Hsieh, Re-Ming Physical Review A, Vol. 78, Issue 2 https://doi.org/10.1103/PhysRevA.78.022509	journal	August 2008
Desorption Dynamics, Internal Energies, and Imaging of Organic Molecules from Surfaces with Laser Desorption and Vacuum Ultraviolet (VUV) Photoionization Kostko, Oleg; Takahashi, Lynelle K.; Ahmed, Musahid Chemistry - An Asian Journal, Vol. 6, Issue 11 https://doi.org/10.1002/asia.201100419	journal	August 2011
Synchrotron-Based Mass Spectrometry to Investigate the Molecular Properties of Mineral–Organic Associations Liu, Suet Yi; Kleber, Markus; Takahashi, Lynelle K. Analytical Chemistry, Vol. 85, Issue 12 https://doi.org/10.1021/ac400976z	journal	May 2013
Elucidation of the chemical composition of avian melanin Liu, Suet Yi; Shawkey, Matthew D.; Parkinson, Dilworth RSC Adv., Vol. 4, Issue 76 https://doi.org/10.1039/C4RA06606E	journal	January 2014
Novel techniques in VUV high-resolution spectroscopy Ubachs, W.; Salumbides, E. J.; Eikema, K. S. E. Journal of Electron Spectroscopy and Related Phenomena, Vol. 196 https://doi.org/10.1016/j.elspec.2013.11.016	journal	October 2014
XUV frequency combs via femtosecond enhancement cavities Mills, Arthur K.; Hammond, T. J.; Lam, Matthew H. C. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 45, Issue 14 https://doi.org/10.1088/0953-4075/45/14/142001	journal	July 2012
New generation of light sources: Present and future Couprie, M. E. Journal of Electron Spectroscopy and Related Phenomena, Vol. 196 https://doi.org/10.1016/j.elspec.2013.12.007	journal	October 2014
On-line spectral diagnostic system for Dalian Coherent Light Source Li, Chaoyang; Wei, Shen; Du, Xuewei Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 783 https://doi.org/10.1016/j.nima.2015.01.089	journal	May 2015
Diffraction-limited storage rings – a window to the science of tomorrow Eriksson, Mikael; van der Veen, J. Friso; Quitmann, Christoph Journal of Synchrotron Radiation, Vol. 21, Issue 5 https://doi.org/10.1107/S1600577514019286	journal	August 2014
Improved Resolution of Hydrocarbon Structures and Constitutional Isomers in Complex Mixtures Using Gas Chromatography-Vacuum Ultraviolet-Mass Spectrometry Isaacman, Gabriel; Wilson, Kevin R.; Chan, Arthur W. H. Analytical Chemistry, Vol. 84, Issue 5 https://doi.org/10.1021/ac2030464	journal	February 2012
Heterogeneous OH Oxidation of Motor Oil Particles Causes Selective Depletion of Branched and Less Cyclic Hydrocarbons Isaacman, Gabriel; Chan, Arthur W. H.; Nah, Theodora Environmental Science & Technology, Vol. 46, Issue 19 https://doi.org/10.1021/es302768a	journal	September 2012
Isomeric Product Detection in the Heterogeneous Reaction of Hydroxyl Radicals with Aerosol Composed of Branched and Linear Unsaturated Organic Molecules Nah, Theodora; Zhang, Haofei; Worton, David R. The Journal of Physical Chemistry A, Vol. 118, Issue 49 https://doi.org/10.1021/jp508378z	journal	November 2014
Lubricating Oil Dominates Primary Organic Aerosol Emissions from Motor Vehicles Worton, David R.; Isaacman, Gabriel; Gentner, Drew R. Environmental Science & Technology, Vol. 48, Issue 7 https://doi.org/10.1021/es405375j	journal	March 2014
Elucidating secondary organic aerosol from diesel and gasoline vehicles through detailed characterization of organic carbon emissions Gentner, D. R.; Isaacman, G.; Worton, D. R. Proceedings of the National Academy of Sciences, Vol. 109, Issue 45 https://doi.org/10.1073/pnas.1212272109	journal	October 2012
Contribution of synchrotron radiation to photoactivation studies of biomolecular ions in the gas phase: ION ACTIVATION BY SYNCHROTRON RADIATION Giuliani, Alexandre; Milosavljević, Aleksandar R.; Canon, Francis Mass Spectrometry Reviews, Vol. 33, Issue 6 https://doi.org/10.1002/mas.21398	journal	December 2013
Photoelectron spectroscopy of size-selected cluster ions using synchrotron radiation Schramm, Thomas; Ganteför, Gerd; Bodi, Andras Applied Physics A, Vol. 115, Issue 3 https://doi.org/10.1007/s00339-014-8434-z	journal	April 2014
Higher Ionization Energies from Sequential Vacuum-Ultraviolet Multiphoton Ionization of Size-Selected Silicon Cluster Cations Kasigkeit, Christian; Hirsch, Konstantin; Langenberg, Andreas The Journal of Physical Chemistry C, Vol. 119, Issue 20 https://doi.org/10.1021/jp511928m	journal	February 2015
Photodissociation of protonated leucine-enkephalin in the VUV range of 8–40 eV Bari, S.; Gonzalez-Magaña, O.; Reitsma, G. The Journal of Chemical Physics, Vol. 134, Issue 2 https://doi.org/10.1063/1.3515301	journal	January 2011
Photoionization of a protein isolated in vacuo Milosavljević, Aleksandar R.; Nicolas, Christophe; Lemaire, Joel Physical Chemistry Chemical Physics, Vol. 13, Issue 34 https://doi.org/10.1039/c1cp21211g	journal	January 2011
Gas phase Photo-Formation and Vacuum UV Photofragmentation Spectroscopy of Tryptophan and Tyrosine Radical-Containing Peptides Brunet, Claire; Antoine, Rodolphe; Allouche, Abdul-Rahman The Journal of Physical Chemistry A, Vol. 115, Issue 32 https://doi.org/10.1021/jp205617x	journal	August 2011
Photo-induced electron detachment of protein polyanions in the VUV range Brunet, Claire; Antoine, Rodolphe; Dugourd, Philippe The Journal of Chemical Physics, Vol. 138, Issue 6 https://doi.org/10.1063/1.4790165	journal	February 2013
Valence shell direct double photodetachment in polyanions Brunet, Claire; Antoine, Rodolphe; Dugourd, Philippe New Journal of Physics, Vol. 15, Issue 6 https://doi.org/10.1088/1367-2630/15/6/063024	journal	June 2013
Photoelectron Wave Function in Photoionization: Plane Wave or Coulomb Wave? Gozem, Samer; Gunina, Anastasia O.; Ichino, Takatoshi The Journal of Physical Chemistry Letters, Vol. 6, Issue 22 https://doi.org/10.1021/acs.jpclett.5b01891	journal	October 2015

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CRF-PEPICO: Double velocity map imaging photoelectron photoion coincidence spectroscopy for reaction kinetics studies Sztáray, Bálint; Voronova, Krisztina; Torma, Krisztián G. The Journal of Chemical Physics, Vol. 147, Issue 1 https://doi.org/10.1063/1.4984304	journal	July 2017
An interstellar synthesis of phosphorus oxoacids Turner, Andrew M.; Bergantini, Alexandre; Abplanalp, Matthew J. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06415-7	journal	September 2018
Enabling liquid vapor analysis using synchrotron VUV single photon ionization mass spectrometry with a microfluidic interface Komorek, R.; Xu, B.; Yao, J. Review of Scientific Instruments, Vol. 89, Issue 11 https://doi.org/10.1063/1.5048315	journal	November 2018
Dissociative Ionization and Thermal Decomposition of Cyclopentanone Pastoors, Johan I. M.; Bodi, Andras; Hemberger, Patrick Chemistry - A European Journal, Vol. 23, Issue 53 https://doi.org/10.1002/chem.201702376	journal	August 2017

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