High-Performance Blue-Excitable Yellow Phosphor Obtained from an Activated Solvochromic Bismuth-Fluorophore Metal–Organic Framework

Deibert, Benjamin J.; Velasco, Ever; Liu, Wei; Teat, Simon J.; Lustig, William P.; Li, Jing

doi:10.1021/acs.cgd.6b00622

Title: High-Performance Blue-Excitable Yellow Phosphor Obtained from an Activated Solvochromic Bismuth-Fluorophore Metal–Organic Framework

Journal Article · Thu Jun 23 00:00:00 EDT 2016 · Crystal Growth and Design

DOI:https://doi.org/10.1021/acs.cgd.6b00622· OSTI ID:1436597

Deibert, Benjamin J. ^[1]; Velasco, Ever ^[1]; Liu, Wei ^[1]; Teat, Simon J. ^[2]; Lustig, William P. ^[1]; Li, Jing ^[1]

Rutgers Univ., Piscataway, NJ (United States). Dept. of Chemistry and Chemical Biology
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Here, we report the synthesis, structure, and photoluminescence properties of a new bismuth based luminescent metal-organic framework (LMOF). The framework is comprised of a 9-coordinated Bi 3+ building unit and 4', 4''', 4''''', 4'''''''-(ethene-1,1,2,2-tetrayl)tetrakis([1,1'-biphenyl]-4-carboxylic acid) (H₄tcbpe) organic linker, which has strong yellow aggregation induced emission (AIE). The structure can be viewed as two interpenetrated 4,4-anionic nets that are stabilized by K⁺ ions forming one-dimensional helical inorganic chains by connecting bismuth nodes through shared oxygen bonds. The as-made LMOF has a bluish emission centered at 459 nm with an internal quantum yield of 57% when excited at 360 nm. The emission properties of the LMOF were found to be highly solvochromic with respect to DMF. Upon partial solvent removal, the framework undergoes significant red-shifting to a greenish emission centered at 500 nm. Complete removal of DMF results in additional red-shifting fluorescence coupled with structural changes. The resulting material has strong blue-excitable (455 nm) yellow emission centered at 553 nm, with a quantum yield of 74%, which is maintained after heating in air for 5 days at 90°C. This is the second highest quantum yield value for blue-excited yellow emission among all reported LMOFs.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC02-05CH11231; DMR-1507210

OSTI ID:: 1436597

Journal Information:: Crystal Growth and Design, Vol. 16, Issue 8; ISSN 1528-7483

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 47 works

Citation information provided by
Web of Science

References (46)

Luminescent metal–organic frameworks Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K. Chemical Society Reviews, Vol. 38, Issue 5 https://doi.org/10.1039/b802352m	journal	January 2009
Luminescent Functional Metal–Organic Frameworks Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200101d	journal	June 2011
Luminescent metal–organic frameworks for chemical sensing and explosive detection Hu, Zhichao; Deibert, Benjamin J.; Li, Jing Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00010B	journal	January 2014
A distinct reversible colorimetric and fluorescent low pH response on a water-stable zirconium–porphyrin metal–organic framework Deibert, Benjamin J.; Li, Jing Chem. Commun., Vol. 50, Issue 68 https://doi.org/10.1039/C4CC01938E	journal	January 2014
A Luminescent Microporous Metal-Organic Framework for the Fast and Reversible Detection of High Explosives Lan, Anjian; Li, Kunhao; Wu, Haohan Angewandte Chemie International Edition, Vol. 48, Issue 13, p. 2334-2338 https://doi.org/10.1002/anie.200804853	journal	January 2009
New Microporous Metal−Organic Framework Demonstrating Unique Selectivity for Detection of High Explosives and Aromatic Compounds Pramanik, Sanhita; Zheng, Chong; Zhang, Xiao Journal of the American Chemical Society, Vol. 133, Issue 12 https://doi.org/10.1021/ja106851d	journal	March 2011
Effects of Extending the π-Electron System of Pillaring Linkers on Fluorescence Sensing of Aromatic Compounds in Two Isoreticular Metal–Organic Frameworks Azhdari Tehrani, Alireza; Ghasempour, Hosein; Morsali, Ali Crystal Growth & Design, Vol. 15, Issue 11 https://doi.org/10.1021/acs.cgd.5b01175	journal	October 2015
White Light Emission and Second Harmonic Generation from Secondary Group Participation (SGP) in a Coordination Network He, Jun; Zeller, Matthias; Hunter, Allen D. Journal of the American Chemical Society, Vol. 134, Issue 3 https://doi.org/10.1021/ja2073559	journal	January 2012
Luminescent MTN -Type Cluster–Organic Framework with 2.6 nm Cages Kang, Yao; Wang, Fei; Zhang, Jian Journal of the American Chemical Society, Vol. 134, Issue 43 https://doi.org/10.1021/ja308801n	journal	October 2012
Solution Processable MOF Yellow Phosphor with Exceptionally High Quantum Efficiency Gong, Qihan; Hu, Zhichao; Deibert, Benjamin J. Journal of the American Chemical Society, Vol. 136, Issue 48 https://doi.org/10.1021/ja509446h	journal	November 2014
Achieving exceptionally high luminescence quantum efficiency by immobilizing an AIE molecular chromophore into a metal–organic framework Hu, Zhichao; Huang, Guangxi; Lustig, William P. Chemical Communications, Vol. 51, Issue 15 https://doi.org/10.1039/C4CC07642G	journal	January 2015
Eu2+-doped Ca-α-SiAlON: A yellow phosphor for white light-emitting diodes Xie, Rong-Jun; Hirosaki, Naoto; Sakuma, Ken Applied Physics Letters, Vol. 84, Issue 26 https://doi.org/10.1063/1.1767596	journal	June 2004
How to produce white light in a single-phase host? Shang, Mengmeng; Li, Chunxia; Lin, Jun Chem. Soc. Rev., Vol. 43, Issue 5 https://doi.org/10.1039/C3CS60314H	journal	January 2014
Effective Detection of Mycotoxins by a Highly Luminescent Metal–Organic Framework Hu, Zhichao; Lustig, William P.; Zhang, Jingming Journal of the American Chemical Society, Vol. 137, Issue 51 https://doi.org/10.1021/jacs.5b10308	journal	December 2015
Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement Wei, Zhangwen; Gu, Zhi-Yuan; Arvapally, Ravi K. Journal of the American Chemical Society, Vol. 136, Issue 23 https://doi.org/10.1021/ja5006866	journal	May 2014
Selective Turn-On Ammonia Sensing Enabled by High-Temperature Fluorescence in Metal–Organic Frameworks with Open Metal Sites Shustova, Natalia B.; Cozzolino, Anthony F.; Reineke, Sebastian Journal of the American Chemical Society, Vol. 135, Issue 36 https://doi.org/10.1021/ja407778a	journal	August 2013
Turn-On Fluorescence in Tetraphenylethylene-Based Metal–Organic Frameworks: An Alternative to Aggregation-Induced Emission Shustova, Natalia B.; McCarthy, Brian D.; Dincă, Mircea Journal of the American Chemical Society, Vol. 133, Issue 50 https://doi.org/10.1021/ja209327q	journal	December 2011
Phenyl Ring Dynamics in a Tetraphenylethylene-Bridged Metal–Organic Framework: Implications for the Mechanism of Aggregation-Induced Emission Shustova, Natalia B.; Ong, Ta-Chung; Cozzolino, Anthony F. Journal of the American Chemical Society, Vol. 134, Issue 36 https://doi.org/10.1021/ja306042w	journal	August 2012
Luminescent Behavior of Bismuth in Rare-Earth Oxides Datta, R. K. Journal of The Electrochemical Society, Vol. 114, Issue 11 https://doi.org/10.1149/1.2426433	journal	January 1967
Bismuth-doped optical fibers: a challenging active medium for near-IR lasers and optical amplifiers Dianov, Evgeny M. Light: Science & Applications, Vol. 1, Issue 5 https://doi.org/10.1038/lsa.2012.12	journal	May 2012
The nature of Bi3+ luminescence in garnet hosts Setlur, A. A.; Srivastava, A. M. Optical Materials, Vol. 29, Issue 4 https://doi.org/10.1016/j.optmat.2005.09.076	journal	December 2006
NMR, ESR, and Luminescence Characterization of Bismuth Embedded Zeolites Y Sun, Hong-Tao; Sakka, Yoshio; Shirahata, Naoto The Journal of Physical Chemistry C, Vol. 117, Issue 12 https://doi.org/10.1021/jp401861c	journal	March 2013
Bismuth—Production, properties, and applications Ojebuoboh, Funsho K. JOM, Vol. 44, Issue 4 https://doi.org/10.1007/BF03222821	journal	April 1992
Bismuth(III) complexes with aminopolycarboxylate and polyaminopolycarboxylate ligands: Chemistry and structure Stavila, Vitalie; Davidovich, Ruven L.; Gulea, Aurelian Coordination Chemistry Reviews, Vol. 250, Issue 21-22 https://doi.org/10.1016/j.ccr.2006.02.032	journal	November 2006
Biocoordination chemistry of bismuth: Recent advances Yang, N.; Sun, H. Coordination Chemistry Reviews, Vol. 251, Issue 17-20 https://doi.org/10.1016/j.ccr.2007.03.003	journal	September 2007
Hydrate Isomerism in Coordination Polymers of Bismuth and Acetylenedicarboxylate Busch, Stefanie; Stein, Irena; Ruschewitz, Uwe Zeitschrift für anorganische und allgemeine Chemie, Vol. 638, Issue 12-13 https://doi.org/10.1002/zaac.201200006	journal	May 2012
Hydrothermal synthesis and characteristics of 3-D hydrated bismuth oxalate coordination polymers with open-channel structure Chen, Xinxiang; Cao, Yanning; Zhang, Hanhui Journal of Solid State Chemistry, Vol. 181, Issue 5 https://doi.org/10.1016/j.jssc.2008.02.018	journal	May 2008
Bismuth Tri- and Tetraarylcarboxylates: Crystal Structures, In Situ X-ray Diffraction, Intermediates and Luminescence Feyand, Mark; Köppen, Milan; Friedrichs, Gernot Chemistry - A European Journal, Vol. 19, Issue 37 https://doi.org/10.1002/chem.201301139	journal	July 2013
Automated Diffraction Tomography for the Structure Elucidation of Twinned, Sub-micrometer Crystals of a Highly Porous, Catalytically Active Bismuth Metal-Organic Framework Feyand, Mark; Mugnaioli, Enrico; Vermoortele, Frederik Angewandte Chemie International Edition, Vol. 51, Issue 41 https://doi.org/10.1002/anie.201204963	journal	September 2012
Unprecedented Topological Complexity in a Metal–Organic Framework Constructed from Simple Building Units Inge, A. Ken; Köppen, Milan; Su, Jie Journal of the American Chemical Society, Vol. 138, Issue 6 https://doi.org/10.1021/jacs.5b12484	journal	February 2016
A Novel Bismuth-Based Metal-Organic Framework for High Volumetric Methane and Carbon Dioxide Adsorption Savage, Mathew; Yang, Sihai; Suyetin, Mikhail Chemistry - A European Journal, Vol. 20, Issue 26 https://doi.org/10.1002/chem.201304799	journal	May 2014
Mixed Cu(ii)–Bi(iii) metal organic framework with a 2D inorganic subnetwork and its catalytic activity Shi, Fa-Nian; Silva, Ana Rosa; Yang, Ting-Hai CrystEngComm, Vol. 15, Issue 19 https://doi.org/10.1039/c3ce27056d	journal	January 2013
A novel 3-D chiral bismuth–organic framework with mixed carboxylate, pyridine and thiolate donors exhibiting a semiconductive property Sun, Yan-Qiong; Ge, Su-Zhi; Liu, Qi CrystEngComm, Vol. 15, Issue 47 https://doi.org/10.1039/c3ce41696h	journal	January 2013
Anionic Metal-Organic Frameworks of Bismuth Benzenedicarboxylates: Synthesis, Structure and Ligand-Sensitized Photoluminescence Thirumurugan, A.; Cheetham, Anthony K. European Journal of Inorganic Chemistry, Vol. 2010, Issue 24 https://doi.org/10.1002/ejic.201000535	journal	July 2010
Heterometallic Inorganic−Organic Frameworks of Sodium−Bismuth Benzenedicarboxylates Thirumurugan, A.; Tan, Jin-Chong; Cheetham, Anthony K. Crystal Growth & Design, Vol. 10, Issue 4 https://doi.org/10.1021/cg901402f	journal	December 2009
A 3-D bismuth–organic framework containing 1-D cationic inorganic [Bi2O2]2+ chains Tran, Dat T.; Chu, Deryn; Oliver, Allen G. Inorganic Chemistry Communications, Vol. 12, Issue 10 https://doi.org/10.1016/j.inoche.2009.08.030	journal	October 2009
Mechanochemical synthesis and characterisation of two new bismuth metal organic frameworks Tröbs, L.; Wilke, M.; Szczerba, W. CrystEngComm, Vol. 16, Issue 25 https://doi.org/10.1039/C3CE42633E	journal	January 2014
A novel metal–organic framework based on bismuth and trimesic acid: synthesis, structure and properties Wang, Guanzhi; Liu, Yuanyuan; Huang, Baibiao Dalton Transactions, Vol. 44, Issue 37 https://doi.org/10.1039/C5DT03111G	journal	January 2015
A Bismuth-Based Metal-Organic Framework as an Efficient Visible-Light-Driven Photocatalyst Wang, Guanzhi; Sun, Qilong; Liu, Yuanyuan Chemistry - A European Journal, Vol. 21, Issue 6 https://doi.org/10.1002/chem.201405047	journal	December 2014
Structural Diversity of Metal–Organic Materials Containing Bismuth(III) and Pyridine-2,5-Dicarboxylate Wibowo, Arief C.; Smith, Mark D.; zur Loye, Hans-Conrad Crystal Growth & Design, Vol. 11, Issue 10 https://doi.org/10.1021/cg200639b	journal	October 2011
Novel 3D bismuth-based coordination polymers: Synthesis, structure, and second harmonic generation properties Wibowo, Arief C.; Smith, Mark D.; Yeon, Jeongho Journal of Solid State Chemistry, Vol. 195 https://doi.org/10.1016/j.jssc.2012.01.038	journal	November 2012
New 3D bismuth-oxo coordination polymers containing terephthalate-based ligands: observation of Bi ₂ O ₂ -layer and Bi ₄ O ₃ -chain motifs Wibowo, Arief C.; Smith, Mark D.; zur Loye, Hans-Conrad CrystEngComm, Vol. 13, Issue 2 https://doi.org/10.1039/C0CE00650E	journal	January 2011
A new Kagomé lattice coordination polymer based on bismuth and pyridine-2,5-dicarboxylate: structure and photoluminescent properties Wibowo, Arief C.; Smith, Mark D.; zur Loye, Hans-Conrad Chemical Communications, Vol. 47, Issue 26 https://doi.org/10.1039/c1cc11720c	journal	January 2011
Novel Bismuth and Lead Coordination Polymers Synthesized with Pyridine-2,5-Dicarboxylates: Two Single Component “White” Light Emitting Phosphors Wibowo, Arief C.; Vaughn, Shae A.; Smith, Mark D. Inorganic Chemistry, Vol. 49, Issue 23 https://doi.org/10.1021/ic1014708	journal	December 2010
Zr-based metal–organic frameworks: design, synthesis, structure, and applications Bai, Yan; Dou, Yibo; Xie, Lin-Hua Chemical Society Reviews, Vol. 45, Issue 8 https://doi.org/10.1039/C5CS00837A	journal	January 2016
Synthesis and structural studies of the simplest bismuth( iii ) oxo-salicylate complex: [Bi ₄ (μ ₃ -O) ₂ (HO-2-C ₆ H ₄ CO ₂ ) ₈ ]·2Solv (Solv = MeCN or MeNO ₂ ) Boyd, Tyler D.; Kumar, Ish; Wagner, Eric E. Chem. Commun., Vol. 50, Issue 27 https://doi.org/10.1039/c4cc00056k	journal	January 2014

Cited By (17)

A Nonlinear Optically Active Bismuth-Camphorate Coordination Polymer: A Nonlinear Optically Active Bismuth-Camphorate Coordination Polymer Vilela, Sérgio M. F.; Babaryk, Artem A.; Jaballi, Rim European Journal of Inorganic Chemistry, Vol. 2018, Issue 20-21 https://doi.org/10.1002/ejic.201800197	journal	May 2018
Multi-Photon Absorption in Metal-Organic Frameworks Medishetty, Raghavender; Nemec, Lydia; Nalla, Venkatram Angewandte Chemie International Edition, Vol. 56, Issue 46 https://doi.org/10.1002/anie.201706492	journal	October 2017
Two blue-light excitable yellow-emitting LMOF phosphors constructed by triangular tri(4-pyridylphenyl)amine Wang, Fangming; Zhou, Zeyu; Liu, Wei Dalton Transactions, Vol. 46, Issue 3 https://doi.org/10.1039/c6dt03883b	journal	January 2017
Robust fluorescent calcium coordination polymers as Cu ²⁺ sensors with high sensitivity and fast response Wu, Zhao-Feng; Velasco, Ever; Shan, Chuan Journal of Materials Chemistry C https://doi.org/10.1039/d0tc00825g	journal	January 2020
Tetraphenylethylene tetracylhydrazine macrocycle with capability for discrimination of n-propanol from i-propanol and highly sensitive/selective detection of nitrobenzene Xie, Wen-Zhao; Zhang, Hong-Chao; Zheng, Yan-Song J. Mater. Chem. C, Vol. 5, Issue 40 https://doi.org/10.1039/c7tc02525d	journal	January 2017
Pure white light emission from a rare earth-free intrinsic metal–organic framework and its application in a WLED Mondal, Tuhina; Mondal, Supriya; Bose, Saptasree Journal of Materials Chemistry C, Vol. 6, Issue 3 https://doi.org/10.1039/c7tc05215d	journal	January 2018
Improving LMOF luminescence quantum yield through guest-mediated rigidification Lustig, William P.; Teat, Simon J.; Li, Jing Journal of Materials Chemistry C, Vol. 7, Issue 46 https://doi.org/10.1039/c9tc05216j	journal	January 2019
Efficient detection of Cr ³⁺ and Cr ₂ O ₇ ²⁻ using a Zn( ii ) luminescent metal–organic framework Guo, Qi; Ma, Tingting; Zhou, Liuqing New Journal of Chemistry, Vol. 44, Issue 18 https://doi.org/10.1039/c9nj05999g	journal	January 2020
Phosphorescence emission and fine structures observed respectively under ambient conditions and at ca. 55 K in a coordination polymer of lead( ii )-thiophenedicarboxylate He, Jin-Yu; Deng, Zheng-Rong; Liu, Xiao Dalton Transactions, Vol. 47, Issue 28 https://doi.org/10.1039/c8dt01951g	journal	January 2018
Alkaline-earth metal based MOFs with second scale long-lasting phosphor behavior Briones, David; Leo, Pedro; Cepeda, Javier CrystEngComm, Vol. 20, Issue 33 https://doi.org/10.1039/c8ce00479j	journal	January 2018
In situ encapsulation of pyridine-substituted tetraphenylethene cations in metal–organic framework for the detection of antibiotics in aqueous medium Ying, Yan-Mei; Tao, Chen-Lei; Yu, Maoxing Journal of Materials Chemistry C, Vol. 7, Issue 27 https://doi.org/10.1039/c9tc02229e	journal	January 2019
Nonwoven fabric coated with a tetraphenylethene-based luminescent metal–organic framework for selective and sensitive sensing of nitrobenzene and ammonia Tao, Chen-Lei; Ying, Yan-Mei; Wang, Hui Journal of Materials Chemistry C, Vol. 6, Issue 45 https://doi.org/10.1039/c8tc03587c	journal	January 2018
Significant enhancement of cathode-ray scintillation for a conductive Bi-SMOF via in situ partial rare earth ion replacement Lu, Jian; Zhao, Xiu-Hui; Bai, Bing Journal of Materials Chemistry C, Vol. 7, Issue 36 https://doi.org/10.1039/c9tc03858b	journal	January 2019
Zinc/itaconate coordination polymers as first examples with long-lasting phosphorescence based on acyclic ligands Wibowo, Atmanto Heru; Suryandari, Yetti; Masykur, Abu Journal of Materials Chemistry C, Vol. 6, Issue 40 https://doi.org/10.1039/c8tc03598a	journal	January 2018
α- and β-[Bmim][BiCl ₄ (2,2′-bpy)]: Two Polymorphic Bismuth-Containing Ionic Liquids with Crystallization-Induced Phosphorescence Shen, Nannan; Li, Jianrong; Wu, Zhaofeng Chemistry - A European Journal, Vol. 23, Issue 62 https://doi.org/10.1002/chem.201703552	journal	October 2017
Recent advances in AIEgen-based luminescent metal–organic frameworks and covalent organic frameworks Ma, Li; Feng, Xiao; Wang, Shan Materials Chemistry Frontiers, Vol. 1, Issue 12 https://doi.org/10.1039/c7qm00254h	journal	January 2017
A new luminescent metal–organic framework based on dicarboxyl-substituted tetraphenylethene for efficient detection of nitro-containing explosives and antibiotics in aqueous media Liu, Xun-Gao; Tao, Chen-Lei; Yu, Huang-Qin Journal of Materials Chemistry C, Vol. 6, Issue 12 https://doi.org/10.1039/c7tc05535h	journal	January 2018

Similar Records

Achieving a blue-excitable yellow-emitting Ca-LMOF phosphor via water induced phase transformation

Journal Article · Sat Jan 01 00:00:00 EST 2022 · Chemical Science · OSTI ID:1436597

Wu, Zhao-Feng; Tan, Bin; Fu, Zhi-Hua; +7 more

Rational design of a high-efficiency, multivariate metal–organic framework phosphor for white LED bulbs

Journal Article · Fri Jan 10 00:00:00 EST 2020 · Chemical Science · OSTI ID:1436597

Lustig, William P.; Shen, Zeqing; Teat, Simon J.; +4 more

Facile solution-precipitation assisted synthesis and luminescence property of greenish-yellow emitting Ca{sub 6}Ba(PO{sub 4}){sub 4}O:Eu{sup 2+} phosphor

Journal Article · Tue Mar 15 00:00:00 EDT 2016 · Materials Research Bulletin · OSTI ID:1436597

Ji, Haipeng; Huang, Zhaohui; Xia, Zhiguo; +3 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
bismuth
chromophore
luminescent MOF
phosphor
White LED

Title: High-Performance Blue-Excitable Yellow Phosphor Obtained from an Activated Solvochromic Bismuth-Fluorophore Metal–Organic Framework

Citation Formats

References (46)

Cited By (17)

Linked Research (1)

Similar Records

Related Subjects