Monovalent manganese based anodes and co-solvent electrolyte for stable low-cost high-rate sodium-ion batteries

Firouzi, Ali; Qiao, Ruimin; Motallebi, Shahrokh; Valencia, Christian W.; Israel, Hannah S.; Fujimoto, Mai; Wray, L. Andrew; Chuang, Yi-De; Yang, Wanli; Wessells, Colin D.

doi:10.1038/s41467-018-03257-1

Title: Monovalent manganese based anodes and co-solvent electrolyte for stable low-cost high-rate sodium-ion batteries

Journal Article · Wed Feb 28 00:00:00 EST 2018 · Nature Communications

DOI:https://doi.org/10.1038/s41467-018-03257-1· OSTI ID:1433131

Firouzi, Ali ^[1]; Qiao, Ruimin ^[2]; Motallebi, Shahrokh ^[1]; Valencia, Christian W. ^[1]; Israel, Hannah S. ^[1]; Fujimoto, Mai ^[1]; Wray, L. Andrew ^[3]; Chuang, Yi-De ^[2];

^[2]; Wessells, Colin D. ^[1]

Alveo Energy, Palo Alto, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
New York Univ., New York, NY (United States). Dept. of Physics

The demand of sustainable power supply requires high-performance cost-effective energy storage technologies. Here in this paperwe report a high-rate long-life low-cost sodium-ion battery full-cell system by innovating both the anode and the electrolyte. The redox couple of manganese(I/II) in Prussian blue analogs enables a high-rate and stable anode. Soft X-ray absorption spectroscopy and resonant inelastic X-ray scattering provide direct evidence suggesting the existence of monovalent manganese in the charged anode. There is a strong hybridization between cyano ligands and manganese-3d states, which benefits the electronic property for improving rate performance. Additionally, we employ an organic-aqueous cosolvent electrolyte to solve the long-standing solubility issue of Prussian blue analogs. A full-cell sodium-ion battery with low-cost Prussian blue analogs in both electrodes and co-solvent electrolyte retains 95% of its initial discharge capacity after 1000 cycles at 1C and 9 5% depth of discharge. The revealed manganese(I/II) redox couple inspires conceptual innovations of batteries based on atypical oxidation states.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC02-05CH11231; AR00000300; DMR-1420073

OSTI ID:: 1433131

Journal Information:: Nature Communications, Vol. 9, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 77 works

Citation information provided by
Web of Science

References (36)

LAPACK Users' Guide Anderson, E.; Bai, Z.; Bischof, C. https://doi.org/10.1137/1.9780898719604	software	January 1999
Fast disproportionation of hexacyanomanganate(III) in acidic solution. Formation of hexacyanomanganate(IV) and kinetics of its decomposition López-Cueto, Guillermo; Ubide, Carlos Canadian Journal of Chemistry, Vol. 64, Issue 12, p. 2301-2304 https://doi.org/10.1139/v86-377	journal	December 1986
Rhombohedral Prussian White as Cathode for Rechargeable Sodium-Ion Batteries Wang, Long; Song, Jie; Qiao, Ruimin Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja510347s	journal	February 2015
Switching Redox-Active Sites by Valence Tautomerism in Prussian Blue Analogues A_xMn_y[Fe(CN)₆]·nH₂O (A: K, Rb): Robust Frameworks for Reversible Li Storage Okubo, M.; Asakura, D.; Mizuno, Y. The Journal of Physical Chemistry Letters, Vol. 1, Issue 14, p. 2063-2071 https://doi.org/10.1021/jz100708b	journal	June 2010
Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides Qiao, Ruimin; Chin, Timothy; Harris, Stephen J. Current Applied Physics, Vol. 13, Issue 3 https://doi.org/10.1016/j.cap.2012.09.017	journal	May 2013
Über einwertiges Mangan (II. Mitteil.) Manchot, W.; Gall, H. Berichte der deutschen chemischen Gesellschaft (A and B Series), Vol. 61, Issue 5 https://doi.org/10.1002/cber.19280610541	journal	May 1928
Highly Reversible Open Framework Nanoscale Electrodes for Divalent Ion Batteries Wang, Richard Y.; Wessells, Colin D.; Huggins, Robert A. Nano Letters, Vol. 13, Issue 11 https://doi.org/10.1021/nl403669a	journal	October 2013
Non-Prussian Blue Structures and Magnetic Ordering of Na ₂ Mn ^II [Mn ^II (CN) ₆ ] and Na ₂ Mn ^II [Mn ^II (CN) ₆ ]·2H ₂ O Kareis, Christopher M.; Lapidus, Saul H.; Her, Jae-Hyuk Journal of the American Chemical Society, Vol. 134, Issue 4 https://doi.org/10.1021/ja209799y	journal	January 2012
Direct evidence of gradient Mn(II) evolution at charged states in LiNi0.5Mn1.5O4 electrodes with capacity fading Qiao, Ruimin; Wang, Yuesheng; Olalde-Velasco, Paul Journal of Power Sources, Vol. 273 https://doi.org/10.1016/j.jpowsour.2014.10.013	journal	January 2015
Electrochemical Energy Storage for Green Grid Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W. Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613 https://doi.org/10.1021/cr100290v	journal	May 2011
Full open-framework batteries for stationary energy storage Pasta, Mauro; Wessells, Colin D.; Liu, Nian Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4007	journal	January 2014
Resonant inelastic x-ray scattering studies of elementary excitations Ament, Luuk J. P.; van Veenendaal, Michel; Devereaux, Thomas P. Reviews of Modern Physics, Vol. 83, Issue 2 https://doi.org/10.1103/RevModPhys.83.705	journal	June 2011
Resonant inelastic x-ray scattering of $MnO$ : $L_{2, 3}$ edge measurements and assessment of their interpretation Ghiringhelli, G.; Matsubara, M.; Dallera, C. Physical Review B, Vol. 73, Issue 3 https://doi.org/10.1103/PhysRevB.73.035111	journal	January 2006
Revealing and suppressing surface Mn(II) formation of Na0.44MnO2 electrodes for Na-ion batteries Qiao, Ruimin; Dai, Kehua; Mao, Jing Nano Energy, Vol. 16 https://doi.org/10.1016/j.nanoen.2015.06.024	journal	September 2015
Electron delocalization in cyanide-bridged coordination polymer electrodes for Li-ion batteries studied by soft x-ray absorption spectroscopy Asakura, Daisuke; Okubo, Masashi; Mizuno, Yoshifumi Physical Review B, Vol. 84, Issue 4 https://doi.org/10.1103/PhysRevB.84.045117	journal	July 2011
2 p x-ray absorption of 3 d transition-metal compounds: An atomic multiplet description including the crystal field de Groot, F. M. F.; Fuggle, J. C.; Thole, B. T. Physical Review B, Vol. 42, Issue 9 https://doi.org/10.1103/PhysRevB.42.5459	journal	September 1990
Modular soft x-ray spectrometer for applications in energy sciences and quantum materials Chuang, Yi-De; Shao, Yu-Cheng; Cruz, Alejandro Review of Scientific Instruments, Vol. 88, Issue 1 https://doi.org/10.1063/1.4974356	journal	January 2017
Prussian blue: a new framework of electrode materials for sodium batteries Lu, Yuhao; Wang, Long; Cheng, Jinguang Chemical Communications, Vol. 48, Issue 52, p. 6544-6546 https://doi.org/10.1039/c2cc31777j	journal	January 2012
Manganese–cobalt hexacyanoferrate cathodes for sodium-ion batteries Pasta, Mauro; Wang, Richard Y.; Ruffo, Riccardo Journal of Materials Chemistry A, Vol. 4, Issue 11 https://doi.org/10.1039/C5TA10571D	journal	January 2016
Electrical Energy Storage for the Grid: A Battery of Choices Dunn, B.; Kamath, H.; Tarascon, J. -M. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212741	journal	November 2011
Core Level Spectroscopy of Solids de Groot, Frank; Kotani, Akio CRC Press https://doi.org/10.1201/9781420008425	book	January 2008
Cost comparison of producing high-performance Li-ion batteries in the U.S. and in China Brodd, Ralph J.; Helou, Carlos Journal of Power Sources, Vol. 231 https://doi.org/10.1016/j.jpowsour.2012.12.048	journal	June 2013
Cyanide complexes of the early transition metals (groups IVa-VIIa) Griffith, W. P. Coordination Chemistry Reviews, Vol. 17, Issue 2-3, p. 177-247 https://doi.org/10.1016/S0010-8545(00)80303-3	journal	November 1975
Chemical Bonding in Aqueous Ferrocyanide: Experimental and Theoretical X-ray Spectroscopic Study Engel, Nicholas; Bokarev, Sergey I.; Suljoti, Edlira The Journal of Physical Chemistry B, Vol. 118, Issue 6 https://doi.org/10.1021/jp411782y	journal	January 2014
Recent Progress in Aqueous Lithium-Ion Batteries Wang, Yonggang; Yi, Jin; Xia, Yongyao Advanced Energy Materials, Vol. 2, Issue 7 https://doi.org/10.1002/aenm.201200065	journal	June 2012
Fe L-Edge XAS Studies of K ₄ [Fe(CN) ₆ ] and K ₃ [Fe(CN) ₆ ]: A Direct Probe of Back-Bonding Hocking, Rosalie K.; Wasinger, Erik C.; de Groot, Frank M. F. Journal of the American Chemical Society, Vol. 128, Issue 32 https://doi.org/10.1021/ja061802i	journal	August 2006
High-efficiency in situ resonant inelastic x-ray scattering (iRIXS) endstation at the Advanced Light Source Qiao, Ruimin; Li, Qinghao; Zhuo, Zengqing Review of Scientific Instruments, Vol. 88, Issue 3 https://doi.org/10.1063/1.4977592	journal	March 2017
Copper hexacyanoferrate battery electrodes with long cycle life and high power Wessells, Colin D.; Huggins, Robert A.; Cui, Yi Nature Communications, Vol. 2, Article No. 550 https://doi.org/10.1038/ncomms1563	journal	November 2011
A Polyionic, Large-Format Energy Storage Device Using an Aqueous Electrolyte and Thick-Format Composite NaTi ₂ (PO ₄ ) ₃ /Activated Carbon Negative Electrodes Whitacre, J. F.; Shanbhag, S.; Mohamed, A. Energy Technology, Vol. 3, Issue 1 https://doi.org/10.1002/ente.201402127	journal	November 2014
Quantitative probe of the transition metal redox in battery electrodes through soft x-ray absorption spectroscopy Li, Qinghao; Qiao, Ruimin; Wray, L. Andrew Journal of Physics D: Applied Physics, Vol. 49, Issue 41 https://doi.org/10.1088/0022-3727/49/41/413003	journal	September 2016
Key electronic states in lithium battery materials probed by soft X-ray spectroscopy Yang, Wanli; Liu, Xiaosong; Qiao, Ruimin Journal of Electron Spectroscopy and Related Phenomena, Vol. 190 https://doi.org/10.1016/j.elspec.2013.03.008	journal	October 2013
Fabrication of a Cyanide-Bridged Coordination Polymer Electrode for Enhanced Electrochemical Ion Storage Ability Asakura, Daisuke; Okubo, Masashi; Mizuno, Yoshifumi The Journal of Physical Chemistry C, Vol. 116, Issue 15, p. 8364-8369 https://doi.org/10.1021/jp2118949	journal	April 2012
Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries Wang, Yuesheng; Liu, Jue; Lee, Byungju Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7401	journal	March 2015
Manganese hexacyanomanganate open framework as a high-capacity positive electrode material for sodium-ion batteries Lee, Hyun-Wook; Wang, Richard Y.; Pasta, Mauro Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6280	journal	October 2014
Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides Qiao, Ruimin; Chin, Timothy; Harris, Stephen J. arXiv https://doi.org/10.48550/arxiv.1208.6319	text	January 2012
Chemical Bonding in Aqueous Ferrocyanide: Experimental and Theoretical X-ray Spectroscopic Study Engel, Nicholas; Bokarev, Sergey I.; Suljoti, Edlira arXiv https://doi.org/10.48550/arxiv.1312.0236	preprint	January 2013

Cited By (11)

Prussian White Hierarchical Nanotubes with Surface‐Controlled Charge Storage for Sodium‐Ion Batteries Ren, Wenhao; Zhu, Zixuan; Qin, Mingsheng Advanced Functional Materials, Vol. 29, Issue 15 https://doi.org/10.1002/adfm.201806405	journal	February 2019
Few‐Layer Bismuthene with Anisotropic Expansion for High‐Areal‐Capacity Sodium‐Ion Batteries Zhou, Jing; Chen, Jiangchun; Chen, Mengxue Advanced Materials, Vol. 31, Issue 12 https://doi.org/10.1002/adma.201807874	journal	January 2019
Electrolytes and Electrolyte/Electrode Interfaces in Sodium‐Ion Batteries: From Scientific Research to Practical Application Huang, Yongxin; Zhao, Luzi; Li, Li Advanced Materials, Vol. 31, Issue 21 https://doi.org/10.1002/adma.201808393	journal	March 2019
Understanding Challenges of Cathode Materials for Sodium‐Ion Batteries using Synchrotron‐Based X‐Ray Absorption Spectroscopy Chen, Mingzhe; Chou, Shu‐Lei; Dou, Shi‐Xue Batteries & Supercaps, Vol. 2, Issue 10 https://doi.org/10.1002/batt.201900054	journal	July 2019
Recent research progresses in ether‐ and ester‐based electrolytes for sodium‐ion batteries Lin, Zeheng; Xia, Qingbing; Wang, Wanlin InfoMat, Vol. 1, Issue 3 https://doi.org/10.1002/inf2.12023	journal	July 2019
Ball-milling synthesis of ultrafine NayFexMn1-x[Fe(CN)6] as high-performance cathode in sodium-ion batteries Gong, Wenzhe; Zeng, Rui; Su, Shang Journal of Nanoparticle Research, Vol. 21, Issue 12 https://doi.org/10.1007/s11051-019-4717-9	journal	December 2019
Ni _1.5 CoSe ₅ nanocubes embedded in 3D dual N-doped carbon network as advanced anode material in sodium-ion full cells with superior low-temperature and high-power properties Wang, Ying-Ying; Fan, Haosen; Hou, Bao-Hua Journal of Materials Chemistry A, Vol. 6, Issue 45 https://doi.org/10.1039/c8ta09264h	journal	January 2018
A room temperature multivalent rechargeable iron ion battery with an ether based electrolyte: a new type of post-lithium ion battery Vijaya Kumar Saroja, Ajay Piriya; Samantaray, Sai Smruti; Sundara, Ramaprabhu Chemical Communications, Vol. 55, Issue 70 https://doi.org/10.1039/c9cc04610k	journal	January 2019
X-ray spectroscopy with variable line spacing based on reflection zone plate optics Yin, Zhong; Löchel, Heike; Rehanek, Jens Optics Letters, Vol. 43, Issue 18 https://doi.org/10.1364/ol.43.004390	journal	January 2018
Fingerprint Oxygen Redox Reactions in Batteries through High-Efficiency Mapping of Resonant Inelastic X-ray Scattering Wu, Jinpeng; Li, Qinghao; Sallis, Shawn Condensed Matter, Vol. 4, Issue 1 https://doi.org/10.3390/condmat4010005	journal	January 2019
X-ray spectroscopy with variable line spacing based on reflection zone plate optics Yin, Zhong; Löchel, Heike; Rehanek, Jens Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2018-03414	text	January 2018

Similar Records

Size‐, Water‐, and Defect‐Regulated Potassium Manganese Hexacyanoferrate with Superior Cycling Stability and Rate Capability for Low‐Cost Sodium‐Ion Batteries

Journal Article · Fri Aug 30 00:00:00 EDT 2019 · Small · OSTI ID:1433131

Zhou, Aijun; Xu, Zemin; Gao, Hongcai; +3 more

Ball Milling-Enabled Fe^2.4+ to Fe³⁺ Redox Reaction in Prussian Blue Materials for Long-Life Aqueous Sodium-Ion Batteries

Journal Article · Sun Jul 23 00:00:00 EDT 2023 · ACS Applied Materials and Interfaces · OSTI ID:1433131

Lucero, Marcos; Armitage, Davis B.; Yang, Xin; +9 more

The Role of Transition Metals on Chemo-Mechanical Instabilities in Prussian Blue Analogues For K-Ion Batteries: The Case Study on KNHCF Versus KMHCF

Journal Article · Mon Jul 24 00:00:00 EDT 2023 · Advanced Energy Materials · OSTI ID:1433131

Li, Zheng; Ozdogru, Bertan; Bal, Batuhan; +7 more

Related Subjects

25 ENERGY STORAGE

Title: Monovalent manganese based anodes and co-solvent electrolyte for stable low-cost high-rate sodium-ion batteries

Citation Formats

References (36)

Cited By (11)

Similar Records

Related Subjects