Effect of nanopatterning on mechanical properties of Lithium anode

Campbell, Colin; Lee, Yong Min; Cho, Kuk Young; Lee, Young-Gi; Lee, Byeongdu; Phatak, Charudatta; Hong, Seungbum

doi:10.1038/s41598-018-20773-8

Title: Effect of nanopatterning on mechanical properties of Lithium anode

Journal Article · Tue Feb 06 00:00:00 EST 2018 · Scientific Reports

DOI:https://doi.org/10.1038/s41598-018-20773-8· OSTI ID:1425265

Campbell, Colin ^[1]; Lee, Yong Min ^[2];

^[3]; Lee, Young-Gi ^[4];

^[5];

^[6];

^[7]

Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division; Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering
Daegu Gyeongbuk Inst. of Science and Technology (DGIST), Daegu (Korea). Dept. of Energy Science and Engineering
Hanyang Univ., Ansan (Korea, Republic of). Dept. of Materials Science and Chemical Engineering
ICT Materials and Components Research Lab., ETRI (Korea)
Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Korea Advanced Inst. Science and Technology (KAIST), Daejeon (Korea, Republic of). Dept. of Materials Science and Engineering

One of the challenges in developing Lithium anodes for Lithium ion batteries (LIB) is controlling the formation of Li dendrites during cycling of the battery. Nanostructuring and nanopatterning of electrodes shows a promising way to suppress the growth of Li dendrites. However, in order to control this behavior, a fundamental understanding of the effect of nanopatterning on the electromechanical properties of Li metal is necessary. In this paper, we have investigated the mechanical and wear properties of Li metal using Atomic Force Microscopy (AFM) in an airtight cell. By using different load regimes, we determined the mechanical properties of Li metal. Here, we show that as a result of nanopatterning, Li metal surface underwent work hardening due to residual compressive stress. The presence of such stresses can help to improve cycle lifetime of LIBs with Li anodes and obtain very high energy densities.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Korea Institute of Energy Technology Evaluation and Planning (KETEP); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1425265

Journal Information:: Scientific Reports, Vol. 8, Issue 1; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 29 works

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Impedance Spectroscopic Investigation of the Impact of Erroneous Cell Assembly on the Aging of Lithium‐Ion Batteries Heins, Tom Patrick; Leithoff, Ruben; Schlüter, Nicolas Energy Technology, Vol. 8, Issue 2 https://doi.org/10.1002/ente.201900288	journal	May 2019
Lithium Mechanics: Roles of Strain Rate and Temperature and Implications for Lithium Metal Batteries LePage, William S.; Chen, Yuxin; Kazyak, Eric Journal of The Electrochemical Society, Vol. 166, Issue 2 https://doi.org/10.1149/2.0221902jes	journal	January 2019
High Dielectric, Robust Composite Protective Layer for Dendrite‐Free and LiPF ₆ Degradation‐Free Lithium Metal Anode Jang, Eun Kwang; Ahn, Jinhyeok; Yoon, Sukeun Advanced Functional Materials, Vol. 29, Issue 48 https://doi.org/10.1002/adfm.201905078	journal	September 2019

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