Bromine substitution improves excited-state dynamics in mesoporous mixed halide perovskite films

Talbert, Eric M.; Zarick, Holly F.; Boulesbaa, Abdelaziz; Soetan, Naiya; Puretzky, Alexander A.; Geohegan, David B.; Bardhan, Rizia

doi:10.1039/c7nr04267a

Title: Bromine substitution improves excited-state dynamics in mesoporous mixed halide perovskite films

Journal Article · Wed Aug 02 00:00:00 EDT 2017 · Nanoscale

DOI:https://doi.org/10.1039/c7nr04267a· OSTI ID:1423098

Talbert, Eric M. ^[1]; Zarick, Holly F. ^[1];

^[2]; Soetan, Naiya ^[1];

^[2];

^[1]

Vanderbilt Univ., Nashville, TN (United States). Dept. of Chemical and Biomolecular Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)

Here in this study, ultrafast transient absorption spectroscopy (TAS) is utilized to examine the excited-state dynamics in methylammonium lead iodide/bromide (MAPb(I_1-xBrx)3) perovskites as a function of bromide content. TAS spectral behavior reveals characteristic lifetimes for thermalization, recombination, and charge carrier injection of MAPb(I_1-xBr_x)₃ from x = 0 to 0.3 infiltrated in mesoporous titania films. Carrier recombination and charge injection lifetimes demonstrated a discernable increase with Br content likely because high carrier populations are supported by the higher density of vacant electronic states in mixed-halide perovskites due to the increased capacity of the conduction band. However, we observe for the first time that carrier thermalization lifetimes significantly decrease with increasing Br. This suggests that the shift in crystal structure from tetragonal towards pseudocubic accelerates carrier cooling, resulting in the relief of the hot phonon bottleneck. Furthermore, the stabilized MAPb(I_1-xBrx)₃ samples exhibit a lower Burstein–Moss shift of 0.07–0.08 eV compared to pure MAPbI₃ (0.12 eV). Our results provide evidence that Br inclusion contributes to a broadening of the parabolic conduction band and to improvement in electron–phonon coupling and phonon propagation in the lattice.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725; P0200A090323

OSTI ID:: 1423098

Journal Information:: Nanoscale, Vol. 9, Issue 33; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 19 works

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