The importance of Rydberg orbitals in dissociative ionization of small hydrocarbon molecules in intense laser fields

Jochim, Bethany; Siemering, R.; Zohrabi, M.; Voznyuk, O.; Mahowald, J. B.; Schmitz, D. G.; Betsch, K. J.; Berry, Ben; Severt, T.; Kling, Nora G.; Burwitz, T. G.; Carnes, K. D.; Kling, M. F.; Ben-Itzhak, I.; Wells, E.; de Vivie-Riedle, R.

doi:10.1038/s41598-017-04638-0

Title: The importance of Rydberg orbitals in dissociative ionization of small hydrocarbon molecules in intense laser fields

Journal Article · Fri Jun 30 00:00:00 EDT 2017 · Scientific Reports

DOI:https://doi.org/10.1038/s41598-017-04638-0· OSTI ID:1418580

Jochim, Bethany ^[1]; Siemering, R. ^[2]; Zohrabi, M. ^[1]; Voznyuk, O. ^[3]; Mahowald, J. B. ^[3]; Schmitz, D. G. ^[3]; Betsch, K. J. ^[1]; Berry, Ben ^[1]; Severt, T. ^[1]; Kling, Nora G. ^[4]; Burwitz, T. G. ^[3]; Carnes, K. D. ^[1]; Kling, M. F. ^[4]; Ben-Itzhak, I. ^[1]; Wells, E. ^[3]; de Vivie-Riedle, R. ^[2]

Kansas State Univ., Manhattan, KS (United States). J.R. Macdonald Lab. and Dept. of Physics
Ludwig Maximilian Univ., Munich (Germany). Dept. of Chemistry
Augustana College, Sioux Falls, SD (United States). Dept. of Physics
Kansas State Univ., Manhattan, KS (United States). J.R. Macdonald Lab. and Dept. of Physics; Ludwig Maximilian Univ., Munich (Germany). Dept. of Physics

Much of our intuition about strong-field processes is built upon studies of diatomic molecules, which typically have electronic states that are relatively well separated in energy. In polyatomic molecules, however, the electronic states are closer together, leading to more complex interactions. A combined experimental and theoretical investigation of strong-field ionization followed by hydrogen elimination in the hydrocarbon series C₂D₂, C₂D₄ and C₂D₆ reveals that the photofragment angular distributions can only be understood when the field-dressed orbitals rather than the field-free orbitals are considered. Our measured angular distributions and intensity dependence show that these field-dressed orbitals can have strong Rydberg character for certain orientations of the molecule relative to the laser polarization and that they may contribute significantly to the hydrogen elimination dissociative ionization yield. Thus, these findings suggest that Rydberg contributions to field-dressed orbitals should be routinely considered when studying polyatomic molecules in intense laser fields.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Kansas State Univ., Manhattan, KS (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; Oak Ridge Institute for Science and Education (ORISE), Oak Ridge, TN (United States); National Science Foundation (NSF); German Science Foundation (DFG)

Grant/Contract Number:: FG02-09ER16115; SC0002378

OSTI ID:: 1418580

Journal Information:: Scientific Reports, Vol. 7, Issue 1; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 9 works

Citation information provided by
Web of Science

References (96)

High Harmonic Generation from Multiple Orbitals in N2 McFarland, B. K.; Farrell, J. P.; Bucksbaum, P. H. Science, Vol. 322, Issue 5905 https://doi.org/10.1126/science.1162780	journal	November 2008
Strong-field control and spectroscopy of attosecond electron-hole dynamics in molecules Smirnova, O.; Patchkovskii, S.; Mairesse, Y. Proceedings of the National Academy of Sciences, Vol. 106, Issue 39 https://doi.org/10.1073/pnas.0907434106	journal	September 2009
Concerted quantum effects of electronic and nuclear fluxes in molecules Barth, Ingo; Hege, Hans-Christian; Ikeda, Hiroshi Chemical Physics Letters, Vol. 481, Issue 1-3 https://doi.org/10.1016/j.cplett.2009.09.011	journal	October 2009
Attosecond Science Corkum, P. B. Springer Series in Optical Sciences https://doi.org/10.1007/978-3-642-37623-8_1	book	January 2013
Control and femtosecond time-resolved imaging of torsion in a chiral molecule Hansen, Jonas L.; Nielsen, Jens H.; Madsen, Christian Bruun The Journal of Chemical Physics, Vol. 136, Issue 20 https://doi.org/10.1063/1.4719816	journal	May 2012
Theory of Tunnel Ionization in Complex Systems Brabec, Thomas; Côté, Michel; Boulanger, Paul Physical Review Letters, Vol. 95, Issue 7 https://doi.org/10.1103/physrevlett.95.073001	journal	August 2005
Dyson orbitals for ionization from the ground and electronically excited states within equation-of-motion coupled-cluster formalism: Theory, implementation, and examples Melania Oana, C.; Krylov, Anna I. The Journal of Chemical Physics, Vol. 127, Issue 23 https://doi.org/10.1063/1.2805393	journal	December 2007
Effects of multi orbital contributions in the angular-dependent ionization of molecules in intense few-cycle laser pulses von den Hoff, P.; Znakovskaya, I.; Zherebtsov, S. Applied Physics B, Vol. 98, Issue 4 https://doi.org/10.1007/s00340-009-3860-x	journal	December 2009
Duration of an intense laser pulse can determine the breakage of multiple chemical bonds Xie, Xinhua; Lötstedt, Erik; Roither, Stefan Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep12877	journal	August 2015
Subfemtosecond steering of hydrocarbon deprotonation through superposition of vibrational modes Alnaser, A. S.; Kübel, M.; Siemering, R. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4800	journal	May 2014
Incorporating real time velocity map image reconstruction into closed-loop coherent control Rallis, C. E.; Burwitz, T. G.; Andrews, P. R. Review of Scientific Instruments, Vol. 85, Issue 11 https://doi.org/10.1063/1.4899267	journal	November 2014
Ultrafast Extreme Ultraviolet Induced Isomerization of Acetylene Cations Jiang, Y. H.; Rudenko, A.; Herrwerth, O. Physical Review Letters, Vol. 105, Issue 26 https://doi.org/10.1103/PhysRevLett.105.263002	journal	December 2010
Control of Electron Localization in Molecular Dissociation Kling, M. F. Science, Vol. 312, Issue 5771 https://doi.org/10.1126/science.1126259	journal	April 2006
Imaging ultrafast molecular dynamics with laser-induced electron diffraction Blaga, Cosmin I.; Xu, Junliang; DiChiara, Anthony D. Nature, Vol. 483, Issue 7388 https://doi.org/10.1038/nature10820	journal	March 2012
Strong Field Ionization to Multiple Electronic States in Water Farrell, Joseph P.; Petretti, Simon; Förster, Johann Physical Review Letters, Vol. 107, Issue 8 https://doi.org/10.1103/PhysRevLett.107.083001	journal	August 2011
Fundamentals of Photonics Saleh, Bahaa E. A.; Teich, Malvin Carl John Wiley & Sons, Inc https://doi.org/10.1002/0471213748	book	January 1991
Single-shot carrier–envelope phase measurement of few-cycle laser pulses Wittmann, T.; Horvath, B.; Helml, W. Nature Physics, Vol. 5, Issue 5 https://doi.org/10.1038/nphys1250	journal	April 2009
Strong field ionization to multiple electronic states in water Farrell, Joe P.; Petretti, Simon; Förster, Johann arXiv https://doi.org/10.48550/arxiv.1103.4423	text	January 2011
Nonadiabatic Multielectron Dynamics in Strong Field Molecular Ionization Lezius, M.; Blanchet, V.; Rayner, D. M. Physical Review Letters, Vol. 86, Issue 1 https://doi.org/10.1103/PhysRevLett.86.51	journal	January 2001
Attosecond control of electron dynamics in carbon monoxide Znakovskaya, I.; Hoff, P. von den; Zherebtsov, S. arXiv https://doi.org/10.48550/arxiv.0906.1175	text	January 2009
Suppressed tunnelling ionization of the molecule in an intense Ti:sapphire laser pulse Talebpour, A.; Larochelle, S.; Chin, S. L. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 31, Issue 2 https://doi.org/10.1088/0953-4075/31/2/003	journal	January 1998
Pump and Probe of Ultrafast Charge Reorganization in Small Peptides: A Computational Study through Sudden Ionizations Kuś, T.; Mignolet, B.; Levine, R. D. The Journal of Physical Chemistry A, Vol. 117, Issue 40 https://doi.org/10.1021/jp407295t	journal	September 2013
Photoelectron imaging spectrometry: Principle and inversion method Bordas, C.; Paulig, F.; Helm, H. Review of Scientific Instruments, Vol. 67, Issue 6 https://doi.org/10.1063/1.1147044	journal	June 1996
Migration of holes: Formalism, mechanisms, and illustrative applications Breidbach, J.; Cederbaum, L. S. The Journal of Chemical Physics, Vol. 118, Issue 9 https://doi.org/10.1063/1.1540618	journal	March 2003
Multiorbital Tunneling Ionization of the CO Molecule Wu, J.; Schmidt, L. Ph. H.; Kunitski, M. Physical Review Letters, Vol. 108, Issue 18 https://doi.org/10.1103/PhysRevLett.108.183001	journal	April 2012
An electronic time scale in chemistry Remacle, F.; Levine, R. D. Proceedings of the National Academy of Sciences, Vol. 103, Issue 18 https://doi.org/10.1073/pnas.0601855103	journal	April 2006
A framework for understanding molecular ionization in strong laser fields Menon, Saipriya V.; Nibarger, John P.; Gibson, George N. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 35, Issue 13 https://doi.org/10.1088/0953-4075/35/13/309	journal	June 2002
Polyatomic molecules in strong laser fields: Nonadiabatic multielectron dynamics Lezius, M.; Blanchet, V.; Ivanov, Misha Yu. The Journal of Chemical Physics, Vol. 117, Issue 4 https://doi.org/10.1063/1.1487823	journal	July 2002
Rings in above-threshold ionization: A quasiclassical analysis Lewenstein, M.; Kulander, K. C.; Schafer, K. J. Physical Review A, Vol. 51, Issue 2 https://doi.org/10.1103/PhysRevA.51.1495	journal	February 1995
Effect of an intense electromagnetic field on a weakly bound system Reiss, Howard R. Physical Review A, Vol. 22, Issue 5 https://doi.org/10.1103/PhysRevA.22.1786	journal	November 1980
Multichannel coherence in strong-field ionization Rohringer, Nina; Santra, Robin Physical Review A, Vol. 79, Issue 5 https://doi.org/10.1103/PhysRevA.79.053402	journal	May 2009
Multiple absorption of laser photons by atoms Faisal, F. H. M. Journal of Physics B: Atomic and Molecular Physics, Vol. 6, Issue 4 https://doi.org/10.1088/0022-3700/6/4/011	journal	April 1973
The Role of Super-Atom Molecular Orbitals in Doped Fullerenes in a Femtosecond Intense Laser Field Berrah, N.; Xiong, H.; Mignolet, B. Journal of Physics: Conference Series, Vol. 875 https://doi.org/10.1088/1742-6596/875/4/032017	journal	July 2017
Creation of multihole molecular wave packets via strong-field ionization Geißler, Dominik; Rozgonyi, Tamás; González-Vázquez, Jesús Physical Review A, Vol. 82, Issue 1 https://doi.org/10.1103/PhysRevA.82.011402	journal	July 2010
Visualizing electron rearrangement in space and time during the transition from a molecule to atoms Li, W.; Jaron-Becker, A. A.; Hogle, C. W. Proceedings of the National Academy of Sciences, Vol. 107, Issue 47 https://doi.org/10.1073/pnas.1014723107	journal	November 2010
Strong-field rescattering physics—self-imaging of a molecule by its own electrons Lin, C. D.; Le, Anh-Thu; Chen, Zhangjin Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 43, Issue 12 https://doi.org/10.1088/0953-4075/43/12/122001	journal	June 2010
Dynamic Exchange in the Strong Field Ionization of Molecules Majety, Vinay Pramod; Scrinzi, Armin Physical Review Letters, Vol. 115, Issue 10 https://doi.org/10.1103/PhysRevLett.115.103002	journal	September 2015
Neutral-Ionic State Correlations in Strong-Field Molecular Ionization Kotur, Marija; Zhou, Congyi; Matsika, Spiridoula Physical Review Letters, Vol. 109, Issue 20 https://doi.org/10.1103/physrevlett.109.203007	journal	November 2012
Coulomb corrections and polarization effects in high-intensity high-harmonic emission Ivanov, Misha Yu.; Brabec, Thomas; Burnett, Neal Physical Review A, Vol. 54, Issue 1 https://doi.org/10.1103/PhysRevA.54.742	journal	July 1996
Angular Tunneling Ionization Probability of Fixed-in-Space $H_{2}$ Molecules in Intense Laser Pulses Staudte, A.; Patchkovskii, S.; Pavičić, D. Physical Review Letters, Vol. 102, Issue 3 https://doi.org/10.1103/PhysRevLett.102.033004	journal	January 2009
Multiorbital tunneling ionization of the CO molecule Wu, J.; Schmidt, L. Ph. H.; Kunitski, M. arXiv https://doi.org/10.48550/arxiv.1203.3119	text	January 2012
Adaptive strong-field control of chemical dynamics guided by three-dimensional momentum imaging Wells, E.; Rallis, C. E.; Zohrabi, M. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3895	journal	December 2013
Strong-field ionization dynamics of a model $H_{2}$ molecule Lein, Manfred; Kreibich, Thomas; Gross, E. K. U. Physical Review A, Vol. 65, Issue 3 https://doi.org/10.1103/PhysRevA.65.033403	journal	February 2002
Sub-laser-cycle electron pulses for probing molecular dynamics Niikura, Hiromichi; Légaré, F.; Hasbani, R. Nature, Vol. 417, Issue 6892 https://doi.org/10.1038/nature00787	journal	June 2002
Real-time observation of valence electron motion Goulielmakis, Eleftherios; Loh, Zhi-Heng; Wirth, Adrian Nature, Vol. 466, Issue 7307 https://doi.org/10.1038/nature09212	journal	August 2010
10th anniversary of attosecond pulses Kienberger, Reinhard; Chang, Zenghu; Nam, Chang Hee Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 45, Issue 7 https://doi.org/10.1088/0953-4075/45/7/070201	journal	March 2012
Review of attosecond resolved measurement and control via carrier–envelope phase tagging with above-threshold ionization Rathje, T.; Johnson, Nora G.; Möller, M. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 45, Issue 7 https://doi.org/10.1088/0953-4075/45/7/074003	journal	March 2012
Glory scattering in deeply inelastic molecular collisions Besemer, Matthieu; Tang, Guoqiang; Gao, Zhi Nature Chemistry, Vol. 14, Issue 6 https://doi.org/10.1038/s41557-022-00907-2	journal	March 2022
Electron-Nuclear Energy Sharing in Above-Threshold Multiphoton Dissociative Ionization of $H_{2}$ Wu, J.; Kunitski, M.; Pitzer, M. Physical Review Letters, Vol. 111, Issue 2 https://doi.org/10.1103/PhysRevLett.111.023002	journal	July 2013
Probing Proton Dynamics in Molecules on an Attosecond Time Scale Baker, S.; Robinson, J. S.; Haworth, C. A. Science, Vol. 312, Issue 5772 https://doi.org/10.1126/science.1123904	journal	March 2006
Strong Field Molecular Ionization in the Impulsive Limit: Freezing Vibrations with Short Pulses Sándor, Péter; Tagliamonti, Vincent; Zhao, Arthur Physical Review Letters, Vol. 116, Issue 6 https://doi.org/10.1103/PhysRevLett.116.063002	journal	February 2016
Attosecond control of electronic processes by intense light fields Baltuška, A.; Udem, Th.; Uiberacker, M. Nature, Vol. 421, Issue 6923, p. 611-615 https://doi.org/10.1038/nature01414	journal	February 2003
Above-threshold ionization with subpicosecond laser pulses Freeman, R. R.; Bucksbaum, P. H.; Milchberg, H. Physical Review Letters, Vol. 59, Issue 10 https://doi.org/10.1103/PhysRevLett.59.1092	journal	September 1987
Following a chemical reaction using high-harmonic interferometry Wörner, H. J.; Bertrand, J. B.; Kartashov, D. V. Nature, Vol. 466, Issue 7306 https://doi.org/10.1038/nature09185	journal	July 2010
Controlling the Interference of Multiple Molecular Orbitals in High-Harmonic Generation Wörner, H. J.; Bertrand, J. B.; Hockett, P. Physical Review Letters, Vol. 104, Issue 23 https://doi.org/10.1103/PhysRevLett.104.233904	journal	June 2010
Tabletop imaging of structural evolutions in chemical reactions demonstrated for the acetylene cation Ibrahim, Heide; Wales, Benji; Beaulieu, Samuel Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5422	journal	July 2014
High harmonic interferometry of multi-electron dynamics in molecules Smirnova, Olga; Mairesse, Yann; Patchkovskii, Serguei Nature, Vol. 460, Issue 7258 https://doi.org/10.1038/nature08253	journal	July 2009
Attosecond tracing of correlated electron-emission in non-sequential double ionization Bergues, Boris; Kübel, Matthias; Johnson, Nora G. Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1807	journal	January 2012
Pulse-shape-dependent strong-field ionization viewed with velocity-map imaging Geißler, Dominik; Rozgonyi, Tamás; González-Vázquez, Jesús Physical Review A, Vol. 84, Issue 5 https://doi.org/10.1103/PhysRevA.84.053422	journal	November 2011
Strong field molecular ionization to multiple ionic states: direct versus indirect pathways Sándor, Péter; Zhao, Arthur; Rozgonyi, Tamás Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 47, Issue 12 https://doi.org/10.1088/0953-4075/47/12/124021	journal	June 2014
The physics of attosecond light pulses Agostini, Pierre; DiMauro, Louis F. Reports on Progress in Physics, Vol. 67, Issue 6 https://doi.org/10.1088/0034-4885/67/6/R01	journal	May 2004
Carrier-envelope-phase dependence of asymmetric C D bond breaking in C2D2 in an intense few-cycle laser field Miura, Shun; Ando, Toshiaki; Ootaka, Kazuki Chemical Physics Letters, Vol. 595-596 https://doi.org/10.1016/j.cplett.2014.01.045	journal	March 2014
Ratiometric Comparison of Intense Field Ionization of Atoms and Diatomic Molecules DeWitt, Merrick J.; Jones, R. R.; Wells, E. The American Physical Society https://doi.org/10.17877/de290r-4190	text	January 2001
Molecular imaging using recolliding electrons Lein, Manfred Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 40, Issue 16 https://doi.org/10.1088/0953-4075/40/16/R01	journal	August 2007
The effects of dissociative recombination in multiphoton ionization of Talebpour, A.; Chien, C-Y; Chin, S. L. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 29, Issue 18 https://doi.org/10.1088/0953-4075/29/18/002	journal	September 1996
Visualizing Electron Rearrangement in Space and Time during the Transition from a Molecule to Atoms Li, Wen; Jaroń-Becker, Agnieszka A.; Hogle, Craig W. International Conference on Ultrafast Phenomena https://doi.org/10.1364/up.2010.we2	conference	January 2010
Laser Tunnel Ionization from Multiple Orbitals in HCl Akagi, H.; Otobe, T.; Staudte, A. Science, Vol. 325, Issue 5946 https://doi.org/10.1126/science.1175253	journal	September 2009
Elusive enhanced ionization structure for $H_{2}^{+}$ in intense ultrashort laser pulses Ben-Itzhak, I.; Wang, P. Q.; Sayler, A. M. Physical Review A, Vol. 78, Issue 6 https://doi.org/10.1103/PhysRevA.78.063419	journal	December 2008
The Role of Super-Atom Molecular Orbitals in Doped Fullerenes in a Femtosecond Intense Laser Field Xiong, Hui; Mignolet, Benoit; Fang, Li Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-00124-9	journal	March 2017
Stereocontrol of attosecond time-scale electron dynamics in ABCU using ultrafast laser pulses: a computational study Mignolet, B.; Gijsbertsen, A.; Vrakking, M. J. J. Physical Chemistry Chemical Physics, Vol. 13, Issue 18 https://doi.org/10.1039/c1cp20094a	journal	January 2011
Strong-Field Molecular Ionization from Multiple Orbitals Kotur, Marija; Weinacht, Thomas C.; Zhou, Congyi Physical Review X, Vol. 1, Issue 2 https://doi.org/10.1103/PhysRevX.1.021010	journal	November 2011
Tomographic imaging of molecular orbitals Itatani, J.; Levesque, J.; Zeidler, D. Nature, Vol. 432, Issue 7019 https://doi.org/10.1038/nature03183	journal	December 2004
Time-Resolved Holography with Photoelectrons Huismans, Y.; Rouzee, A.; Gijsbertsen, A. Science, Vol. 331, Issue 6013 https://doi.org/10.1126/science.1198450	journal	December 2010
Ionization and dissociation of $H_{2}$ in intense laser fields at 1.064 μm, 532 nm, and 355 nm Zavriyev, A.; Bucksbaum, P. H.; Muller, H. G. Physical Review A, Vol. 42, Issue 9 https://doi.org/10.1103/PhysRevA.42.5500	journal	November 1990
Ratiometric Comparison of Intense Field Ionization of Atoms and Diatomic Molecules DeWitt, Merrick J.; Wells, E.; Jones, R. R. Physical Review Letters, Vol. 87, Issue 15 https://doi.org/10.1103/PhysRevLett.87.153001	journal	September 2001
Effects Of Molecular Structure on Ion Disintegration Patterns In Ionization of $O_{2}$ and $N_{2}$ by Short Laser Pulses Alnaser, A. S.; Voss, S.; Tong, X. -M. Physical Review Letters, Vol. 93, Issue 11 https://doi.org/10.1103/PhysRevLett.93.113003	journal	September 2004
Attosecond imaging of molecular electronic wavepackets Haessler, S.; Caillat, J.; Boutu, W. Nature Physics, Vol. 6, Issue 3 https://doi.org/10.1038/nphys1511	journal	January 2010
Selective Control over Fragmentation Reactions in Polyatomic Molecules Using Impulsive Laser Alignment Xie, Xinhua; Doblhoff-Dier, Katharina; Xu, Huailiang Physical Review Letters, Vol. 112, Issue 16 https://doi.org/10.1103/PhysRevLett.112.163003	journal	April 2014
Charge-resonance-enhanced ionization of diatomic molecular ions by intense lasers Zuo, T.; Bandrauk, A. D. Physical Review A, Vol. 52, Issue 4 https://doi.org/10.1103/PhysRevA.52.R2511	journal	October 1995
Double Ionization of Nitrogen from Multiple Orbitals Wu, Zhifeng; Wu, Chengyin; Liu, Xianrong The Journal of Physical Chemistry A, Vol. 114, Issue 25 https://doi.org/10.1021/jp1018197	journal	July 2010
Attosecond Electron Wave Packet Dynamics in Strong Laser Fields Johnsson, P.; López-Martens, R.; Kazamias, S. Physical Review Letters, Vol. 95, Issue 1 https://doi.org/10.1103/physrevlett.95.013001	journal	June 2005
Strong Field Molecular Ionization in the Impulsive Limit: Freezing Vibrations with Short Pulses Sándor, Péter; Tagliamonti, Vincent; Zhao, Arthur arXiv https://doi.org/10.48550/arxiv.1611.09142	text	January 2016
Theory of molecular tunneling ionization Tong, X. M.; Zhao, Z. X.; Lin, C. D. Physical Review A, Vol. 66, Issue 3 https://doi.org/10.1103/PhysRevA.66.033402	journal	September 2002
Time-Resolved Electron Diffraction from Selectively Aligned Molecules Reckenthaeler, Peter; Centurion, Martin; Fuß, Werner Physical Review Letters, Vol. 102, Issue 21 https://doi.org/10.1103/PhysRevLett.102.213001	journal	May 2009
Signatures of the continuum electron phase in molecular strong-field photoelectron holography Meckel, M.; Staudte, A.; Patchkovskii, S. Nature Physics, Vol. 10, Issue 8 https://doi.org/10.1038/nphys3010	journal	July 2014
Probing molecular dynamics with attosecond resolution using correlated wave packet pairs Niikura, Hiromichi; Légaré, F.; Hasbani, R. Nature, Vol. 421, Issue 6925 https://doi.org/10.1038/nature01430	journal	February 2003
Attosecond Control of Electron Dynamics in Carbon Monoxide Znakovskaya, I.; von den Hoff, P.; Zherebtsov, S. Physical Review Letters, Vol. 103, Issue 10 https://doi.org/10.1103/PhysRevLett.103.103002	journal	September 2009
Attosecond physics Krausz, Ferenc; Ivanov, Misha Reviews of Modern Physics, Vol. 81, Issue 1 https://doi.org/10.1103/RevModPhys.81.163	journal	February 2009
Velocity map imaging of ions and electrons using electrostatic lenses: Application in photoelectron and photofragment ion imaging of molecular oxygen Eppink, André T. J. B.; Parker, David H. Review of Scientific Instruments, Vol. 68, Issue 9 https://doi.org/10.1063/1.1148310	journal	September 1997
Real-time pulse length measurement of few-cycle laser pulses using above-threshold ionization Sayler, A. M.; Rathje, Tim; Müller, W. Optics Express, Vol. 19, Issue 5 https://doi.org/10.1364/oe.19.004464	journal	January 2011
Multi-channel Electronic and Vibrational Dynamics in Polyatomic High-order Harmonic Generation Ferré, A.; Boguslavskiy, A. E.; Dagan, M. arXiv https://doi.org/10.48550/arxiv.1407.6213	text	January 2014
Plasma perspective on strong field multiphoton ionization Corkum, P. B. Physical Review Letters, Vol. 71, Issue 13 https://doi.org/10.1103/PhysRevLett.71.1994	journal	September 1993
Multichannel coherence in strong-field ionization Rohringer, Nina; Santra, Robin Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/phppubdb-22208	text	January 2009
Multi-channel electronic and vibrational dynamics in polyatomic resonant high-order harmonic generation Ferré, A.; Boguslavskiy, A. E.; Dagan, M. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6952	journal	January 2015
Comparison of intense-field ionization of diatomic molecules and rare-gas atoms Wells, E.; DeWitt, Merrick J.; Jones, R. R. Physical Review A, Vol. 66, Issue 1 https://doi.org/10.1103/PhysRevA.66.013409	journal	July 2002
Field-dressed orbitals in strong-field molecular ionization Siemering, Robert; Njoya, Oumarou; Weinacht, Thomas Physical Review A, Vol. 92, Issue 4 https://doi.org/10.1103/PhysRevA.92.042515	journal	October 2015

Cited By (1)

Deformation of an inner valence molecular orbital in ethanol by an intense laser field Akagi, Hiroshi; Otobe, Tomohito; Itakura, Ryuji Science Advances, Vol. 5, Issue 5 https://doi.org/10.1126/sciadv.aaw1885	journal	May 2019

Similar Records

Predissociation of high-lying Rydberg states of molecular iodine via ion-pair states

Journal Article · Fri Mar 28 00:00:00 EDT 2014 · Journal of Chemical Physics · OSTI ID:1418580

Bogomolov, Alexandr S.; Grüner, Barbara; Mudrich, Marcel; +2 more

Ionization of N{sub 2}, O{sub 2}, and linear carbon clusters in a strong laser pulse

Journal Article · Sun Feb 01 00:00:00 EST 2004 · Physical Review. A · OSTI ID:1418580

Jaron-Becker, A; Becker, A; Faisal, F H.M.

Rotationally resolved photoelectron spectra in resonance enhanced multiphoton ionization of H sub 2 O via the C sup 1 B sub 1 Rydberg state

Journal Article · Tue Sep 15 00:00:00 EDT 1992 · Journal of Chemical Physics; (United States) · OSTI ID:1418580

Lee, M; Wang, K; McKoy, V; +1 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS

Title: The importance of Rydberg orbitals in dissociative ionization of small hydrocarbon molecules in intense laser fields

Citation Formats

References (96)

Cited By (1)

Similar Records

Related Subjects