Active molecular iodine photochemistry in the Arctic

Raso, Angela R. W.; Custard, Kyle D.; May, Nathaniel W.; Tanner, David; Newburn, Matt K.; Walker, Lawrence; Moore, Ronald J.; Huey, L. G.; Alexander, Liz; Shepson, Paul B.; Pratt, Kerri A.

doi:10.1073/pnas.1702803114

Title: Active molecular iodine photochemistry in the Arctic

Journal Article · Tue Sep 05 00:00:00 EDT 2017 · Proceedings of the National Academy of Sciences of the United States of America

DOI:https://doi.org/10.1073/pnas.1702803114· OSTI ID:1406742

Raso, Angela R. W. ^[1]; Custard, Kyle D. ^[2]; May, Nathaniel W. ^[3]; Tanner, David ^[4]; Newburn, Matt K. ^[5]; Walker, Lawrence ^[5]; Moore, Ronald J. ^[5]; Huey, L. G. ^[4]; Alexander, Liz ^[5]; Shepson, Paul B. ^[2];

^[3]

Purdue Univ., West Lafayette, IN (United States); Univ. of Michigan, Ann Arbor, MI (United States)
Purdue Univ., West Lafayette, IN (United States)
Univ. of Michigan, Ann Arbor, MI (United States)
Georgia Inst. of Technology, Atlanta, GA (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

During springtime, the Arctic atmospheric boundary layer undergoes frequent rapid depletions in ozone and gaseous elemental mercury due to reactions with halogen atoms, influencing atmospheric composition and pollutant fate. Although bromine chemistry has been shown to initiate ozone depletion events, and it has long been hypothesized that iodine chemistry may contribute, no previous measurements of molecular iodine (I₂) have been reported in the Arctic. Iodine chemistry also contributes to atmospheric new particle formation and therefore cloud properties and radiative forcing. Here we present Arctic atmospheric I₂ and snowpack iodide (I^-) measurements, which were conducted near Utqiagvik, AK, in February 2014. Using chemical ionization mass spectrometry, I₂ was observed in the atmosphere at mole ratios of 0.3–1.0 ppt, and in the snowpack interstitial air at mole ratios up to 22 ppt under natural sunlit conditions and up to 35 ppt when the snowpack surface was artificially irradiated, suggesting a photochemical production mechanism. Further, snow meltwater I-measurements showed enrichments of up to ~1,900 times above the seawater ratio of I-/Na⁺, consistent with iodine activation and recycling. Modeling shows that observed I₂ levels are able to significantly increase ozone depletion rates, while also producing iodine monoxide (IO) at levels recently observed in the Arctic. Furthermore, these results emphasize the significance of iodine chemistry and the role of snowpack photochemistry in Arctic atmospheric composition, and imply that I₂ is likely a dominant source of iodine atoms in the Arctic.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1406742

Report Number(s):: PNNL-SA-129703; 49331; KP1704020

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Vol. 114, Issue 38; ISSN 0027-8424

Publisher:: National Academy of Sciences, Washington, DC (United States)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 50 works

Citation information provided by
Web of Science

References (67)

Surface ozone measurements in clean air Oltmans, Samuel J. Journal of Geophysical Research, Vol. 86, Issue C2 https://doi.org/10.1029/JC086iC02p01174	journal	January 1981
Iodine monoxide in the Antarctic snowpack Frieß, U.; Deutschmann, T.; Gilfedder, B. S. Atmospheric Chemistry and Physics, Vol. 10, Issue 5 https://doi.org/10.5194/acp-10-2439-2010	journal	January 2010
Halogens and their role in polar boundary-layer ozone depletion Simpson, W. R.; von Glasow, R.; Riedel, K. Atmospheric Chemistry and Physics, Vol. 7, Issue 16 https://doi.org/10.5194/acp-7-4375-2007	journal	January 2007
Photochemical chlorine and bromine activation from artificial saline snow Wren, S. N.; Donaldson, D. J.; Abbatt, J. P. D. Atmospheric Chemistry and Physics, Vol. 13, Issue 19 https://doi.org/10.5194/acp-13-9789-2013	journal	January 2013
Boundary Layer Halogens in Coastal Antarctica Saiz-Lopez, A.; Mahajan, A. S.; Salmon, R. A. Science, Vol. 317, Issue 5836 https://doi.org/10.1126/science.1141408	journal	July 2007
Chlorine, Bromine AND Iodine in arctic aerosols Sturges, W. T.; Barrie, L. A. Atmospheric Environment (1967), Vol. 22, Issue 6 https://doi.org/10.1016/0004-6981(88)90349-6	journal	January 1988
Kinetics and Products of the IO + BrO Reaction Rowley, David M.; Bloss, William J.; Cox, R. Anthony The Journal of Physical Chemistry A, Vol. 105, Issue 33 https://doi.org/10.1021/jp004494y	journal	August 2001
First observations of iodine oxide from space Saiz-Lopez, Alfonso; Chance, Kelly; Liu, Xiong Geophysical Research Letters, Vol. 34, Issue 12 https://doi.org/10.1029/2007GL030111	journal	January 2007
Production of Molecular Iodine and Tri-iodide in the Frozen Solution of Iodide: Implication for Polar Atmosphere Kim, Kitae; Yabushita, Akihiro; Okumura, Masanori Environmental Science & Technology, Vol. 50, Issue 3 https://doi.org/10.1021/acs.est.5b05148	journal	January 2016
Photolysis of frozen iodate salts as a source of active iodine in the polar environment Gálvez, Óscar; Baeza-Romero, M. Teresa; Sanz, Mikel Atmospheric Chemistry and Physics, Vol. 16, Issue 19 https://doi.org/10.5194/acp-16-12703-2016	journal	January 2016
Molecular-scale evidence of aerosol particle formation via sequential addition of HIO3 Sipilä, Mikko; Sarnela, Nina; Jokinen, Tuija Nature, Vol. 537, Issue 7621 https://doi.org/10.1038/nature19314	journal	August 2016
Formation of Gas-Phase Bromine from Interaction of Ozone with Frozen and Liquid NaCl/NaBr Solutions: Quantitative Separation of Surficial Chemistry from Bulk-Phase Reaction Oldridge, N. W.; Abbatt, J. P. D. The Journal of Physical Chemistry A, Vol. 115, Issue 12 https://doi.org/10.1021/jp200074u	journal	March 2011
Compilation of Henry's law constants (version 4.0) for water as solvent Sander, R. Atmospheric Chemistry and Physics, Vol. 15, Issue 8 https://doi.org/10.5194/acp-15-4399-2015	journal	January 2015
Photochemical production of molecular bromine in Arctic surface snowpacks Pratt, Kerri A.; Custard, Kyle D.; Shepson, Paul B. Nature Geoscience, Vol. 6, Issue 5 https://doi.org/10.1038/ngeo1779	journal	April 2013
Bromine explosion Wennberg, Paul Nature, Vol. 397, Issue 6717 https://doi.org/10.1038/16805	journal	January 1999
Release of gas-phase halogens from sodium halide substrates: heterogeneous oxidation of frozen solutions and desiccated salts by hydroxyl radicals Sjostedt, S. J.; Abbatt, J. P. D. Environmental Research Letters, Vol. 3, Issue 4 https://doi.org/10.1088/1748-9326/3/4/045007	journal	October 2008
Hydroxyl radical and NO _x production rates, black carbon concentrations and light-absorbing impurities in snow from field measurements of light penetration and nadir reflectivity of onshore and offshore coastal Alaskan snow : ALASKAN SNOW OPTICS AND PHOTOCHEMISTRY France, J. L.; Reay, H. J.; King, M. D. Journal of Geophysical Research: Atmospheres, Vol. 117, Issue D14 https://doi.org/10.1029/2011JD016639	journal	March 2012
Direct evidence for coastal iodine particles from Laminaria macroalgae – linkage to emissions of molecular iodine McFiggans, G.; Coe, H.; Burgess, R. Atmospheric Chemistry and Physics, Vol. 4, Issue 3 https://doi.org/10.5194/acp-4-701-2004	journal	January 2004
Iodine observed in new particle formation events in the Arctic atmosphere during ACCACIA Allan, J. D.; Williams, P. I.; Najera, J. Atmospheric Chemistry and Physics Discussions, Vol. 14, Issue 21 https://doi.org/10.5194/acpd-14-28949-2014	journal	January 2014
Interactions of bromine, chlorine, and iodine photochemistry during ozone depletions in Barrow, Alaska Thompson, C. R.; Shepson, P. B.; Liao, J. Atmospheric Chemistry and Physics, Vol. 15, Issue 16 https://doi.org/10.5194/acp-15-9651-2015	journal	January 2015
Bromine measurements in ozone depleted air over the Arctic Ocean Neuman, J. A.; Nowak, J. B.; Huey, L. G. Atmospheric Chemistry and Physics, Vol. 10, Issue 14 https://doi.org/10.5194/acp-10-6503-2010	journal	January 2010
Potential influence of iodine-containing compounds on the chemistry of the troposphere in the polar spring. I. Ozone depletion Calvert, Jack G.; Lindberg, Steve E. Atmospheric Environment, Vol. 38, Issue 30 https://doi.org/10.1016/j.atmosenv.2004.05.049	journal	September 2004
Kinetics and Product Yields in the Heterogeneous Reactions of HOBr with Ice Surfaces Containing NaBr and NaCl Huff, Amy K.; Abbatt, Jonathan P. D. The Journal of Physical Chemistry A, Vol. 106, Issue 21 https://doi.org/10.1021/jp014296m	journal	May 2002
Can We Model Snow Photochemistry? Problems with the Current Approaches Domine, Florent; Bock, Josué; Voisin, Didier The Journal of Physical Chemistry A, Vol. 117, Issue 23 https://doi.org/10.1021/jp3123314	journal	May 2013
Dynamics of ozone and nitrogen oxides at Summit, Greenland: I. Multi-year observations in the snowpack Van Dam, Brie; Helmig, Detlev; Toro, Claudia Atmospheric Environment, Vol. 123 https://doi.org/10.1016/j.atmosenv.2015.09.060	journal	December 2015
Air–snowpack exchange of bromine, ozone and mercury in the springtime Arctic simulated by the 1-D model PHANTAS – Part 1: In-snow bromine activation and its impact on ozone Toyota, K.; McConnell, J. C.; Staebler, R. M. Atmospheric Chemistry and Physics, Vol. 14, Issue 8 https://doi.org/10.5194/acp-14-4101-2014	journal	January 2014
Temporal and spatial characteristics of ozone depletion events from measurements in the Arctic Halfacre, J. W.; Knepp, T. N.; Shepson, P. B. Atmospheric Chemistry and Physics, Vol. 14, Issue 10 https://doi.org/10.5194/acp-14-4875-2014	journal	January 2014
Estimating the climate significance of halogen-driven ozone loss in the tropical marine troposphere Saiz-Lopez, A.; Lamarque, J. -F.; Kinnison, D. E. Atmospheric Chemistry and Physics, Vol. 12, Issue 9 https://doi.org/10.5194/acp-12-3939-2012	journal	January 2012
Heterogeneous chemistry and tropospheric ozone Jacob, D. Atmospheric Environment, Vol. 34, Issue 12-14 https://doi.org/10.1016/S1352-2310(99)00462-8	journal	January 2000
Tropospheric Halogen Chemistry: Sources, Cycling, and Impacts Simpson, William R.; Brown, Steven S.; Saiz-Lopez, Alfonso Chemical Reviews, Vol. 115, Issue 10 https://doi.org/10.1021/cr5006638	journal	February 2015
Observations of inorganic bromine (HOBr, BrO, and Br ₂ ) speciation at Barrow, Alaska, in spring 2009 : INORGANIC BROMINE SPECIATION AT BARROW Liao, J.; Huey, L. G.; Tanner, D. J. Journal of Geophysical Research: Atmospheres, Vol. 117, Issue D14 https://doi.org/10.1029/2011JD016641	journal	March 2012
Non-metal redox kinetics: iodine monobromide reaction with iodide ion and the hydrolysis of IBr Troy, Robert C.; Kelley, Mark D.; Nagy, Julius C. Inorganic Chemistry, Vol. 30, Issue 25 https://doi.org/10.1021/ic00025a030	journal	December 1991
Constraints on Arctic Atmospheric Chlorine Production through Measurements and Simulations of Cl ₂ and ClO Custard, Kyle D.; Pratt, Kerri A.; Wang, Siyuan Environmental Science & Technology, Vol. 50, Issue 22 https://doi.org/10.1021/acs.est.6b03909	journal	October 2016
Production and Release of Molecular Bromine and Chlorine from the Arctic Coastal Snowpack Custard, K. D.; Raso, A. R. W.; Shepson, P. B. ACS Earth and Space Chemistry, Vol. 1, Issue 3 https://doi.org/10.1021/acsearthspacechem.7b00014	journal	April 2017
Uncertainties in gas-phase atmospheric iodine chemistry Sommariva, R.; Bloss, W. J.; von Glasow, R. Atmospheric Environment, Vol. 57 https://doi.org/10.1016/j.atmosenv.2012.04.032	journal	September 2012
Anthropogenic aerosols and gases in the lower troposphere at Alert Canada in April 1986 Barrie, L. A.; den Hartog, G.; Bottenheim, J. W. Journal of Atmospheric Chemistry, Vol. 9, Issue 1-3 https://doi.org/10.1007/BF00052827	journal	July 1989
Ozone destruction and photochemical reactions at polar sunrise in the lower Arctic atmosphere Barrie, L. A.; Bottenheim, J. W.; Schnell, R. C. Nature, Vol. 334, Issue 6178 https://doi.org/10.1038/334138a0	journal	July 1988
Observations of BrO and its vertical distribution during surface ozone depletion at Alert Hönninger, Gerd; Platt, U. Atmospheric Environment, Vol. 36, Issue 15-16 https://doi.org/10.1016/S1352-2310(02)00104-8	journal	May 2002
Experimental verification of gas phase bromine enrichment in reactions of HOBr with sea salt doped ice surfaces Kirchner, U.; Benter, T. H.; Schindler, R. N. Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 101, Issue 6 https://doi.org/10.1002/bbpc.19971010614	journal	June 1997
Evidence of reactive iodine chemistry in the Arctic boundary layer Mahajan, Anoop S.; Shaw, Marvin; Oetjen, Hilke Journal of Geophysical Research, Vol. 115, Issue D20 https://doi.org/10.1029/2009JD013665	journal	January 2010
Bromine activation in the troposphere by the dark reaction of O ₃ with seawater ice Oum, K. W.; Lakin, M. J.; Finlayson-Pitts, B. J. Geophysical Research Letters, Vol. 25, Issue 21 https://doi.org/10.1029/1998GL900078	journal	November 1998
Bromide and chloride distribution across the snow-sea ice-ocean interface: A comparative study between an Arctic coastal marine site and an experimental sea ice mesocosm: HALIDES IN THE MARINE CRYOSPHERE Xu, Wen; Tenuta, Mario; Wang, Feiyue Journal of Geophysical Research: Oceans, Vol. 121, Issue 8 https://doi.org/10.1002/2015JC011409	journal	August 2016
Iodine chemistry in the troposphere and its effect on ozone Saiz-Lopez, A.; Fernandez, R. P.; Ordóñez, C. Atmospheric Chemistry and Physics, Vol. 14, Issue 23 https://doi.org/10.5194/acp-14-13119-2014	journal	January 2014
Spectroscopic measurement of bromine oxide and ozone in the high Arctic during Polar Sunrise Experiment 1992 Hausmann, M.; Platt, U. Journal of Geophysical Research, Vol. 99, Issue D12 https://doi.org/10.1029/94JD01314	journal	January 1994
Release of Gas-Phase Halogens by Photolytic Generation of OH in Frozen Halide−Nitrate Solutions: An Active Halogen Formation Mechanism? Abbatt, J.; Oldridge, N.; Symington, A. The Journal of Physical Chemistry A, Vol. 114, Issue 23 https://doi.org/10.1021/jp102072t	journal	June 2010
Absolute absorption cross-section and photolysis rate of I<sub>2</sub> Saiz-Lopez, A.; Saunders, R. W.; Joseph, D. M. Atmospheric Chemistry and Physics, Vol. 4, Issue 5 https://doi.org/10.5194/acp-4-1443-2004	journal	January 2004
Modelling molecular iodine emissions in a coastal marine environment: the link to new particle formation Saiz-Lopez, A.; Plane, J. M. C.; McFiggans, G. Atmospheric Chemistry and Physics, Vol. 6, Issue 4 https://doi.org/10.5194/acp-6-883-2006	journal	January 2006
Halogens in the coastal snow pack near Barrow, Alaska: Evidence for active bromine air-snow chemistry during springtime: BROMIDE IN SNOW NEAR BARROW Simpson, William R.; Alvarez-Aviles, Laura; Douglas, Thomas A. Geophysical Research Letters, Vol. 32, Issue 4 https://doi.org/10.1029/2004GL021748	journal	February 2005
A mechanism for biologically-induced iodine emissions from sea-ice Saiz-Lopez, A.; Blaszczak-Boxe, C. S.; Carpenter, L. J. Atmospheric Chemistry and Physics Discussions, Vol. 15, Issue 7 https://doi.org/10.5194/acpd-15-10257-2015	journal	January 2015
Novel iodine chemistry in the marine boundary layer Saiz-Lopez, Alfonso Geophysical Research Letters, Vol. 31, Issue 4 https://doi.org/10.1029/2003GL019215	journal	January 2004
The polar iodine paradox Saiz-Lopez, Alfonso; Blaszczak-Boxe, Christopher Shawn Atmospheric Environment, Vol. 145 https://doi.org/10.1016/j.atmosenv.2016.09.019	journal	November 2016
High levels of molecular chlorine in the Arctic atmosphere Liao, Jin; Huey, L. Gregory; Liu, Zhen Nature Geoscience, Vol. 7, Issue 2 https://doi.org/10.1038/ngeo2046	journal	January 2014
Observations of rapid photochemical destruction of ozone in snowpack interstitial air Peterson, M. C.; Honrath, R. E. Geophysical Research Letters, Vol. 28, Issue 3 https://doi.org/10.1029/2000GL012129	journal	February 2001
Atmospheric Chemistry of Iodine Saiz-Lopez, Alfonso; Plane, John M. C.; Baker, Alex R. Chemical Reviews, Vol. 112, Issue 3 https://doi.org/10.1021/cr200029u	journal	October 2011
A review of air–ice chemical and physical interactions (AICI): liquids, quasi-liquids, and solids in snow Bartels-Rausch, T.; Jacobi, H. -W.; Kahan, T. F. Atmospheric Chemistry and Physics, Vol. 14, Issue 3 https://doi.org/10.5194/acp-14-1587-2014	journal	January 2014
Dependence of the vertical distribution of bromine monoxide in the lower troposphere on meteorological factors such as wind speed and stability Peterson, P. K.; Simpson, W. R.; Pratt, K. A. Atmospheric Chemistry and Physics, Vol. 15, Issue 4 https://doi.org/10.5194/acp-15-2119-2015	journal	January 2015
Modeling chemistry in and above snow at Summit, Greenland – Part 1: Model description and results Thomas, J. L.; Stutz, J.; Lefer, B. Atmospheric Chemistry and Physics, Vol. 11, Issue 10 https://doi.org/10.5194/acp-11-4899-2011	journal	January 2011
Iodine emissions from the sea ice of the Weddell Sea Atkinson, H. M.; Huang, R. -J.; Chance, R. Atmospheric Chemistry and Physics, Vol. 12, Issue 22 https://doi.org/10.5194/acp-12-11229-2012	journal	January 2012
The Role of Br2 and BrCl in Surface Ozone Destruction at Polar Sunrise Foster, K. L. Science, Vol. 291, Issue 5503 https://doi.org/10.1126/science.291.5503.471	journal	January 2001
Equilibrium and Kinetics of Bromine Hydrolysis Beckwith, Richard C.; Wang, Tian Xiang; Margerum, Dale W. Inorganic Chemistry, Vol. 35, Issue 4 https://doi.org/10.1021/ic950909w	journal	January 1996
The distribution of dissolved inorganic iodine in the seas around Iceland Waite, Tim J.; Truesdale, Victor W.; Olafsson, Jon Marine Chemistry, Vol. 101, Issue 1-2 https://doi.org/10.1016/j.marchem.2006.01.003	journal	September 2006
A comparison of Arctic BrO measurements by chemical ionization mass spectrometry and long path-differential optical absorption spectroscopy Liao, J.; Sihler, H.; Huey, L. G. Journal of Geophysical Research, Vol. 116 https://doi.org/10.1029/2010JD014788	journal	January 2011
Extinction of UV radiation in Arctic snow at Alert, Canada (82°N) King, Martin D.; Simpson, William R. Journal of Geophysical Research: Atmospheres, Vol. 106, Issue D12 https://doi.org/10.1029/2001JD900006	journal	June 2001
Uptake and reaction of HOI and IONO2 on frozen and dry NaCl/NaBr surfaces and H2SO4 Holmes, Nicholas S.; Adams, Jonathan W.; Crowley, John N. Physical Chemistry Chemical Physics, Vol. 3, Issue 9 https://doi.org/10.1039/b100247n	journal	January 2001
Atmospheric iodine levels influenced by sea surface emissions of inorganic iodine Carpenter, Lucy J.; MacDonald, Samantha M.; Shaw, Marvin D. Nature Geoscience, Vol. 6, Issue 2 https://doi.org/10.1038/ngeo1687	journal	January 2013
Uptake and reaction of HOBr on frozen and dry NaCl/NaBr surfaces between 253 and 233 K Adams, J. W.; Holmes, N. S.; Crowley, J. N. Atmospheric Chemistry and Physics, Vol. 2, Issue 1 https://doi.org/10.5194/acp-2-79-2002	journal	January 2002
A mechanism for biologically induced iodine emissions from sea ice Saiz-Lopez, A.; Blaszczak-Boxe, C. S.; Carpenter, L. J. Atmospheric Chemistry and Physics, Vol. 15, Issue 17 https://doi.org/10.5194/acp-15-9731-2015	journal	January 2015

Cited By (11)

Direct detection of atmospheric atomic bromine leading to mercury and ozone depletion Wang, Siyuan; McNamara, Stephen M.; Moore, Christopher W. Proceedings of the National Academy of Sciences, Vol. 116, Issue 29 https://doi.org/10.1073/pnas.1900613116	journal	June 2019
A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface Artiglia, Luca; Edebeli, Jacinta; Orlando, Fabrizio ETH Zurich https://doi.org/10.3929/ethz-b-000192730	text	January 2017
A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface Artiglia, Luca; Edebeli, Jacinta; Orlando, Fabrizio Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00823-x	journal	September 2017
Diurnal cycle of iodine, bromine, and mercury concentrations in Svalbard surface snow Spolaor, Andrea; Barbaro, Elena; Cappelletti, David Atmospheric Chemistry and Physics, Vol. 19, Issue 20 https://doi.org/10.5194/acp-19-13325-2019	journal	January 2019
pH-dependent production of molecular chlorine, bromine, and iodine from frozen saline surfaces Halfacre, John W.; Shepson, Paul B.; Pratt, Kerri A. Atmospheric Chemistry and Physics, Vol. 19, Issue 7 https://doi.org/10.5194/acp-19-4917-2019	journal	January 2019
Holocene atmospheric iodine evolution over the North Atlantic Corella, Juan Pablo; Maffezzoli, Niccolo; Cuevas, Carlos Alberto Climate of the Past, Vol. 15, Issue 6 https://doi.org/10.5194/cp-15-2019-2019	journal	January 2019
Characterization of aerosol growth events over Ellesmere Island during the summers of 2015 and 2016 Tremblay, Samantha; Picard, Jean-Christophe; Bachelder, Jill O. Atmospheric Chemistry and Physics, Vol. 19, Issue 8 https://doi.org/10.5194/acp-19-5589-2019	journal	January 2019
Rapid increase in atmospheric iodine levels in the North Atlantic since the mid-20th century Cuevas, Carlos A.; Maffezzoli, Niccolò; Corella, Juan Pablo Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03756-1	journal	April 2018
Atmospheric chemistry of iodine anions: elementary reactions of I ⁻ , IO ⁻ , and IO ₂ ⁻ with ozone studied in the gas-phase at 300 K using an ion trap Teiwes, Ricky; Elm, Jonas; Handrup, Karsten Physical Chemistry Chemical Physics, Vol. 20, Issue 45 https://doi.org/10.1039/c8cp05721d	journal	January 2018
Modeling the Sources and Chemistry of Polar Tropospheric Halogens (Cl, Br, and I) Using the CAM‐Chem Global Chemistry‐Climate Model Fernandez, Rafael P.; Carmona‐Balea, Antía; Cuevas, Carlos A. Journal of Advances in Modeling Earth Systems, Vol. 11, Issue 7 https://doi.org/10.1029/2019ms001655	journal	July 2019
Processes Controlling the Composition and Abundance of Arctic Aerosol Willis, Megan D.; Leaitch, W. Richard; Abbatt, Jonathan P. D. Reviews of Geophysics, Vol. 56, Issue 4 https://doi.org/10.1029/2018rg000602	journal	November 2018

Similar Records

Potential influence of iodine-containing compounds on the chemistry of the troposphere in the polar spring. I. Mercury depletion

Journal Article · Sat May 01 00:00:00 EDT 2004 · Atmospheric Environment · OSTI ID:1406742

Calvert, Jack G; Lindberg, Steven Eric

Low ozone dry deposition rates to sea ice during the MOSAiC field campaign: Implications for the Arctic boundary layer ozone budget

Journal Article · Wed Feb 15 00:00:00 EST 2023 · Elementa · OSTI ID:1406742

Barten, Johannes G. M.; Ganzeveld, Laurens N.; Steeneveld, Gert-Jan; +18 more

Substantial contribution of iodine to Arctic ozone destruction

Journal Article · Thu Sep 15 00:00:00 EDT 2022 · Nature Geoscience (Online) · OSTI ID:1406742

Benavent, Nuria; Mahajan, Anoop S.; Li, Qinyi; +31 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
54 ENVIRONMENTAL SCIENCES
Environmental Molecular Sciences Laboratory
atmosphere
iodine
cryosphere
snowpack
photochemistry

Title: Active molecular iodine photochemistry in the Arctic

Citation Formats

References (67)

Cited By (11)

Similar Records

Related Subjects