Derivation and Decoration of Nets with Trigonal-Prismatic Nodes: A Unique Route to Reticular Synthesis of Metal–Organic Frameworks

Qin, Jun-Sheng; Du, Dong-Ying; Li, Mian; Lian, Xi-Zhen; Dong, Long-Zhang; Bosch, Mathieu; Su, Zhong-Min; Zhang, Qiang; Li, Shun-Li; Lan, Ya-Qian; Yuan, Shuai; Zhou, Hong-Cai

doi:10.1021/jacs.6b01093

Title: Derivation and Decoration of Nets with Trigonal-Prismatic Nodes: A Unique Route to Reticular Synthesis of Metal–Organic Frameworks

Journal Article · Tue Apr 05 00:00:00 EDT 2016 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.6b01093· OSTI ID:1387707

Qin, Jun-Sheng ^[1]; Du, Dong-Ying ^[2]; Li, Mian ^[3]; Lian, Xi-Zhen ^[4]; Dong, Long-Zhang ^[5]; Bosch, Mathieu ^[4]; Su, Zhong-Min ^[2]; Zhang, Qiang ^[4]; Li, Shun-Li ^[5]; Lan, Ya-Qian ^[6]; Yuan, Shuai ^[4]; Zhou, Hong-Cai ^[4]

Texas A & M Univ., College Station, TX (United States); Northeast Normal Univ., Changchun (People's Republic of China)
Northeast Normal Univ., Changchun (People's Republic of China)
Shantou Univ., Guangdong (People's Republic of China)
Texas A & M Univ., College Station, TX (United States)
Nanjing Normal Univ. (People's Republic of China)
Nanjing Normal Univ. (People's Republic of China); Northeast Normal Univ., Changchun (People's Republic of China)

Quests for advanced functionalities in metal–organic frameworks (MOFs) inevitably encounter increasing complexity in their tailored framework architectures, accompanied by heightened challenges with their geometric design. Herein, we demonstrate the feasibility of rationally exploiting topological prediction as a blueprint for predesigned MOFs. A new triangular frusta secondary building unit (SBU), {Zn₄(tz)₃}, was bridged by three TDC^2– fragments to initially form a trigonal prismatic node, {Zn₈(tz)₆(TDC)₃} (Htz = 1H-1,2,3-triazole and H₂TDC = 2,5-thiophenedicarboxylic acid). Furthermore, the trigonal prism unit can be considered as a double SBU derived from triply bound triangular frusta. By considering theoretical derived nets for linking this trigonal-prismatic node with ditopic, tritopic, and tetratopic linkers, we have synthesized and characterized a new family of MOFs that adopt the decorated lon, jea, and xai nets, respectively. Pore sizes have also been successively increased within TPMOF-n family, which facilitates heterogeneous biomimetic catalysis with Fe–porphyrin-based TPMOF-7 as a catalyst.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NSFC); China Postdoctoral Science Foundation; Priority Academic Program Development of Jiangsu Higher Education Institutions; Foundation of Jiangsu Collaborative Innovation Center of Biomedical Functional Materials; Science and Technology Development Planning of Jilin Province

Grant/Contract Number:: SC0001015

OSTI ID:: 1387707

Journal Information:: Journal of the American Chemical Society, Vol. 138, Issue 16; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 80 works

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Single-crystal structure validation with the program PLATON Spek, A. L. Journal of Applied Crystallography, Vol. 36, Issue 1, p. 7-13 https://doi.org/10.1107/S0021889802022112	journal	January 2003
Dimethylformamide as a Carbon Monoxide Source in Fast Palladium-Catalyzed Aminocarbonylations of Aryl Bromides Wan, Yiqian; Alterman, Mathias; Larhed, Mats The Journal of Organic Chemistry, Vol. 67, Issue 17 https://doi.org/10.1021/jo025965a	journal	August 2002
Design, Synthesis, Structure, and Gas (N₂, Ar, CO₂, CH₄, and H₂) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W. Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118 https://doi.org/10.1021/ja042802q	journal	May 2005
A Metal–Organic Framework with a Hierarchical System of Pores and Tetrahedral Building Blocks Sudik, Andrea C.; Côté, Adrien P.; Wong-Foy, Antek G. Angewandte Chemie International Edition, Vol. 45, Issue 16, p. 2528-2533 https://doi.org/10.1002/anie.200600175	journal	April 2006
Pore Space Partition and Charge Separation in Cage-within-Cage Indium−Organic Frameworks with High CO ₂ Uptake Zheng, Shou-Tian; Bu, Julia T.; Li, Yufei Journal of the American Chemical Society, Vol. 132, Issue 48 https://doi.org/10.1021/ja106903p	journal	December 2010
Remarkable structural diversity and single-crystal-to-single-crystal transformations in sulfone functionalized lanthanide MOFs Neofotistou, Eleftheria; Malliakas, Christos D.; Trikalitis, Pantelis N. CrystEngComm, Vol. 12, Issue 4 https://doi.org/10.1039/B918269C	journal	January 2010
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Mimicking Zeolite to Its Core: Porous Sodalite Cages as Hangers for Pendant Trimeric M ₃ (OH) Clusters (M = Mg, Mn, Co, Ni, Cd) Zheng, Shou-Tian; Wu, Tao; Zuo, Fan Journal of the American Chemical Society, Vol. 134, Issue 4 https://doi.org/10.1021/ja209800x	journal	January 2012
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Construction of Zeolite-Like Cluster Organic Frameworks from 3 d-4 d/3 d-3 d Heterometallic Supertetrahedral Secondary Building Units: Syntheses, Structures, and Properties Lin, Li-Dan; Deng, Chu-Chu; Zhao, D. Chemistry - A European Journal, Vol. 24, Issue 1 https://doi.org/10.1002/chem.201704511	journal	December 2017
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Construction of solvent-dependent self-assembled porous Ni( ii )-coordinated frameworks as effective catalysts for chemical transformation of CO ₂ Zhou, Zhen; Yang, Lu; Wang, Yefei RSC Advances, Vol. 6, Issue 109 https://doi.org/10.1039/c6ra22971a	journal	January 2016
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Gate-opening upon CO ₂ adsorption on a metal–organic framework that mimics a natural stimuli-response system Tseng, T. W.; Lee, L. W.; Luo, T. T. Dalton Transactions, Vol. 46, Issue 43 https://doi.org/10.1039/c7dt03119j	journal	January 2017
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Directed assembly of a high surface area 2D metal–organic framework displaying the augmented “kagomé dual” (kgd-a) layered topology with high H ₂ and CO ₂ uptake Spanopoulos, Ioannis; Tsangarakis, Constantinos; Barnett, Sarah Inorganic Chemistry Frontiers, Vol. 4, Issue 5 https://doi.org/10.1039/c6qi00547k	journal	January 2017
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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
membrane
carbon capture
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)
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CCDC 1480267: Experimental Crystal Structure Determination Qin, Jun-Sheng; Du, Dong-Ying; Li, Mian https://doi.org/10.5517/ccdc.csd.cc1lpbk5 The current record is supplemented by this dataset	dataset	January 2016
CCDC 1480269: Experimental Crystal Structure Determination Qin, Jun-Sheng; Du, Dong-Ying; Li, Mian https://doi.org/10.5517/ccdc.csd.cc1lpbm7 The current record is supplemented by this dataset	dataset	January 2016
CCDC 1480264: Experimental Crystal Structure Determination Qin, Jun-Sheng; Du, Dong-Ying; Li, Mian https://doi.org/10.5517/ccdc.csd.cc1lpbg2 The current record is supplemented by this dataset	dataset	January 2016
CCDC 1480262: Experimental Crystal Structure Determination Qin, Jun-Sheng; Du, Dong-Ying; Li, Mian https://doi.org/10.5517/ccdc.csd.cc1lpbd0 The current record is supplemented by this dataset	dataset	January 2016
CCDC 1480266: Experimental Crystal Structure Determination Qin, Jun-Sheng; Du, Dong-Ying; Li, Mian https://doi.org/10.5517/ccdc.csd.cc1lpbj4 The current record is supplemented by this dataset	dataset	January 2016
CCDC 1480268: Experimental Crystal Structure Determination Qin, Jun-Sheng; Du, Dong-Ying; Li, Mian https://doi.org/10.5517/ccdc.csd.cc1lpbl6 The current record is supplemented by this dataset	dataset	January 2016
CCDC 1480263: Experimental Crystal Structure Determination Qin, Jun-Sheng; Du, Dong-Ying; Li, Mian https://doi.org/10.5517/ccdc.csd.cc1lpbf1 The current record is supplemented by this dataset	dataset	January 2016
CCDC 1480265: Experimental Crystal Structure Determination Qin, Jun-Sheng; Du, Dong-Ying; Li, Mian https://doi.org/10.5517/ccdc.csd.cc1lpbh3 The current record is supplemented by this dataset	dataset	January 2016