Ion conducting polymers and polymer blends for alkali metal ion batteries
Abstract
Electrolyte compositions for batteries such as lithium ion and lithium air batteries are described. In some embodiments the compositions are liquid compositions comprising (a) a homogeneous solvent system, said solvent system comprising a perfluropolyether (PFPE) and polyethylene oxide (PEO); and (b) an alkali metal salt dissolved in said solvent system. In other embodiments the compositions are solid electrolyte compositions comprising: (a) a solid polymer, said polymer comprising a crosslinked product of a crosslinkable perfluropolyether (PFPE) and a crosslinkable polyethylene oxide (PEO); and (b) an alkali metal ion salt dissolved in said polymer. Batteries containing such compositions as electrolytes are also described.
- Inventors:
- Publication Date:
- Research Org.:
- The University of North Carolina at Chapel Hill, Chapel Hill, NC (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1377828
- Patent Number(s):
- 9,748,604
- Application Number:
- 14/436,603
- Assignee:
- The University of North Carolina at Chapel Hill
- DOE Contract Number:
- SC0001011
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2013 Oct 17
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 25 ENERGY STORAGE
Citation Formats
DeSimone, Joseph M., Pandya, Ashish, Wong, Dominica, and Vitale, Alessandra. Ion conducting polymers and polymer blends for alkali metal ion batteries. United States: N. p., 2017.
Web.
DeSimone, Joseph M., Pandya, Ashish, Wong, Dominica, & Vitale, Alessandra. Ion conducting polymers and polymer blends for alkali metal ion batteries. United States.
DeSimone, Joseph M., Pandya, Ashish, Wong, Dominica, and Vitale, Alessandra. 2017.
"Ion conducting polymers and polymer blends for alkali metal ion batteries". United States. https://www.osti.gov/servlets/purl/1377828.
@article{osti_1377828,
title = {Ion conducting polymers and polymer blends for alkali metal ion batteries},
author = {DeSimone, Joseph M. and Pandya, Ashish and Wong, Dominica and Vitale, Alessandra},
abstractNote = {Electrolyte compositions for batteries such as lithium ion and lithium air batteries are described. In some embodiments the compositions are liquid compositions comprising (a) a homogeneous solvent system, said solvent system comprising a perfluropolyether (PFPE) and polyethylene oxide (PEO); and (b) an alkali metal salt dissolved in said solvent system. In other embodiments the compositions are solid electrolyte compositions comprising: (a) a solid polymer, said polymer comprising a crosslinked product of a crosslinkable perfluropolyether (PFPE) and a crosslinkable polyethylene oxide (PEO); and (b) an alkali metal ion salt dissolved in said polymer. Batteries containing such compositions as electrolytes are also described.},
doi = {},
url = {https://www.osti.gov/biblio/1377828},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 29 00:00:00 EDT 2017},
month = {Tue Aug 29 00:00:00 EDT 2017}
}
Works referenced in this record:
Processes for preparing perfluoropolyether oils of very high purity and low volatility
patent, December 1979
- Caporiccio, Gerardo; Corti, Costante; Belardinelli, Giorgio
- US Patent Document 4,178,465
Perfluoroglycidyl ethers
patent, November 1982
- Krespan, Carl G.; King, Alicia P.
- US Patent Document 4,360,645
Method for protecting stone materials from atmospheric agents by means of perfluoropolyether derivatives
patent, May 1988
- Piacenti, Franco; Pasetti, Adolfo; Matteoli, Ugo
- US Patent Document 4,745,009
Electrochemical device
patent, April 1991
- Yoneyama, Sachiko; Ohsawa, Toshiyuki; Kimura, Okitoshi
- US Patent Document 5,011,751
Acrylamido functional disubstituted acetyl aryl ketone photoinitiators
patent, April 1996
- Babu, Gaddam N.; Bennett, Greggory S.; Chen, Kejian
- US Patent Document 5,506,279
Oil-in-water emulsion containing a perfluoropolyether, composition containing the same, preparation process and use in cosmetics and dermatology
patent, March 1997
- Deprez, Sabine; Candau, Didier
- US Patent Document 5,612,043
Polyethylene oxide coated intraocular lens
patent, April 1997
- Hoffman, Allan S.; Patel, Anilbhai S.; Llanos, Gerard
- US Patent Document 5,618,316
Alkali metal ion battery electrode material
patent, February 1998
- Shackle, Dale R.
- US Patent Document 5,721,070
Preparation of ultrafine particles from water-in-oil microemulsions
patent, March 1998
- Chittofrati, Alba; Boselli, Viviana
- US Patent Document 5,725,802
Process for preparing perfluoropolyethers with bromo- or iodo-containing end groups
patent, July 1998
- Marchionni, Giuseppe; Guarda, Pier Antonio
- US Patent Document 5,777,174
Nonflammable/self-extinguishing electrolytes for batteries
patent, November 1998
- Narang, Subhash C.; Ventura, Susanna; Dougherty, Brian
- US Patent Document 5,830,600
Perfluoropolyethers having polycarbonate structure
patent, May 1999
- Turri, Stefano; Levi, Marinella; Tonelli, Claudio
- US Patent Document 5,900,500
Synthetic lubricating oil
patent, August 2000
- Hagihara, Toshiya; Nakagawa, Shoji; Kobayashi, Yuichiro
- US Patent Document 6,096,692
Phosphorus-comprising lubricating oil composition
patent, February 2001
- Nakagawa, Shoji; Kobayashi, Yuichiro; Togashi, Hiroyasu
- US Patent Document 6,190,574
Films, fibers and articles of chemically modified polyethylene oxide compositions with improved environmental stability and method of making same
patent, February 2003
- Balogh, Bridget; Topolkaraev, Vasily A.
- US Patent Document 6,515,075
Perfluoropolyether compounds as additives in formulations
patent, August 2003
- Carignano, Gabriella; Dominicis, Mattia De
- US Patent Document 6,608,138
Electrolyte system and energy storage device using same
patent, September 2004
- Tsukamoto, Hisashi; Koike, Tsuneaki
- US Patent Document 6,797,437
Photosenseitive polymer having fluorinated ethylene glycol group and chemically amplified resist composition comprising the same
patent, January 2005
- Choi, Sang-jun; Moon, Joo-tae; Woo, Sang-Gyun
- US Patent Document 6,844,134
Perfluoropolyether additives for electrochemical applications
patent, May 2005
- Marchionni, Giuseppe; Zompatori, Alberto; Chittofrati, Alba
- US Patent Document 6,896,996
Process for the back-surface grinding of wafers
patent, October 2005
- Rogalli, Michael; Schneegans, Manfred
- US Patent Document 6,958,256
Perfluoropolyether silanes and use thereof
patent, November 2007
- Flynn, Richard M.; Fan, Wayne W.
- US Patent Document 7,294,731
Pupil regulated multifocal contact lenses
patent, May 2008
- Roffman, Jeffrey H.; Kumar, Ganesh; Jubin, Philippe F.
- US Patent Document 7,370,962
Flame retardant battery
patent, January 2009
- Lam, Phuong-Nghi; Nagata, Mikito; Tsukamoto, Hisashi
- US Patent Document 7,476,468
Electrolyte system having multiple liquid phases in contact with one another
patent, January 2009
- Tsukamoto, Hisashi; Koike, Tsuneaki
- US Patent Document 7,482,098
Modified 2′ and 3′-nucleoside prodrugs for treating Flaviviridae infections
patent, October 2009
- Storer, Richard; Gosselin, Gilles; Sommadossi, Jean-Pierre
- US Patent Document 7,608,600
Solid polymer electrolyte for lithium ion battery and lithium ion battery
patent, June 2010
- Wakihara, Masataka; Seki, Masayuki; Mita, Hidehisa
- US Patent Document 7,732,100
Electrolyte composition
patent, September 2010
- Costello, Michael G.; Flynn, Richard M.; Segawa, Haruki
- US Patent Document 7,790,312
Polyethylene-oxide based films and drug delivery systems made therefrom
patent, March 2011
- Yang, Robert K.; Fuisz, Richard C.; Myers, Gary L.
- US Patent Document 7,897,080
Process for producing fluoropolymers
patent, August 2011
- Coughlin, Michael Cregg; Hung, Ming-Hong
- US Patent Document 7,989,566
Crosslinkable graft polymer non-preferentially wetted by polystyrene and polyethylene oxide
patent, December 2011
- Millward, Dan B.
- US Patent Document 8,080,615
Composition comprising perfluoropolyether
patent, December 2011
- Howell, Jon Lee; Van Der Ende, Alice E.; Perez, Erik William
- US Patent Document 8,084,405
Coating composition for a urinary catheter
patent, March 2012
- Dias, Aylvin Jorge Angelo Athanasius; Hensen, Guido Joseph Elisabeth; Belt, Johannes Wilhelmus
- US Patent Document 8,133,580
Methods and materials for fabricating microfluidic devices
patent, April 2012
- DeSimone, Joseph M.; Rolland, Jason P.; Rothrock, Ginger
- US Patent Document 8,158,728
Photocrosslinkable composition comprising a polyorganosiloxane
patent, June 2012
- Pinto, Olivier; Alric, Jerome; Thivillon, Maud
- US Patent Document 8,197,943
Fuser member coating having aliphatic-aromatic fluoropolymers
patent, December 2012
- Moorlag, Carolyn; Hu, Nan-Xing
- US Patent Document 8,337,986
Functionalized halogenated polymers for microencapsulation
patent, January 2013
- Zang, HongMei; Chen, Huiyong Paul; Armoush, Mahmoud-Zohdi
- US Patent Document 8,361,620
Intrastromal refractive surgery by inducing shape change of the cornea
patent, April 2013
- Lai, Shui T.
- US Patent Document 8,409,177
Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes
patent, July 2013
- Chen, Zonghai; Amine, Khalil
- US Patent Document 8,475,688
Lithium ion battery electrolyte including a vitreous eutectic mixture
patent, August 2014
- Halalay, Ion C.; Frisch, Damon R.; Geiculescu, Olt E.
- US Patent Document 8,802,301
Non-flammable electrolyte composition including carbonate-terminated perfluoropolymer and phosphate-terminated or phosphonate-terminated perfluoropolymer and battery using same
patent, January 2017
- Teran, Alexander; Rupert, Benjamin; Nasybulin, Eduard
- US Patent Document 9,540,312
Functionalized phosphorus containing fluoropolymers and electrolyte compositions
patent, January 2017
- Teran, Alexander; Rupert, Benjamin; Nasybulin, Eduard
- US Patent Document 9,543,619
Perfluoropolyether additives for electrochemical applications
patent-application, September 2002
- Marchionni, Giuseppe; Zompatori, Alberto; Chittofrati, Alba
- US Patent Application 10/028310; 20020127475
Thermally stable perfluoropolyethers and processes therefor and therewith
patent-application, February 2003
- Howell, Jon L.; Perez, Erik William; Waterfeld, Alfred
- US Patent Application 09/901975; 20030027732
Process for preparing ionomeric membranes
patent-application, November 2003
- Navarrini, Walter; Panero, Stefania; Scrosati, Bruno
- US Patent Application 10/423027; 20030215719
Hybrid multifocal contact lenses
patent-application, July 2004
- Roffman, Jeffrey H.; Kumar, Ganesh N.; Durland, Scott C.
- US Patent Application 10/348448; 20040141150
Liquid Materials for use in Electrochemical Cells
patent-application, January 2009
- DeSimone, Joseph M.; Kelly, Jennifer Y.; Rolland, Jason P.
- US Patent Application 12/203435; 20090023038
Electrolytic Solution
patent-application, April 2009
- Koh, Meiten; Yamauchi, Akiyoshi
- US Patent Application 11/887543; 20090086408
Anode and Battery
patent-application, April 2009
- Hirose, Takakazu; Nakai, Hideki; Kawase, Kenichi
- US Patent Application 12/262301; 20090111019
Electrolytic Solution
patent-application, May 2009
- Koh, Meiten; Yamauchi, Akiyoshi; Takagahara, Yasuko
- US Patent Application 11/887540; 20090134353
Electrolytic Solution
patent-application, November 2009
- Koh, Meiten; Yamauchi, Akiyoshi; Takagahara, Yasuko
- US Patent Application 11/887548; 20090291364
Lithium-Ion Electrolytes Containing Flame Retardant Additives for Increased Safety Characteristics
patent-application, February 2010
- Smart, Marshall C.; Smith, Kiah A.; Bugga, Ratnakumar V.
- US Patent Application 12/543495; 20100047695
Fluorinated Compositions and Surface Treatments Made Therefrom
patent-application, July 2010
- Dams, Rudolf J.; Martin, Steven J.; Pellerite, Mark J.
- US Patent Application 12/663027; 20100183889
Non-Aqueous Electrolyte Secondary Cell
patent-application, August 2010
- Iwanaga, Masato; Yamashita, Noriko
- US Patent Application 12/710659; 20100216035
Method for Producing Carbonate Compound
patent-application, September 2010
- Okamoto, Hidekazu; Tajima, Kouhei; Okazoe, Takashi
- US Patent Application 12/792231; 20100240912
Electrolyte for a Lithium Ion Battery
patent-application, May 2011
- Halalay, Ion C.; Frisch, Damon R.; Geiculescu, Olt E.
- US Patent Application 12/902120; 20110111308
Multiple Electrolyte Electrochemical Cells
patent-application, November 2011
- Singh, Mohit; Gur, Ilan; Eitouni, Hany Basam
- US Patent Application 13/128232; 20110281173
Lithium Sulfonate Polyazole Solid Polymer Electrolytes in Polymer Electrolyte Lithium Ion Batteries and Supercapacitors, and Processes of Fabrication
patent-application, December 2011
- Benicewicz, Brian C.
- US Patent Application 13/165062; 20110311881
Functionalized Ionic Liquid Electrolytes for Lithium Ion Batteries
patent-application, April 2012
- Zhang, Zhengcheng; Weng, Wei; Zhang, Lu
- US Patent Application 12/895395; 20120082903
Electrolyte Solution and Lithium Ion Secondary Battery Using the Same
patent-application, June 2012
- Ohashi, Asami; Ishii, Yoshiyuki
- US Patent Application 13/376886; 20120141878
Lithium sulfur battery
patent-application, August 2012
- Olschimke, Jens; Bomkamp, Martin; Eicher, Johannes
- US Patent Application 13/504094; 20120214043
Mixture for Abating Combustion by a Li-ion Battery
patent-application, March 2014
- Kountz, Dennis J.; Hoover, James R.; Pruce, George Martin
- US Patent Application 13/973311; 20140060859
Li-ion Battery Having Improved Safety Against Combustion
patent-application, March 2014
- Kountz, Dennis J.; Hoover, James R.; Pruce, George Martin
- US Patent Application 13/973261; 20140065461
Refrigerant Additive Compositions Containing Perfluoropolyethers
patent-application, September 2014
- Leck, Thomas Joseph; Saturno, Thomas Frank; Bell, Gregory A.
- US Patent Application 14/277489; 20140245760
Composition for a Lithium Battery Comprising at Least One Specific Fluorinated Compound as an Organic Solvent and at Least One Lithium Salt
patent-application, April 2015
- Galiano, Herve; Beord, Charlotte; Pierre, Nathalie
- US Patent Application 14/394559; 20150093654
Multi-Phase Electrolyte Lithium Batteries
patent-application, January 2016
- Pratt, Russell Clayton; Eitouni, Hany Basam; Wang, Xiao-Liang
- US Patent Application 14/811664; 20160028114
Ion Conducting Fluoropolymer Carbonates for Alkali Metal Ion Batteries
patent-application, February 2016
- DeSimone, Joseph M.
- US Patent Application 14/779460; 20160043435
Functionalized Fluoropolymers and Electrolyte Compositions
patent-application, August 2016
- Teran, Alexander; Rupert, Benjamin; Nasybulin, Eduard
- US Patent Application 15/012470; 20160221926
Functionalized Fluoropolymers and Electrolyte Compositions
patent-application, August 2016
- Teran, Alexander; Rupert, Benjamin; Nasybulin, Eduard
- US Patent Application 15/012483; 20160226102
Functionalized Fluoropolymers and Electrolyte Compositions
patent-application, August 2016
- Teran, Alexander; Rupert, Benjamin; Nasybulin, Eduard
- US Patent Application 15/012497; 20160226103
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
The preparation of primary poly-hexafluoropropylene oxide halides (poly-HFPO-CF2X where X = I, Br, Cl and F)
journal, October 2004
- Howell, Jon L.; Lu, Norman; Perez, Erik W.
- Journal of Fluorine Chemistry, Vol. 125, Issue 10, p. 1513-1518
Degradation of perfluoropolyethers catalyzed by aluminum oxide
journal, September 1991
- Kasai, Paul H.; Tang, Wing T.; Wheeler, Patrick
- Applied Surface Science, Vol. 51, Issue 3-4, p. 201-211
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012
- Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
- Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
Stability of perfluoroalkylethers
journal, May 1994
- Paciorek, K. J. L.; Kratzer, R. H.
- Journal of Fluorine Chemistry, Vol. 67, Issue 2, p. 169-175
Preparation and properties of polyurethane networks based on α,ω-difunctional poly(hexafluoropropylene oxide)
journal, July 1995
- Proudmore, Martin; Ding, Ji-Feng; Mobbs, Richard H.
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 33, Issue 10, p. 1615-1625
Improved performance of lithium-ion cells with the use of fluorinated carbonate-based electrolytes
journal, April 2003
- Smart, M.C.; Ratnakumar, B.V.; Ryan-Mowrey, V.S.
- Journal of Power Sources, Vol. 119-121, p. 359-367
Solvent-Resistant Photocurable “Liquid Teflon” for Microfluidic Device Fabrication
journal, March 2004
- Rolland, Jason P.; Van Dam, R. Michael; Schorzman, Derek A.
- Journal of the American Chemical Society, Vol. 126, Issue 8, p. 2322-2323
Methacrylic-based solid polymer electrolyte membranes for lithium-based batteries by a rapid UV-curing process
journal, April 2011
- Nair, Jijeesh R.; Gerbaldi, C.; Destro, M.
- Reactive and Functional Polymers, Vol. 71, Issue 4, p. 409-416
Photochemically Cross-Linked Perfluoropolyether-Based Elastomers: Synthesis, Physical Characterization, and Biofouling Evaluation
journal, September 2009
- Hu, Zhaokang; Finlay, John A.; Chen, Liang
- Macromolecules, Vol. 42, Issue 18, p. 6999-7007
Linear perfluoropolyether difunctional oligomers: chemistry, properties and applications
journal, June 1999
- Tonelli, Claudio; Gavezotti, Piero; Strepparola, Ezio
- Journal of Fluorine Chemistry, Vol. 95, Issue 1-2, p. 51-70