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Title: In situ Investigation of Methane Dry Reforming on M-CeO2(111) {M= Co, Ni, Cu} Surfaces: Metal-Support Interactions and the activation of C-H bonds at Low Temperature

Journal Article · · Angewandte Chemie (International Edition)
 [1];  [2];  [3];  [4];  [5];  [1];  [6];  [7];  [8];  [6];  [5];  [9];  [1]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States)
  2. Brookhaven National Lab. (BNL) (China)
  3. Instituto de Fisica Rosario (IFIR), CONICET (Argentina)
  4. Universidad Central de Venezuela (Venezuela)
  5. Univ. College Cork (Ireland)
  6. Charles Univ., Prague (Czech Republic)
  7. Brookhaven National Lab. (BNL) (United Kingdom)
  8. Univ. Central de Venezuela (Venezuela)
  9. Institute of Catalysis - Madrid (Spain)
+ Show Author Affiliations

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0012704; CTQ2015-78823-R
OSTI ID:
1377057
Alternate ID(s):
OSTI ID: 1378788
Report Number(s):
BNL-114204-2017-JA; R&D Project: CO040; KC0302010
Journal Information:
Angewandte Chemie (International Edition), Vol. 56, Issue 42; ISSN 1433-7851
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 97 works
Citation information provided by
Web of Science

References (30)

In-operando elucidation of bimetallic CoNi nanoparticles during high-temperature CH 4 /CO 2 reaction journal September 2017
Control of the Charge State of Metal Atoms on Thin MgO Films journal March 2007
Methane activation on Ni(111): Effects of poisons and step defects journal October 2005
Dry Reforming of Methane on a Highly-Active Ni-CeO 2 Catalyst: Effects of Metal-Support Interactions on C−H Bond Breaking journal May 2016
Theoretical investigation of the methane cracking reaction pathways on Ni (1 1 1) surface journal October 2015
Methane dissociation and adsorption on Ni(111), Pt(111), Ni(100), Pt(100), and Pt(110)-(1×2): Energetic study journal February 2010
Correlation of Methane Activation and Oxide Catalyst Reducibility and Its Implications for Oxidative Coupling journal February 2016
The adsorption and dissociation of methane on cobalt surfaces: thermochemistry and reaction barriers journal January 2014
Au Dimers on Thin MgO(001) Films: Flat and Charged or Upright and Neutral? journal June 2008
Methane activation on Ni and Ru model catalysts journal December 2000
A New Type of Strong Metal–Support Interaction and the Production of H 2 through the Transformation of Water on Pt/CeO 2 (111) and Pt/CeO x /TiO 2 (110) Catalysts journal May 2012
Ab initio calculations of the reaction pathways for methane decomposition over the Cu (111) surface journal August 2011
Mode selectivity in methane dissociative chemisorption on Ni(111) journal January 2013
First-Principles Thermodynamics of Graphene Growth on Cu Surfaces journal August 2011
Mechanism and Site Requirements for Activation and Chemical Conversion of Methane on Supported Pt Clusters and Turnover Rate Comparisons among Noble Metals journal April 2004
A density functional theory study of CH4 dehydrogenation on Co(111) journal August 2010
Controlled Oxidation of Hydrocarbons by the Membrane-Bound Methane Monooxygenase: The Case for a Tricopper Cluster journal August 2008
Efficient Oxidation of Methane to Methanol by Dioxygen Mediated by Tricopper Clusters journal February 2013
Theoretical Studies of the Adsorption of CO and C on Ni(111) and Ni/CeO 2 (111): Evidence of a Strong Metal–Support Interaction journal April 2013
Room temperature activation of methane over Zn modified H-ZSM-5 zeolites: Insight from solid-state NMR and theoretical calculations journal January 2012
Dry Reforming of Methane on a Highly-Active Ni-CeO 2 Catalyst: Effects of Metal-Support Interactions on C−H Bond Breaking journal May 2016
C–H bond activation over metal oxides: A new insight into the dissociation kinetics from density functional theory journal February 2008
Consequences of Surface Oxophilicity of Ni, Ni-Co, and Co Clusters on Methane Activation journal May 2017
C–H Bond Activation of Methane via σ–d Interaction on the IrO 2 (110) Surface: Density Functional Theory Study journal March 2012
Low-temperature activation of methane on the IrO 2 (110) surface journal April 2017
DFT studies of dry reforming of methane on Ni catalyst journal November 2009
Efficient Oxidation of Methane to Methanol by Dioxygen Mediated by Tricopper Clusters journal February 2013
A review of dry (CO 2 ) reforming of methane over noble metal catalysts journal January 2014
Room-Temperature Activation of Methane and Dry Re-forming with CO 2 on Ni-CeO 2 (111) Surfaces: Effect of Ce 3+ Sites and Metal–Support Interactions on C–H Bond Cleavage journal November 2016
Understanding trends in C–H bond activation in heterogeneous catalysis journal October 2016

Cited By (7)

A Fluorogenic AggTag Method Based on Halo‐ and SNAP‐Tags to Simultaneously Detect Aggregation of Two Proteins in Live Cells journal March 2019
Ambient Pressure Photoelectron Spectroscopy: Opportunities in Catalysis from Solids to Liquids and Introducing Time Resolution journal January 2018
Metal Carbide as A Light‐Harvesting and Anticoking Catalysis Support for Dry Reforming of Methane journal October 2019
Syngas production from methane steam reforming and dry reforming reactions over sintering-resistant Ni@SiO2 catalyst journal December 2019
Developing descriptors for CO 2 methanation and CO 2 reforming of CH 4 over Al 2 O 3 supported Ni and low-cost Ni based alloy catalysts journal January 2018
Low-temperature activation of methane on doped single atoms: descriptor and prediction journal January 2018
Structure–function relationship for CO 2 methanation over ceria supported Rh and Ni catalysts under atmospheric pressure conditions journal January 2019

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
catalysis
Surface Science
methane activation
CO2
Hydrogen production