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Title: Magnesium-ion battery-relevant electrochemistry of MgMn2O4: crystallite size effects and the notable role of electrolyte water content

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/c7cc00265c· OSTI ID:1376671
 [1];  [1];  [2]; ORCiD logo [1];  [1]
  1. Stony Brook Univ., Stony Brook, NY (United States)
  2. Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
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MgMn2O4 nanoparticles with crystallite sizes of 11 (MMO-1) and 31 nm (MMO-2) were synthesized and their magnesium-ion battery-relevant electrochemistry was investigated. Here, MMO-1 delivered an initial capacity of 220 mA h g–1 (678 mW h g–1). Electrolyte water content had a profound effect on cycle retention.

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Electricity (OE); USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC00112704
OSTI ID:
1376671
Report Number(s):
BNL-114103-2017-JA; CHCOFS
Journal Information:
ChemComm, Vol. 53, Issue 26; ISSN 1359-7345
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 65 works
Citation information provided by
Web of Science

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Cited By (7)

MgSc 2 Se 4 —A Magnesium Solid Ionic Conductor for All‐Solid‐State Mg Batteries? journal April 2019
Electrolyte Evolution Propelling the Development of Nonlithium Metal–Sulfur Batteries journal May 2019
High magnesium mobility in ternary spinel chalcogenides journal November 2017
Superior high rate capability of MgMn 2 O 4 /rGO nanocomposites as cathode materials for aqueous rechargeable magnesium ion batteries journal January 2018
Three-dimensional hollow spheres of the tetragonal-spinel MgMn 2 O 4 cathode for high-performance magnesium ion batteries journal January 2018
Hollow-sphere iron oxides exhibiting enhanced cycling performance as lithium-ion battery anodes journal January 2019
Rapid room-temperature synthesis of ultrasmall cubic Mg–Mn spinel cathode materials for rechargeable Mg-ion batteries journal January 2019

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