Circular dichroism in photoelectron images from aligned nitric oxide molecules

Sen, Ananya; Pratt, S. T.; Reid, K. L.

doi:10.1063/1.4982218

Title: Circular dichroism in photoelectron images from aligned nitric oxide molecules

Journal Article · Wed May 03 00:00:00 EDT 2017 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.4982218· OSTI ID:1371761

Sen, Ananya ^[1]; Pratt, S. T. ^[1];

^[2]

Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. of Nottingham, Nottingham (United Kingdom)

We have used velocity map photoelectron imaging to study circular dichroism of the photoelectron angular distributions (PADs) of nitric oxide following two-color resonanceenhanced two-photon ionization via selected rotational levels of the A ²Σ⁺, v' = 0 state. By using a circularly polarized pump beam and a counter-propagating, circularly polarized probe beam, cylindrical symmetry is preserved in the ionization process, and the images can be reconstructed using standard algorithms. The VMI set up enables individual ion rotational states to be resolved with excellent collection efficiency, rendering the measurements considerably simpler to perform than previous measurements conducted with a conventional photoelectron spectrometer. The results demonstrate that circular dichroism is observed even when cylindrical symmetry is maintained, and serve as a reminder that dichroism is a general feature of the multiphoton ionization of atoms and molecules. Furthermore, the observed PADs are in good agreement with calculations based on parameters extracted from previous experimental results obtained by using a time-offlight electron spectrometer.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Chemical Sciences, Geosciences, and Biosciences Division; USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1371761

Alternate ID(s):: OSTI ID: 1361854

Journal Information:: Journal of Chemical Physics, Vol. 147, Issue 1; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Vibrationally resolved above-threshold ionization in NO molecules by intense ultrafast two-color laser pulses: An experimental and theoretical study Liu, Yong; Hu, Wenhui; Luo, Sizuo Physical Review A, Vol. 100, Issue 2 https://doi.org/10.1103/physreva.100.023404	journal	August 2019

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