Impact of oleylamine: Oleic acid ratio on the morphology of yttria nanomaterials

Treadwell, LaRico J.; Boyle, Timothy J.; Bell, Nelson S.; Rodriguez, Mark. A.; Muntifering, Brittany R.; Hattar, Khalid

doi:10.1007/s10853-017-1042-5

Title: Impact of oleylamine: Oleic acid ratio on the morphology of yttria nanomaterials

Journal Article · Fri Mar 31 00:00:00 EDT 2017 · Journal of Materials Science

DOI:https://doi.org/10.1007/s10853-017-1042-5· OSTI ID:1371482

Treadwell, LaRico J. ^[1];

^[1]; Bell, Nelson S. ^[1]; Rodriguez, Mark. A. ^[1]; Muntifering, Brittany R. ^[1]; Hattar, Khalid ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

In this paper, the impact on the final morphology of yttria (Y₂O₃) nanoparticles from different ratios (100/0, 90/10, 65/35, and 50/50) of oleylamine (ON) and oleic acid (OA) via a solution precipitation route has been determined. In all instances, powder X-ray diffraction indicated that the cubic Y₂O₃ phase (PDF #00-025-1200) with the space group I-3a (206) had been formed. Analysis of the collected FTIR data revealed the presence of stretches and bends consistent with ON and OA, for all ratios investigated, except the 100/0. Transmission electron microscopy images revealed regular and elongated hexagons were produced for the ON (100/0) sample. As OA was added, the nanoparticle morphology changed to lamellar pillars (90/10), then irregular particles (65/35), and finally plates (50/50). The formation of the hexagonal-shaped nanoparticles was determined to be due to the preferential adsorption of ON onto the {101} planes. As OA was added to the reaction mixture, it was found that the {111} planes were preferentially coated, replacing ON from the surface, resulting in the various morphologies noted. The roles of the ratio of ON/OA in the synthesis of the nanocrystals were elucidated in the formation of the various Y₂O₃ morphologies, as well as a possible growth mechanism based on the experimental data.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1371482

Report Number(s):: SAND-2017-5499J; PII: 1042

Journal Information:: Journal of Materials Science, Vol. 52, Issue 13; ISSN 0022-2461

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 6 works

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Title: Impact of oleylamine: Oleic acid ratio on the morphology of yttria nanomaterials

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