Coherent structural trapping through wave packet dispersion during photoinduced spin state switching

Lemke, Henrik T.; Kjær, Kasper S.; Hartsock, Robert; van Driel, Tim B.; Chollet, Matthieu; Glownia, James M.; Song, Sanghoon; Zhu, Diling; Pace, Elisabetta; Matar, Samir F.; Nielsen, Martin M.; Benfatto, Maurizio; Gaffney, Kelly J.; Collet, Eric; Cammarata, Marco

doi:10.1038/ncomms15342

Title: Coherent structural trapping through wave packet dispersion during photoinduced spin state switching

Journal Article · Wed May 24 00:00:00 EDT 2017 · Nature Communications

DOI:https://doi.org/10.1038/ncomms15342· OSTI ID:1367851

^[1]; Kjær, Kasper S. ^[2]; Hartsock, Robert ^[3]; van Driel, Tim B. ^[4]; Chollet, Matthieu ^[3]; Glownia, James M. ^[3];

^[3]; Zhu, Diling ^[3];

^[5]; Matar, Samir F. ^[6];

^[7]; Benfatto, Maurizio ^[5]; Gaffney, Kelly J. ^[3];

^[8];

^[8]

SLAC National Accelerator Lab., Menlo Park, CA (United States); Paul Scherrer Inst. (PSI), Villigen (Switzerland)
SLAC National Accelerator Lab., Menlo Park, CA (United States); Technical Univ. of Denmark, Lyngby (Denmark); Lund Univ. (Sweden)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States); Technical Univ. of Denmark, Lyngby (Denmark)
Istituto Nazionale di Fisica Nucleare (INFN), Frascati (Italy)
Univ. of Bordeaux (France)
Technical Univ. of Denmark, Lyngby (Denmark)
Univ. of Rennes (France)

The description of ultrafast nonadiabatic chemical dynamics during molecular photo-transformations remains challenging because electronic and nuclear configurations impact each other and cannot be treated independently. Here we gain experimental insights, beyond the Born–Oppenheimer approximation, into the light-induced spin-state trapping dynamics of the prototypical [Fe(bpy)3]2+ compound by time-resolved X-ray absorption spectroscopy at sub-30-femtosecond resolution and high signal-to-noise ratio. The electronic decay from the initial optically excited electronic state towards the high spin state is distinguished from the structural trapping dynamics, which launches a coherent oscillating wave packet (265 fs period), clearly identified as molecular breathing. Throughout the structural trapping, the dispersion of the wave packet along the reaction coordinate reveals details of intramolecular vibronic coupling before a slower vibrational energy dissipation to the solution environment. These findings illustrate how modern time-resolved X-ray absorption spectroscopy can provide key information to unravel dynamic details of photo-functional molecules.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1367851

Journal Information:: Nature Communications, Vol. 8; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 124 works

Citation information provided by
Web of Science

References (29)

Electronic and Molecular Structure of Photoexcited [Ru ^II (bpy) ₃ ] ²⁺ Probed by Picosecond X-ray Absorption Spectroscopy Gawelda, Wojciech; Johnson, Melanie; de Groot, Frank M. F. Journal of the American Chemical Society, Vol. 128, Issue 15 https://doi.org/10.1021/ja054932k	journal	April 2006
Femtosecond X-ray Absorption Spectroscopy at a Hard X-ray Free Electron Laser: Application to Spin Crossover Dynamics Lemke, Henrik T.; Bressler, Christian; Chen, Lin X. The Journal of Physical Chemistry A, Vol. 117, Issue 4 https://doi.org/10.1021/jp312559h	journal	January 2013
Linac Coherent Light Source: The first five years Bostedt, Christoph; Boutet, Sébastien; Fritz, David M. Reviews of Modern Physics, Vol. 88, Issue 1 https://doi.org/10.1103/RevModPhys.88.015007	journal	March 2016
Room-Temperature Photoinduced Electron Transfer in a Prussian Blue Analogue under Hydrostatic Pressure Cafun, Jean-Daniel; Lejeune, Julien; Baudelet, François Angewandte Chemie International Edition, Vol. 51, Issue 36 https://doi.org/10.1002/anie.201203943	journal	August 2012
Quantum yield determinations for subnanosecond-lived excited states and photoproducts: applications to inorganic complexes and photosynthetic models Bergkamp, Michael A.; Chang, Chi Kwong; Netzel, Thomas L. The Journal of Physical Chemistry, Vol. 87, Issue 22 https://doi.org/10.1021/j100245a024	journal	October 1983
MXAN: New improvements for potential and structural refinement Benfatto, Maurizio; Longa, Stefano Della Journal of Physics: Conference Series, Vol. 190 https://doi.org/10.1088/1742-6596/190/1/012031	journal	November 2009
Achieving few-femtosecond time-sorting at hard X-ray free-electron lasers Harmand, M.; Coffee, R.; Bionta, M. R. Nature Photonics, Vol. 7, Issue 3 https://doi.org/10.1038/nphoton.2013.11	journal	February 2013
Femtosecond laser control of a chemical reaction Potter, E. D.; Herek, J. L.; Pedersen, S. Nature, Vol. 355, Issue 6355 https://doi.org/10.1038/355066a0	journal	January 1992
Femtosecond XANES Study of the Light-Induced Spin Crossover Dynamics in an Iron(II) Complex Bressler, Ch.; Milne, C.; Pham, V. -T. Science, Vol. 323, Issue 5913 https://doi.org/10.1126/science.1165733	journal	January 2009
Observing Solvation Dynamics with Simultaneous Femtosecond X-ray Emission Spectroscopy and X-ray Scattering Haldrup, Kristoffer; Gawelda, Wojciech; Abela, Rafael The Journal of Physical Chemistry B, Vol. 120, Issue 6 https://doi.org/10.1021/acs.jpcb.5b12471	journal	February 2016
Direct observation of collective modes coupled to molecular orbital-driven charge transfer Ishikawa, T.; Hayes, S. A.; Keskin, S. Science, Vol. 350, Issue 6267 https://doi.org/10.1126/science.aab3480	journal	December 2015
Vibrational Coherences and Relaxation in the High-Spin State of Aqueous [Fe ^II (bpy) ₃ ] ²⁺ Consani, Cristina; Prémont-Schwarz, Mirabelle; ElNahhas, Amal Angewandte Chemie International Edition, Vol. 48, Issue 39 https://doi.org/10.1002/anie.200902728	journal	September 2009
Tracking excited-state charge and spin dynamics in iron coordination complexes Zhang, Wenkai; Alonso-Mori, Roberto; Bergmann, Uwe Nature, Vol. 509, Issue 7500 https://doi.org/10.1038/nature13252	journal	May 2014
Sub-50-fs photoinduced spin crossover in [Fe(bpy)3]2+ Auböck, Gerald; Chergui, Majed Nature Chemistry, Vol. 7, Issue 8 https://doi.org/10.1038/nchem.2305	journal	July 2015
Ultrafast Deactivation Mechanism of the Excited Singlet in the Light-Induced Spin Crossover of [Fe(2,2′-bipyridine) ₃ ] ²⁺ Sousa, Carmen; de Graaf, Coen; Rudavskyi, Andrii Chemistry - A European Journal, Vol. 19, Issue 51 https://doi.org/10.1002/chem.201302992	journal	November 2013
Sequential Activation of Molecular Breathing and Bending during Spin-Crossover Photoswitching Revealed by Femtosecond Optical and X-Ray Absorption Spectroscopy Cammarata, Marco; Bertoni, Roman; Lorenc, Maciej Physical Review Letters, Vol. 113, Issue 22 https://doi.org/10.1103/PhysRevLett.113.227402	journal	November 2014
The X-ray Pump–Probe instrument at the Linac Coherent Light Source Chollet, Matthieu; Alonso-Mori, Roberto; Cammarata, Marco Journal of Synchrotron Radiation, Vol. 22, Issue 3 https://doi.org/10.1107/S1600577515005135	journal	April 2015
Femtochemistry: Atomic-Scale Dynamics of the Chemical Bond ^† Zewail, Ahmed H. The Journal of Physical Chemistry A, Vol. 104, Issue 24 https://doi.org/10.1021/jp001460h	journal	June 2000
Geometrical fitting of experimental XANES spectra by a full multiple-scattering procedure Benfatto, M.; Della Longa, S. Journal of Synchrotron Radiation, Vol. 8, Issue 4 https://doi.org/10.1107/S0909049501006422	journal	June 2001
Self-Referenced Coherent Diffraction X-Ray Movie of Ångstrom- and Femtosecond-Scale Atomic Motion Glownia, J. M.; Natan, A.; Cryan, J. P. Physical Review Letters, Vol. 117, Issue 15 https://doi.org/10.1103/PhysRevLett.117.153003	journal	October 2016
Light-induced excited spin state trapping in a transition-metal complex: The hexa-1-propyltetrazole-iron (II) tetrafluoroborate spin-crossover system Decurtins, S.; Gütlich, P.; Köhler, C. P. Chemical Physics Letters, Vol. 105, Issue 1 https://doi.org/10.1016/0009-2614(84)80403-0	journal	March 1984
Direct Probing of Spin State Dynamics Coupled with Electronic and Structural Modifications by Picosecond Time-Resolved XAFS Nozawa, Shunsuke; Sato, Tokushi; Chollet, Matthieu Journal of the American Chemical Society, Vol. 132, Issue 1 https://doi.org/10.1021/ja907460b	journal	January 2010
Ab Initio Molecular Dynamics Study of an Aqueous Solution of [Fe(bpy) ₃ ](Cl) ₂ in the Low-Spin and in the High-Spin States Lawson Daku, Latévi Max; Hauser, Andreas The Journal of Physical Chemistry Letters, Vol. 1, Issue 12 https://doi.org/10.1021/jz100548m	journal	May 2010
A time-dependent order parameter for ultrafast photoinduced phase transitions Beaud, P.; Caviezel, A.; Mariager, S. O. Nature Materials, Vol. 13, Issue 10 https://doi.org/10.1038/nmat4046	journal	August 2014
Direct observation of ultrafast collective motions in CO myoglobin upon ligand dissociation Barends, T. R. M.; Foucar, L.; Ardevol, A. Science, Vol. 350, Issue 6259 https://doi.org/10.1126/science.aac5492	journal	September 2015
Vibrational Coherences and Relaxation in the High-Spin State of Aqueous [Fe ^II (bpy) ₃ ] ²⁺ Consani, Cristina; Prémont-Schwarz, Mirabelle; ElNahhas, Amal Angewandte Chemie, Vol. 121, Issue 39 https://doi.org/10.1002/ange.200902728	journal	September 2009
Femtosecond laser control of a chemical reaction Potter, E. D.; Herek, J. L.; Pedersen, S. Femtochemistry: Ultrafast Dynamics of the Chemical Bond https://doi.org/10.1142/9789814287609_0047	book	September 1994
Room‐Temperature Photoinduced Electron Transfer in a Prussian Blue Analogue under Hydrostatic Pressure Cafun, Jean‐Daniel; Lejeune, Julien; Baudelet, François Angewandte Chemie, Vol. 124, Issue 36 https://doi.org/10.1002/ange.201203943	journal	August 2012
Self-referenced coherent diffraction x-ray movie of Angstrom- and femtosecond-scale atomic motion Glownia, J. M.; Natan, A.; Cryan, J. P. arXiv https://doi.org/10.48550/arxiv.1608.03039	text	January 2016

Cited By (42)

Molecular Spin Crossover Materials: Review of the Lattice Dynamical Properties Molnár, Gábor; Mikolasek, Mirko; Ridier, Karl Annalen der Physik, Vol. 531, Issue 10 https://doi.org/10.1002/andp.201900076	journal	August 2019
The First Observation of Hidden Hysteresis in an Iron(III) Spin‐Crossover Complex Boonprab, Theerapoom; Lee, Seok J.; Telfer, Shane G. Angewandte Chemie, Vol. 131, Issue 34 https://doi.org/10.1002/ange.201907619	journal	July 2019
Hot Branching Dynamics in a Light‐Harvesting Iron Carbene Complex Revealed by Ultrafast X‐ray Emission Spectroscopy Tatsuno, Hideyuki; Kjær, Kasper S.; Kunnus, Kristjan Angewandte Chemie, Vol. 132, Issue 1 https://doi.org/10.1002/ange.201908065	journal	October 2019
Structural Dynamics upon Photoexcitation in a Spin Crossover Crystal Probed with Femtosecond Electron Diffraction Jiang, Yifeng; Liu, Lai Chung; Müller-Werkmeister, Henrike M. Angewandte Chemie International Edition, Vol. 56, Issue 25 https://doi.org/10.1002/anie.201702497	journal	May 2017
The First Observation of Hidden Hysteresis in an Iron(III) Spin-Crossover Complex Boonprab, Theerapoom; Lee, Seok J.; Telfer, Shane G. Angewandte Chemie International Edition, Vol. 58, Issue 34 https://doi.org/10.1002/anie.201907619	journal	July 2019
Hot Branching Dynamics in a Light‐Harvesting Iron Carbene Complex Revealed by Ultrafast X‐ray Emission Spectroscopy Tatsuno, Hideyuki; Kjær, Kasper S.; Kunnus, Kristjan Angewandte Chemie International Edition, Vol. 59, Issue 1 https://doi.org/10.1002/anie.201908065	journal	January 2020
Disentangling Ultrafast Electronic and Structural Dynamics with X-Ray Lasers Collet, Eric; Cammarata, Marco Chemistry - A European Journal, Vol. 24, Issue 59 https://doi.org/10.1002/chem.201802105	journal	September 2018
Tracking multiple components of a nuclear wavepacket in photoexcited Cu(I)-phenanthroline complex using ultrafast X-ray spectroscopy Katayama, Tetsuo; Northey, Thomas; Gawelda, Wojciech Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11499-w	journal	August 2019
Vibrational wavepacket dynamics in Fe carbene photosensitizer determined with femtosecond X-ray emission and scattering Kunnus, Kristjan; Vacher, Morgane; Harlang, Tobias C. B. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14468-w	journal	January 2020
Vibrational coherences in manganese single-molecule magnets after ultrafast photoexcitation Liedy, Florian; Eng, Julien; McNab, Robbie Nature Chemistry https://doi.org/10.1038/s41557-020-0431-6	journal	March 2020
Impulsive UV-pump/X-ray probe study of vibrational dynamics in glycine Mincigrucci, Riccardo; Kowalewski, Markus; Rouxel, Jérémy R. Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-33607-4	journal	October 2018
Spin-state dependence of the structural and vibrational properties of solvated iron( ii ) polypyridyl complexes from AIMD simulations: II. aqueous [Fe(tpy) ₂ ]Cl ₂ Lawson Daku, Latévi M. Physical Chemistry Chemical Physics, Vol. 21, Issue 2 https://doi.org/10.1039/c8cp06671j	journal	January 2019
Photoinduced anisotropic distortion as the electron trapping site of tungsten trioxide by ultrafast W L ₁ -edge X-ray absorption spectroscopy with full potential multiple scattering calculations Koide, Akihiro; Uemura, Yohei; Kido, Daiki Physical Chemistry Chemical Physics, Vol. 22, Issue 5 https://doi.org/10.1039/c9cp01332f	journal	January 2020
A first peek into sub-picosecond dynamics of spin energy levels in magnetic biomolecules Rosaleny, Lorena E.; Zinovjev, Kirill; Tuñón, Iñaki Physical Chemistry Chemical Physics, Vol. 21, Issue 21 https://doi.org/10.1039/c9cp01909j	journal	January 2019
Ligand manipulation of charge transfer excited state relaxation and spin crossover in [Fe(2,2′-bipyridine) ₂ (CN) ₂ ] Kjær, Kasper S.; Zhang, Wenkai; Alonso-Mori, Roberto Structural Dynamics, Vol. 4, Issue 4 https://doi.org/10.1063/1.4985017	journal	July 2017
Perspective: Opportunities for ultrafast science at SwissFEL Abela, Rafael; Beaud, Paul; van Bokhoven, Jeroen A. Structural Dynamics, Vol. 4, Issue 6 https://doi.org/10.1063/1.4997222	journal	November 2017
Light-induced magnetization changes in aggregated and isolated cobalt ferrite nanoparticles Brinzari, Tatiana V.; Rajan, Divya; Ferreira, Cauê F. Journal of Applied Physics, Vol. 124, Issue 10 https://doi.org/10.1063/1.5040327	journal	September 2018
Hard X-ray induced fast secondary electron cascading processes in solids Mecseki, K.; Höppner, H.; Büscher, M. Applied Physics Letters, Vol. 113, Issue 11 https://doi.org/10.1063/1.5046070	journal	September 2018
Ultrafast molecular photophysics in the deep-ultraviolet Chergui, Majed The Journal of Chemical Physics, Vol. 150, Issue 7 https://doi.org/10.1063/1.5082644	journal	February 2019
A versatile experimental system for tracking ultrafast chemical reactions with X-ray free-electron lasers Katayama, Tetsuo; Nozawa, Shunsuke; Umena, Yasufumi Structural Dynamics, Vol. 6, Issue 5 https://doi.org/10.1063/1.5111795	journal	September 2019
Photoinduced valence tautomerism of a cobalt-dioxolene complex revealed with femtosecond M-edge XANES Ash, Ryan; Zhang, Kaili; Vura-Weis, Josh The Journal of Chemical Physics, Vol. 151, Issue 10 https://doi.org/10.1063/1.5115227	journal	September 2019
Photoselective MLCT to d-d pathways for light-induced excited spin state trapping Zerdane, S.; Cammarata, M.; Iasco, O. The Journal of Chemical Physics, Vol. 151, Issue 17 https://doi.org/10.1063/1.5127507	journal	November 2019
Chemical interactions and dynamics with femtosecond X-ray spectroscopy and the role of X-ray free-electron lasers Wernet, Philippe Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2145 https://doi.org/10.1098/rsta.2017.0464	journal	April 2019
Scientific instrument Femtosecond X-ray Experiments (FXE): instrumentation and baseline experimental capabilities Galler, Andreas; Gawelda, Wojciech; Biednov, Mykola Journal of Synchrotron Radiation, Vol. 26, Issue 5 https://doi.org/10.1107/s1600577519006647	journal	August 2019
Lattice phonon modes of the spin crossover crystal [Fe(phen)2(NCS)2] studied by THz, IR, Raman spectroscopies and DFT calculations Collet, Eric; Azzolina, Giovanni; Ichii, Tomoaki The European Physical Journal B, Vol. 92, Issue 1 https://doi.org/10.1140/epjb/e2018-90553-2	journal	January 2019
Hole dynamics in a photovoltaic donor-acceptor couple revealed by simulated time-resolved X-ray absorption spectroscopy Khalili, Khadijeh; Inhester, Ludger; Arnold, Caroline Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2019-02799	text	January 2019
Initial metal-metal bond breakage detected by fs X-ray scattering in the photolysis of Ru3(CO)12 in cyclohexane at 400 nm Kong, Q. J.; Laursen, M. G.; Haldrup, K. Zenodo https://doi.org/10.5281/zenodo.3237041	text	January 2019
Structural Dynamics upon Photoexcitation in a Spin Crossover Crystal Probed with Femtosecond Electron Diffraction Jiang, Yifeng; Liu, Lai Chung; Müller-Werkmeister, Henrike M. Angewandte Chemie, Vol. 129, Issue 25 https://doi.org/10.1002/ange.201702497	journal	May 2017
Sub-50 fs broadband absorption spectroscopy with tunable excitation: putting the analysis of ultrafast molecular dynamics on solid ground Megerle, U.; Pugliesi, I.; Schriever, C. Applied Physics B, Vol. 96, Issue 2-3 https://doi.org/10.1007/s00340-009-3610-0	journal	June 2009
Initial metal–metal bond breakage detected by fs X-ray scattering in the photolysis of Ru ₃ (CO) ₁₂ in cyclohexane at 400 nm Kong, Q. Y.; Laursen, M. G.; Haldrup, K. Photochemical & Photobiological Sciences, Vol. 18, Issue 2 https://doi.org/10.1039/c8pp00420j	journal	January 2019
The restricted active space followed by second-order perturbation theory method: Theory and application to the study of CuO2 and Cu2O2 systems Malmqvist, Per Åke; Pierloot, Kristine; Shahi, Abdul Rehaman Moughal The Journal of Chemical Physics, Vol. 128, Issue 20 https://doi.org/10.1063/1.2920188	journal	May 2008
Hard X-ray induced fast secondary electron cascading processes in solids Mecseki, K.; Höppner, H.; Büscher, M. Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2018-03517	text	January 2018
Chemical interactions and dynamics with femtosecond X-ray spectroscopy and the role of X-ray free-electron lasers Wernet, Philippe Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2019-02735	text	January 2019
Perspective: Opportunities for ultrafast science at SwissFEL Abela, Rafael; Beaud, Paul; Van Bokhoven, Jeroen A. AIP Publishing https://doi.org/10.7892/boris.114739	text	January 2017
Hole dynamics in a photovoltaic donor-acceptor couple revealed by simulated time-resolved X-ray absorption spectroscopy Khalili, Khadijeh; Inhester, Ludger; Arnold, Caroline Structural Dynamics, Vol. 6, Issue 4 https://doi.org/10.1063/1.5097653	journal	July 2019
Vibrational wavepacket dynamics in Fe carbene photosensitizer determined with femtosecond X-ray emission and scattering Kunnus, Kristjan; Vacher, Morgane; Harlang, Tobias C. B. Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2021-00565	text	January 2020
Improved charge transfer multiplet method to simulate M - and L -edge X-ray absorption spectra of metal-centered excited states Zhang, Kaili; Girolami, Gregory S.; Vura-Weis, Josh International Union of Crystallography (IUCr) https://doi.org/10.1107/s1600577518009517/il5004sup2.pdf	text	January 2018
Vibrational Coherences in Manganese Single-molecule Magnets after Ultrafast Photoexcitation Liedy, Florian; McNab, Robbie; Eng, Julien https://doi.org/10.26434/chemrxiv.7485011	posted_content	December 2018
Tracking multiple components of a nuclear wavepacket in photoexcited Cu(I)-phenanthroline complex using ultrafast X-ray spectroscopy Katayama, Tetsuo; Northey, Thomas; Gawelda, Wojciech Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2020-00136	text	January 2019
Hot Branching Dynamics in a Light‐Harvesting Iron Carbene Complex Revealed by Ultrafast X‐ray Emission Spectroscopy Tatsuno, Hideyuki; Kjær, Kasper S.; Kunnus, Kristjan Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2021-00416	text	January 2020
Perspective: Opportunities for ultrafast science at SwissFEL Abela, Rafael; Beaud, Paul; Van Bokhoven, Jeroen A. ETH Zurich https://doi.org/10.3929/ethz-b-000231826	text	January 2017
Perspective: THz-driven nuclear dynamics from solids to molecules Peter, Hamm,; Markus, Meuwly,; L., Johnson, Steve ETH Zurich https://doi.org/10.3929/ethz-b-000228312	text	January 2017

Similar Records

Ultrafast X-ray Transient Absorption Spectroscopy of Gas-Phase Photochemical Reactions: A New Universal Probe of Photoinduced Molecular Dynamics

Journal Article · Wed Nov 21 00:00:00 EST 2018 · Accounts of Chemical Research · OSTI ID:1367851

Bhattacherjee, Aditi; Leone, Stephen R.

Mechanistic Studies of Photoinduced Spin Crossover and Electron Transfer in Inorganic Complexes

Journal Article · Thu Mar 19 00:00:00 EDT 2015 · Accounts of Chemical Research · OSTI ID:1367851

Zhang, Wenkai; Gaffney, Kelly J.

Excited-State Dynamics during Primary C–I Homolysis in Acetyl Iodide Revealed by Ultrafast Core-Level Spectroscopy

Journal Article · Thu Apr 27 00:00:00 EDT 2023 · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory · OSTI ID:1367851

Troß, Jan; Carter-Fenk, Kevin; Cole-Filipiak, Neil Charles; +5 more

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS

Title: Coherent structural trapping through wave packet dispersion during photoinduced spin state switching

Citation Formats

References (29)

Cited By (42)

Similar Records

Related Subjects