The redox chemistry of neptunium in γ-irradiated aqueous nitric acid in the presence of an organic phase
Journal Article
·
· Journal of Radioanalytical and Nuclear Chemistry
- Idaho National Lab. (INL), Idaho Falls, ID (United States)
- Oregon State Univ., Corvallis, OR (United States); Academy of Sciences of the Czech Republic (ASCR), Prague (Czech Republic)
- Oregon State Univ., Corvallis, OR (United States)
The radiolytic changes in oxidation state for solutions of initially Np(V) and/or Np(VI) were investigated by gamma-irradiation in conjunction with UV/Vis spectroscopy of the aqueous phase. Samples were irradiated in varying concentrations of nitric acid, and with or without the presence of 30% TBP in dodecane. At short irradiation times Np(V) was oxidized to Np(VI), even in the presence of the organic phase. Upon the radiolytic production of sufficient amounts of nitrous acid, reduction of Np(VI) to Np(V) occurred in both phases. This was accompanied by stripping of the previously extracted Np(VI). Nitric acid concentrations of 6 M mitigated this reduction.
- Research Organization:
- Idaho National Lab. (INL), Idaho Falls, ID (United States)
- Sponsoring Organization:
- USDOE Office of Nuclear Energy (NE)
- Grant/Contract Number:
- AC07-05ID14517
- OSTI ID:
- 1358433
- Report Number(s):
- INL/JOU-15-36192; PII: 4530
- Journal Information:
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 308, Issue 3; ISSN 0236-5731
- Publisher:
- SpringerCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 5 works
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