X-ray Crystal Truncation Rod Studies of Surface Oxidation and Reduction on Pt(111)

Liu, Yihua; Barbour, Andi; Komanicky, Vladimir; You, Hoydoo

doi:10.1021/acs.jpcc.6b00492

Title: X-ray Crystal Truncation Rod Studies of Surface Oxidation and Reduction on Pt(111)

Journal Article · Fri Feb 26 00:00:00 EST 2016 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.6b00492· OSTI ID:1352615

Liu, Yihua ^[1]; Barbour, Andi ^[1]; Komanicky, Vladimir ^[2]; You, Hoydoo ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)
Safarik Univ., Kosice (Slovakia)

Here, we present X-ray crystal truncation rods measurements of Pt(111) surface under electrochemical conditions. Analyses of crystal truncation rods reveal that surface oxide formation buckles the top surface layer of platinum to two different heights at the potential (0.95 V vs RHE) below the so-called place-exchange potential. While the anti-Bragg intensity, sensitive to the top surface layer, drops in response to the anodic charge transfers, its responses to the cathodic charge transfers are significantly delayed. Implications to the surface oxidation and reduction behaviors are discussed.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1352615

Journal Information:: Journal of Physical Chemistry. C, Vol. 120, Issue 29; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 35 works

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Oscillations in the Electro-Oxidation of Thiourea on Platinum Electrode Studied by On-Line HPLC Zhang, W.; Liu, Y.; Luo, H. Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.1361914jes	journal	January 2019
Thermodynamics of the formation of surface PtO ₂ stripes on Pt(111) in the absence of subsurface oxygen Hanselman, Selwyn; McCrum, Ian T.; Rost, Marcel J. Physical Chemistry Chemical Physics, Vol. 22, Issue 19 https://doi.org/10.1039/c9cp05107d	journal	January 2020
Atomic-Scale Identification of the Electrochemical Roughening of Platinum Jacobse, Leon; Rost, Marcel J.; Koper, Marc T. M. ACS Central Science, Vol. 5, Issue 12 https://doi.org/10.1021/acscentsci.9b00782	journal	November 2019

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