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Title: Electrolytes comprising metal amide and metal chlorides for multivalent battery

Patent ·
OSTI ID:1347538
; ; ;

An electrolyte includes compounds of formula M.sup.1X.sub.n and M.sup.2Z.sub.m; and a solvent wherein M.sup.1 is Mg, Ca, Sr, Ba, Sc, Ti, Al, or Zn; M.sup.2 is Mg, Ca, Sr, Ba, Sc, Ti, Al, or Zn; X is a group forming a covalent bond with M.sup.1; Z is a halogen or pseudo-halogen; n is 1, 2, 3, 4, 5, or 6; and m is 1, 2, 3, 4, 5, or 6.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
Assignee:
UCHICAGO ARGONNE, LLC
Patent Number(s):
9,601,801
Application Number:
14/335,604
OSTI ID:
1347538
Resource Relation:
Patent File Date: 2014 Jul 18
Country of Publication:
United States
Language:
English

References (10)

Catalytic composition and a process for oligomerizing ethylene, in particular to 1-hexene patent December 2004
Electrochemical device with a magnesium anode and a stable, safe electrolyte compatible with sulfur patent-application May 2012
High Voltage Rechargeable Magnesium Batteries Having A Non-Aqueous Electrolyte patent-application September 2013
Prototype systems for rechargeable magnesium batteries journal October 2000
Nonaqueous Electrochemistry of Magnesium
  • Gregory, Thomas D.; Hoffman, Ronald J.; Winterton, Richard C.
  • Journal of The Electrochemical Society, Vol. 137, Issue 3, p. 775-780 https://doi.org/10.1149/1.2086553
journal January 1990
Molten salt synthesis (MSS) of Cu2Mo6S8—New way for large-scale production of Chevrel phases journal June 2006
Plating of magnesium from organic solvents journal February 1996
On the electrochemical behavior of magnesium electrodes in polar aprotic electrolyte solutions journal May 1999
Electrolyte Solutions with a Wide Electrochemical Window for Rechargeable Magnesium Batteries journal January 2008
Corrosion of magnesium electrolytes: chlorides – the culprit journal December 2012

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
25 ENERGY STORAGE
36 MATERIALS SCIENCE