Self-Assembled Fe-N-Doped Carbon Nanotube Aerogels with Single-Atom Catalyst Feature as High-Efficiency Oxygen Reduction Electrocatalysts

Zhu, Chengzhou; Fu, Shaofang; Song, Junhua; Shi, Qiurong; Su, Dong; Engelhard, Mark H.; Li, Xiaolin; Xiao, Dongdong; Li, Dongsheng; Estevez, Luis; Du, Dan; Lin, Yuehe

doi:10.1002/smll.201603407

Title: Self-Assembled Fe-N-Doped Carbon Nanotube Aerogels with Single-Atom Catalyst Feature as High-Efficiency Oxygen Reduction Electrocatalysts

Journal Article · Mon Feb 06 00:00:00 EST 2017 · Small

DOI:https://doi.org/10.1002/smll.201603407· OSTI ID:1347291

Zhu, Chengzhou ^[1]; Fu, Shaofang ^[1]; Song, Junhua ^[1]; Shi, Qiurong ^[1]; Su, Dong ^[2]; Engelhard, Mark H. ^[3]; Li, Xiaolin ^[4]; Xiao, Dongdong ^[3]; Li, Dongsheng ^[3]; Estevez, Luis ^[4]; Du, Dan ^[1]; Lin, Yuehe ^[5]

School of Mechanical and Materials Engineering, Washington State University, Pullman WA 99164 USA
Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton NY 11973 USA
Environmental Molecular Science Laboratory, Pacific Northwest National Laboratory, Richland WA 99354 USA
Energy and Environmental Directory, Pacific Northwest National Laboratory, Richland WA 99354 USA
School of Mechanical and Materials Engineering, Washington State University, Pullman WA 99164 USA; Environmental Molecular Science Laboratory, Pacific Northwest National Laboratory, Richland WA 99354 USA

In this study, self-assembled M–N-doped carbon nanotube aerogels with single-atom catalyst feature are for the first time reported through one-step hydrothermal route and subsequent facile annealing treatment. By taking advantage of the porous nanostructures, 1D nanotubes as well as single-atom catalyst feature, the resultant Fe–N-doped carbon nanotube aerogels exhibit excellent oxygen reduction reaction electrocatalytic performance even better than commercial Pt/C in alkaline solution.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704; AC05-76RL01830

OSTI ID:: 1347291

Report Number(s):: BNL-113588-2017-JA; R&D Project: 16060; 16060; KC0403020

Journal Information:: Small, Vol. 13, Issue 15; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 260 works

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Puffing Up Energetic Metal-Organic Frameworks to Large Carbon Networks with Hierarchical Porosity and Atomically Dispersed Metal Sites Zhao, Ruo; Liang, Zibin; Gao, Song Angewandte Chemie, Vol. 131, Issue 7 https://doi.org/10.1002/ange.201811126	journal	December 2018
Theoretical study of single transition metal atom modified MoP as a nitrogen reduction electrocatalyst Han, Miaomiao; Wang, Guozhong; Zhang, Haimin Physical Chemistry Chemical Physics, Vol. 21, Issue 11 https://doi.org/10.1039/c9cp00621d	journal	January 2019
Enhanced Electrocatalytic Activity and Stability toward the Oxygen Reduction Reaction with Unprotected Pt Nanoclusters Liu, Jing; Yin, Jiao; Feng, Bo Nanomaterials, Vol. 8, Issue 11 https://doi.org/10.3390/nano8110955	journal	November 2018
Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles Liu, Lichen; Corma, Avelino Chemical Reviews, Vol. 118, Issue 10 https://doi.org/10.1021/acs.chemrev.7b00776	journal	April 2018

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77 NANOSCIENCE AND NANOTECHNOLOGY
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Aerogels
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single-atom catalysts
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Title: Self-Assembled Fe-N-Doped Carbon Nanotube Aerogels with Single-Atom Catalyst Feature as High-Efficiency Oxygen Reduction Electrocatalysts

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