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Title: One-dimensional biomass fast pyrolysis model with reaction kinetics integrated in an Aspen Plus Biorefinery Process Model

Journal Article · · ACS Sustainable Chemistry & Engineering
 [1];  [2];  [2]; ORCiD logo [3]
  1. DWH Process Consulting, Centennial, CO (United States)
  2. Colorado School of Mines, Golden, CO (United States)
  3. National Renewable Energy Lab. (NREL), Golden, CO (United States)

A biomass fast pyrolysis reactor model with detailed reaction kinetics and one-dimensional fluid dynamics was implemented in an equation-oriented modeling environment (Aspen Custom Modeler). Portions of this work were detailed in previous publications; further modifications have been made here to improve stability and reduce execution time of the model to make it compatible for use in large process flowsheets. The detailed reactor model was integrated into a larger process simulation in Aspen Plus and was stable for different feedstocks over a range of reactor temperatures. Sample results are presented that indicate general agreement with experimental results, but with higher gas losses caused by stripping of the bio-oil by the fluidizing gas in the simulated absorber/condenser. Lastly, this integrated modeling approach can be extended to other well-defined, predictive reactor models for fast pyrolysis, catalytic fast pyrolysis, as well as other processes.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1346539
Report Number(s):
NREL/JA-5100-67468
Journal Information:
ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 3; ISSN 2168-0485
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 33 works
Citation information provided by
Web of Science

References (10)

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Kinetic modeling of the thermal degradation and combustion of biomass journal May 2014
Evaluating the effect of potassium on cellulose pyrolysis reaction kinetics journal March 2015

Cited By (2)

Advancing catalytic fast pyrolysis through integrated multiscale modeling and experimentation: Challenges, progress, and perspectives
  • Ciesielski, Peter N.; Pecha, M. Brennan; Bharadwaj, Vivek S.
  • Wiley Interdisciplinary Reviews: Energy and Environment, Vol. 7, Issue 4 https://doi.org/10.1002/wene.297
journal April 2018
A rigorous process modeling methodology for biomass fast pyrolysis with an entrained‐flow reactor journal August 2019