Bandgap- and local field-dependent photoactivity of Ag/black phosphorus nanohybrids

Lei, Wanying; Zhang, Tingting; Liu, Ping; Rodriguez, Jose A.; Liu, Gang; Liu, Minghua

doi:10.1021/acscatal.6b02520

Title: Bandgap- and local field-dependent photoactivity of Ag/black phosphorus nanohybrids

Journal Article · Tue Oct 18 00:00:00 EDT 2016 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.6b02520· OSTI ID:1345735

Lei, Wanying ^[1]; Zhang, Tingting ^[2]; Liu, Ping ^[3]; Rodriguez, Jose A. ^[3]; Liu, Gang ^[2]; Liu, Minghua ^[2]

National Center for Nanoscience and Technology, Beijing (People's Republic of China); Peking Univ., Beijing (People's Republic of China); Univ. of Chinese Academy of Sciences, Beijing (People's Republic of China)
National Center for Nanoscience and Technology, Beijing (People's Republic of China)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Black phosphorus (BP) is the most exciting post-graphene layered nanomaterial that serendipitously bridges the 2D materials gap between semimetallic graphene and large bandgap transition-metal dichalcogenides in terms of high charge-carrier mobility and tunable direct bandgap, yet research into BP-based solar to chemical energy conversion is still in its infancy. Herein, a novel hybrid photocatalyst with Ag nanoparticles supported on BP nanosheets is prepared using a chemical reduction approach. Spin-polarized density functional theory (DFT) calculations show that Ag nanoparticles are stabilized on BP by covalent bonds at the Ag/BP interface and Ag–Ag interactions. In the visible-light photocatalysis of rhodamine B by Ag/BP plasmonic nanohybrids, a significant rise in photoactivity compared with pristine BP nanosheets is observed either by decreasing BP layer thickness or increasing Ag particle size, with the greatest enhancement being up to ~20-fold. By virtue of finite-difference time domain (FDTD) simulations and photocurrent measurements, we give insights into the enhanced photocatalytic performance of Ag/BP nanohybrids, including the effects of BP layer thickness and Ag particle size. In comparison with BP, Ag/BP nanohybrids present intense local field amplification at the perimeter of Ag NPs, which is increased by either decreasing the BP layer thickness from multiple to few layers or increasing the Ag particle size from 20 to 40 nm. Additionally, when the BP layer thickness is decreased from multiple to few layers, the bandgap becomes favorable to generate more strongly oxidative holes in the proximity of the Ag/BP interface to enhance photoactivity. Our findings illustrate a synergy between locally enhanced electric fields and BP bandgap, in which BP layer thickness and Ag particle size can be independently tuned to enhance photoactivity. Lastly, this study may open a new avenue for further exploiting BP-based plasmonic nanostructures in photocatalysis, photodetectors, and photovoltaics.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1345735

Report Number(s):: BNL-113575-2017-JA; R&D Project: CO040; KC0302010; TRN: US1701364

Journal Information:: ACS Catalysis, Vol. 6, Issue 12; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 119 works

Citation information provided by
Web of Science

References (73)

Plasmonics for improved photovoltaic devices Atwater, Harry A.; Polman, Albert Nature Materials, Vol. 9, Issue 3, p. 205-213 https://doi.org/10.1038/nmat2629	journal	February 2010
Photovoltaic materials: Present efficiencies and future challenges Polman, A.; Knight, M.; Garnett, E. C. Science, Vol. 352, Issue 6283 https://doi.org/10.1126/science.aad4424	journal	April 2016
Graphene and Graphene-like Two-Dimensional Materials in Photodetection: Mechanisms and Methodology Sun, Zhenhua; Chang, Haixin ACS Nano, Vol. 8, Issue 5 https://doi.org/10.1021/nn500508c	journal	April 2014
Photodetection with Active Optical Antennas Knight, M. W.; Sobhani, H.; Nordlander, P. Science, Vol. 332, Issue 6030, p. 702-704 https://doi.org/10.1126/science.1203056	journal	May 2011
Nano-photocatalytic Materials: Possibilities and Challenges Tong, Hua; Ouyang, Shuxin; Bi, Yingpu Advanced Materials, Vol. 24, Issue 2 https://doi.org/10.1002/adma.201102752	journal	October 2011
Toward Solar Fuels: Photocatalytic Conversion of Carbon Dioxide to Hydrocarbons Roy, Somnath C.; Varghese, Oomman K.; Paulose, Maggie ACS Nano, Vol. 4, Issue 3 https://doi.org/10.1021/nn9015423	journal	February 2010
Electrochemical Photolysis of Water at a Semiconductor Electrode Fujishima, Akira; Honda, Kenichi Nature, Vol. 238, Issue 5358, p. 37-38 https://doi.org/10.1038/238037a0	journal	July 1972
Semiconductor-mediated photodegradation of pollutants under visible-light irradiation Chen, Chuncheng; Ma, Wanhong; Zhao, Jincai Chemical Society Reviews, Vol. 39, Issue 11 https://doi.org/10.1039/b921692h	journal	January 2010
Surface-Structure Sensitivity of CeO ₂ Nanocrystals in Photocatalysis and Enhancing the Reactivity with Nanogold Lei, Wanying; Zhang, Tingting; Gu, Lin ACS Catalysis, Vol. 5, Issue 7 https://doi.org/10.1021/acscatal.5b00620	journal	June 2015
Facet-Mediated Photodegradation of Organic Dye over Hematite Architectures by Visible Light Zhou, Xuemei; Lan, Jinyao; Liu, Gang Angewandte Chemie International Edition, Vol. 51, Issue 1 https://doi.org/10.1002/anie.201105028	journal	November 2011
Metal/Semiconductor Hybrid Nanostructures for Plasmon-Enhanced Applications Jiang, Ruibin; Li, Benxia; Fang, Caihong Advanced Materials, Vol. 26, Issue 31 https://doi.org/10.1002/adma.201400203	journal	April 2014
Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals Chen, X.; Liu, L.; Yu, P. Y. Science, Vol. 331, Issue 6018 https://doi.org/10.1126/science.1200448	journal	January 2011
Synthesis and photocatalytic application of visible-light active β -Fe 2 O 3 /g-C 3 N 4 hybrid nanocomposites Christoforidis, Konstantinos C.; Montini, Tiziano; Bontempi, Elza Applied Catalysis B: Environmental, Vol. 187 https://doi.org/10.1016/j.apcatb.2016.01.013	journal	June 2016
Selective Aerobic Oxidation Mediated by TiO ₂ Photocatalysis Lang, Xianjun; Ma, Wanhong; Chen, Chuncheng Accounts of Chemical Research, Vol. 47, Issue 2 https://doi.org/10.1021/ar4001108	journal	October 2013
Surface plasmon resonance-mediated photocatalysis by noble metal-based composites under visible light Zhou, Xuemei; Liu, Gang; Yu, Jiaguo Journal of Materials Chemistry, Vol. 22, Issue 40 https://doi.org/10.1039/c2jm31902k	journal	January 2012
Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures Christopher, Phillip; Xin, Hongliang; Linic, Suljo Nature Chemistry, Vol. 3, Issue 6 https://doi.org/10.1038/nchem.1032	journal	May 2011
Graphene-Based Photocatalysts for Solar-Fuel Generation Xiang, Quanjun; Cheng, Bei; Yu, Jiaguo Angewandte Chemie International Edition, Vol. 54, Issue 39 https://doi.org/10.1002/anie.201411096	journal	June 2015
Photocatalytic Conversion of CO ₂ to Hydrocarbon Fuels via Plasmon-Enhanced Absorption and Metallic Interband Transitions Hou, Wenbo; Hung, Wei Hsuan; Pavaskar, Prathamesh ACS Catalysis, Vol. 1, Issue 8 https://doi.org/10.1021/cs2001434	journal	July 2011
Heterogeneous photocatalyst materials for water splitting Kudo, Akihiko; Miseki, Yugo Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B800489G	journal	January 2009
Nanomaterials for renewable energy production and storage Chen, Xiaobo; Li, Can; Grätzel, Michaël Chemical Society Reviews, Vol. 41, Issue 23 https://doi.org/10.1039/c2cs35230c	journal	January 2012
Plasmon resonances for solar energy harvesting: A mechanistic outlook Smith, Jeremy G.; Faucheaux, Jacob A.; Jain, Prashant K. Nano Today, Vol. 10, Issue 1 https://doi.org/10.1016/j.nantod.2014.12.004	journal	February 2015
Semiconductor-based Photocatalytic Hydrogen Generation Chen, Xiaobo; Shen, Shaohua; Guo, Liejin Chemical Reviews, Vol. 110, Issue 11 https://doi.org/10.1021/cr1001645	journal	November 2010
Engineering titania nanostructure to tune and improve its photocatalytic activity Cargnello, Matteo; Montini, Tiziano; Smolin, Sergey Y. Proceedings of the National Academy of Sciences, Vol. 113, Issue 15 https://doi.org/10.1073/pnas.1524806113	journal	March 2016
The role of ceria-based nanostructured materials in energy applications Melchionna, M.; Fornasiero, P. Materials Today, Vol. 17, Issue 7 https://doi.org/10.1016/j.mattod.2014.05.005	journal	September 2014
Fundamentals and Catalytic Applications of CeO ₂ -Based Materials Montini, Tiziano; Melchionna, Michele; Monai, Matteo Chemical Reviews, Vol. 116, Issue 10 https://doi.org/10.1021/acs.chemrev.5b00603	journal	April 2016
Correlation of Ti3+ states with photocatalytic enhancement in TiO2-passivated p-GaAs Qiu, Jing; Zeng, Guangtong; Ge, Mingyuan Journal of Catalysis, Vol. 337 https://doi.org/10.1016/j.jcat.2016.02.002	journal	May 2016
Ultrathin Two-Dimensional Nanomaterials Zhang, Hua ACS Nano, Vol. 9, Issue 10 https://doi.org/10.1021/acsnano.5b05040	journal	September 2015
Waltzing with the Versatile Platform of Graphene to Synthesize Composite Photocatalysts Zhang, Nan; Yang, Min-Quan; Liu, Siqi Chemical Reviews, Vol. 115, Issue 18 https://doi.org/10.1021/acs.chemrev.5b00267	journal	August 2015
Physical and chemical tuning of two-dimensional transition metal dichalcogenides Wang, Haotian; Yuan, Hongtao; Sae Hong, Seung Chemical Society Reviews, Vol. 44, Issue 9 https://doi.org/10.1039/C4CS00287C	journal	January 2015
Recent Advances in Two-Dimensional Materials beyond Graphene Bhimanapati, Ganesh R.; Lin, Zhong; Meunier, Vincent ACS Nano, Vol. 9, Issue 12 https://doi.org/10.1021/acsnano.5b05556	journal	October 2015
Polymeric Photocatalysts Based on Graphitic Carbon Nitride Cao, Shaowen; Low, Jingxiang; Yu, Jiaguo Advanced Materials, Vol. 27, Issue 13 https://doi.org/10.1002/adma.201500033	journal	February 2015
Semiconducting black phosphorus: synthesis, transport properties and electronic applications Liu, Han; Du, Yuchen; Deng, Yexin Chemical Society Reviews, Vol. 44, Issue 9 https://doi.org/10.1039/C4CS00257A	journal	January 2015
The Reemergence of Chemistry for Post-Graphene Two-Dimensional Nanomaterials Hersam, Mark C. ACS Nano, Vol. 9, Issue 5 https://doi.org/10.1021/acsnano.5b02806	journal	May 2015
Ultrahigh sensitivity and layer-dependent sensing performance of phosphorene-based gas sensors Cui, Shumao; Pu, Haihui; Wells, Spencer A. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9632	journal	October 2015
Black Phosphorus Gas Sensors Abbas, Ahmad N.; Liu, Bilu; Chen, Liang ACS Nano, Vol. 9, Issue 5 https://doi.org/10.1021/acsnano.5b01961	journal	May 2015
Band Gap Engineering in a 2D Material for Solar-to-Chemical Energy Conversion Hu, Jun; Guo, Zhenkun; Mcwilliams, Peter E. Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b02895	journal	December 2015
2D phosphorene as a water splitting photocatalyst: fundamentals to applications Rahman, Mohammad Ziaur; Kwong, Chi Wai; Davey, Kenneth Energy & Environmental Science, Vol. 9, Issue 3 https://doi.org/10.1039/C5EE03732H	journal	January 2016
Anisotropic Thermal Conductivity of Exfoliated Black Phosphorus Jang, Hyejin; Wood, Joshua D.; Ryder, Christopher R. Advanced Materials, Vol. 27, Issue 48 https://doi.org/10.1002/adma.201503466	journal	October 2015
The Electrical Properties of Black Phosphorus Keyes, Robert W. Physical Review, Vol. 92, Issue 3 https://doi.org/10.1103/PhysRev.92.580	journal	November 1953
Solvent Exfoliation of Electronic-Grade, Two-Dimensional Black Phosphorus Kang, Joohoon; Wood, Joshua D.; Wells, Spencer A. ACS Nano, Vol. 9, Issue 4 https://doi.org/10.1021/acsnano.5b01143	journal	February 2015
Phosphorene: An Unexplored 2D Semiconductor with a High Hole Mobility Liu, Han; Neal, Adam T.; Zhu, Zhen ACS Nano, Vol. 8, Issue 4 https://doi.org/10.1021/nn501226z	journal	March 2014
Probing Out-of-Plane Charge Transport in Black Phosphorus with Graphene-Contacted Vertical Field-Effect Transistors Kang, Junmo; Jariwala, Deep; Ryder, Christopher R. Nano Letters, Vol. 16, Issue 4 https://doi.org/10.1021/acs.nanolett.6b00144	journal	March 2016
Covalent functionalization and passivation of exfoliated black phosphorus via aryl diazonium chemistry Ryder, Christopher R.; Wood, Joshua D.; Wells, Spencer A. Nature Chemistry, Vol. 8, Issue 6 https://doi.org/10.1038/nchem.2505	journal	May 2016
Metal Semiconductor Heterostructures for Photocatalytic Conversion of Light Energy Dutta, Sumit Kumar; Mehetor, Shyamal Kumar; Pradhan, Narayan The Journal of Physical Chemistry Letters, Vol. 6, Issue 6 https://doi.org/10.1021/acs.jpclett.5b00113	journal	March 2015
A Review of Surface Plasmon Resonance-Enhanced Photocatalysis Hou, Wenbo; Cronin, Stephen B. Advanced Functional Materials, Vol. 23, Issue 13, p. 1612-1619 https://doi.org/10.1002/adfm.201202148	journal	October 2012
Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy Linic, Suljo; Christopher, Phillip; Ingram, David B. Nature Materials, Vol. 10, Issue 12 https://doi.org/10.1038/nmat3151	journal	November 2011
Strategies for enhancing the sensitivity of plasmonic nanosensors Guo, Longhua; Jackman, Joshua A.; Yang, Huang-Hao Nano Today, Vol. 10, Issue 2 https://doi.org/10.1016/j.nantod.2015.02.007	journal	April 2015
Noncovalent Functionalization of Graphene and Graphene Oxide for Energy Materials, Biosensing, Catalytic, and Biomedical Applications Georgakilas, Vasilios; Tiwari, Jitendra N.; Kemp, K. Christian Chemical Reviews, Vol. 116, Issue 9 https://doi.org/10.1021/acs.chemrev.5b00620	journal	March 2016
Understanding TiO ₂ Photocatalysis: Mechanisms and Materials Schneider, Jenny; Matsuoka, Masaya; Takeuchi, Masato Chemical Reviews, Vol. 114, Issue 19 https://doi.org/10.1021/cr5001892	journal	May 2014
Evidence and implications of direct charge excitation as the dominant mechanism in plasmon-mediated photocatalysis Boerigter, Calvin; Campana, Robert; Morabito, Matthew Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10545	journal	January 2016
Ultrathin Black Phosphorus Nanosheets for Efficient Singlet Oxygen Generation Wang, Hui; Yang, Xianzhu; Shao, Wei Journal of the American Chemical Society, Vol. 137, Issue 35 https://doi.org/10.1021/jacs.5b06025	journal	August 2015
Interlayer electronic hybridization leads to exceptional thickness-dependent vibrational properties in few-layer black phosphorus Hu, Zhi-Xin; Kong, Xianghua; Qiao, Jingsi Nanoscale, Vol. 8, Issue 5 https://doi.org/10.1039/C5NR06293D	journal	January 2016
Plasma-assisted fabrication of monolayer phosphorene and its Raman characterization Lu, Wanglin; Nan, Haiyan; Hong, Jinhua Nano Research, Vol. 7, Issue 6 https://doi.org/10.1007/s12274-014-0446-7	journal	May 2014
Manipulation of charge transfer and transport in plasmonic-ferroelectric hybrids for photoelectrochemical applications Wang, Zhijie; Cao, Dawei; Wen, Liaoyong Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10348	journal	January 2016
Creating a Stable Oxide at the Surface of Black Phosphorus Edmonds, M. T.; Tadich, A.; Carvalho, A. ACS Applied Materials & Interfaces, Vol. 7, Issue 27 https://doi.org/10.1021/acsami.5b01297	journal	June 2015
On the Synergetic Catalytic Effect in Heterogeneous Nanocomposite Catalysts Shi, Jianlin Chemical Reviews, Vol. 113, Issue 3 https://doi.org/10.1021/cr3002752	journal	November 2012
Plasmon Emission Quantum Yield of Single Gold Nanorods as a Function of Aspect Ratio Fang, Ying; Chang, Wei-Shun; Willingham, Britain ACS Nano, Vol. 6, Issue 8 https://doi.org/10.1021/nn3022469	journal	July 2012
Surface Plasmon Dynamics in Silver Nanoparticles Studied by Femtosecond Time-Resolved Photoemission Lehmann, J.; Merschdorf, M.; Pfeiffer, W. Physical Review Letters, Vol. 85, Issue 14 https://doi.org/10.1103/PhysRevLett.85.2921	journal	October 2000
Ultrafast Photoinduced Charge Separation in Metal–Semiconductor Nanohybrids Mongin, Denis; Shaviv, Ehud; Maioli, Paolo ACS Nano, Vol. 6, Issue 8 https://doi.org/10.1021/nn302089h	journal	July 2012
Super-Resolution Mapping of Photogenerated Electron and Hole Separation in Single Metal–Semiconductor Nanocatalysts Ha, Ji Won; Ruberu, T. Purnima A.; Han, Rui Journal of the American Chemical Society, Vol. 136, Issue 4 https://doi.org/10.1021/ja409011y	journal	January 2014
Plasmon-Induced Hot Electron Transfer from the Au Tip to CdS Rod in CdS-Au Nanoheterostructures Wu, Kaifeng; Rodríguez-Córdoba, William E.; Yang, Ye Nano Letters, Vol. 13, Issue 11 https://doi.org/10.1021/nl402730m	journal	October 2013
Water Splitting on Composite Plasmonic-Metal/Semiconductor Photoelectrodes: Evidence for Selective Plasmon-Induced Formation of Charge Carriers near the Semiconductor Surface Ingram, David B.; Linic, Suljo Journal of the American Chemical Society, Vol. 133, Issue 14 https://doi.org/10.1021/ja200086g	journal	April 2011
Photochemical transformations on plasmonic metal nanoparticles Linic, Suljo; Aslam, Umar; Boerigter, Calvin Nature Materials, Vol. 14, Issue 6 https://doi.org/10.1038/nmat4281	journal	May 2015
On the True Photoreactivity Order of {001}, {010}, and {101} Facets of Anatase TiO2 Crystals Pan, Jian; Liu, Gang; Lu, Gao Qing Max Angewandte Chemie International Edition, Vol. 50, Issue 9 https://doi.org/10.1002/anie.201006057	journal	January 2011
Iterative minimization techniques for ab initio total-energy calculations: molecular dynamics and conjugate gradients Payne, M. C.; Teter, M. P.; Allan, D. C. Reviews of Modern Physics, Vol. 64, Issue 4 https://doi.org/10.1103/RevModPhys.64.1045	journal	October 1992
First-principles simulation: ideas, illustrations and the CASTEP code Segall, M. D.; Lindan, Philip J. D.; Probert, M. J. Journal of Physics: Condensed Matter, Vol. 14, Issue 11 https://doi.org/10.1088/0953-8984/14/11/301	journal	March 2002
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Semiempirical GGA-type density functional constructed with a long-range dispersion correction Grimme, Stefan Journal of Computational Chemistry, Vol. 27, Issue 15, p. 1787-1799 https://doi.org/10.1002/jcc.20495	journal	January 2006
Effect of van der Waals interactions on the structural and elastic properties of black phosphorus Appalakondaiah, S.; Vaitheeswaran, G.; Lebègue, S. Physical Review B, Vol. 86, Issue 3 https://doi.org/10.1103/PhysRevB.86.035105	journal	July 2012
Effect of pressure on bonding in black phosphorus Cartz, L.; Srinivasa, S. R.; Riedner, R. J. The Journal of Chemical Physics, Vol. 71, Issue 4 https://doi.org/10.1063/1.438523	journal	August 1979
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Bilayer Phosphorene: Effect of Stacking Order on Bandgap and Its Potential Applications in Thin-Film Solar Cells Dai, Jun; Zeng, Xiao Cheng The Journal of Physical Chemistry Letters, Vol. 5, Issue 7 https://doi.org/10.1021/jz500409m	journal	March 2014
Optical Anisotropy of Black Phosphorus in the Visible Regime Mao, Nannan; Tang, Jingyi; Xie, Liming Journal of the American Chemical Society, Vol. 138, Issue 1 https://doi.org/10.1021/jacs.5b10685	journal	December 2015

Cited By (29)

Visible- and NIR-Light Responsive Black-Phosphorus-Based Nanostructures in Solar Fuel Production and Environmental Remediation Feng, Rongjuan; Lei, Wanying; Liu, Gang Advanced Materials, Vol. 30, Issue 49 https://doi.org/10.1002/adma.201804770	journal	October 2018
Z-Scheme Photocatalytic Water Splitting on a 2D Heterostructure of Black Phosphorus/Bismuth Vanadate Using Visible Light Zhu, Mingshan; Sun, Zhichao; Fujitsuka, Mamoru Angewandte Chemie, Vol. 130, Issue 8 https://doi.org/10.1002/ange.201711357	journal	January 2018
Black Phosphorus Nanosheets as a Neuroprotective Nanomedicine for Neurodegenerative Disorder Therapy Chen, Wansong; Ouyang, Jiang; Yi, Xinyao Advanced Materials, Vol. 30, Issue 3 https://doi.org/10.1002/adma.201703458	journal	November 2017
Two dimensional semiconductors for ultrasound-mediated cancer therapy: the case of black phosphorus nanosheets Ouyang, Jiang; Deng, Liu; Chen, Wansong Chemical Communications, Vol. 54, Issue 23 https://doi.org/10.1039/c8cc00392k	journal	January 2018
Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters Lloret, Vicent; Rivero-Crespo, Miguel Ángel; Vidal-Moya, José Alejandro Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-018-08063-3	journal	January 2019
Tunable transport and optoelectronic properties of monolayer black phosphorus by grafting PdCl ₂ quantum dots Sun, Cuicui; Wang, Yuxiu; Jiang, Yingjie RSC Advances, Vol. 8, Issue 61 https://doi.org/10.1039/c8ra07053a	journal	January 2018
Black Phosphorus/Platinum Heterostructure: A Highly Efficient Photocatalyst for Solar-Driven Chemical Reactions Bai, Licheng; Wang, Xin; Tang, Shaobin Advanced Materials, Vol. 30, Issue 40 https://doi.org/10.1002/adma.201803641	journal	September 2018
Highly Fluorescent and Stable Black Phosphorus Quantum Dots in Water Long, Liyuan; Niu, Xianghong; Yan, Kun Small, Vol. 14, Issue 48 https://doi.org/10.1002/smll.201803132	journal	October 2018
Black Phosphorus, a Rising Star 2D Nanomaterial in the Post-Graphene Era: Synthesis, Properties, Modifications, and Photocatalysis Applications Li, Bisheng; Lai, Cui; Zeng, Guangming Small, Vol. 15, Issue 8 https://doi.org/10.1002/smll.201804565	journal	January 2019
Plasmon resonant amplification of hot electron-driven photocatalysis Shen, Lang; Gibson, George N.; Poudel, Nirakar Applied Physics Letters, Vol. 113, Issue 11 https://doi.org/10.1063/1.5048582	journal	September 2018
Phosphorene for energy and catalytic application—filling the gap between graphene and 2D metal chalcogenides Jain, Rishabh; Narayan, Rekha; Sasikala, Suchithra Padmajan 2D Materials, Vol. 4, Issue 4 https://doi.org/10.1088/2053-1583/aa89b3	journal	September 2017
Black Phosphorus‐Based Semiconductor Heterojunctions for Photocatalytic Water Splitting Liu, Fulai; Huang, Chen; Liu, Chu‐Xuan Chemistry – A European Journal, Vol. 26, Issue 20 https://doi.org/10.1002/chem.201904594	journal	January 2020
A black phosphorus based synergistic antibacterial platform against drug resistant bacteria Ouyang, Jiang; Liu, Ren-Yu; Chen, Wansong Journal of Materials Chemistry B, Vol. 6, Issue 39 https://doi.org/10.1039/c8tb01669k	journal	January 2018
Black/red phosphorus quantum dots for photocatalytic water splitting: from a type I heterostructure to a Z-scheme system Shi, Rui; Liu, Fulai; Wang, Zhuan Chemical Communications, Vol. 55, Issue 83 https://doi.org/10.1039/c9cc06146k	journal	January 2019
Engineering the energy gap of black phosphorene quantum dots by surface modification for efficient chemiluminescence Liu, Houjing; Su, Yingying; Sun, Tong Chemical Communications, Vol. 56, Issue 12 https://doi.org/10.1039/c9cc09355a	journal	January 2020
Recent Progress on Black Phosphorus‐Based Materials for Photocatalytic Water Splitting Yan, Junqing; Verma, Priyanka; Kuwahara, Yasutaka Small Methods, Vol. 2, Issue 12 https://doi.org/10.1002/smtd.201800212	journal	September 2018
Charge Transfer Doping Modulated Raman Scattering and Enhanced Stability of Black Phosphorus Quantum Dots on a ZnO Nanorod Hu, Liang; Amini, Mozhgan N.; Wu, Yunyi Advanced Optical Materials, Vol. 6, Issue 15 https://doi.org/10.1002/adom.201800440	journal	May 2018
3D reticulated carbon nitride materials high-uniformly capture 0D black phosphorus as 3D/0D composites for stable and efficient photocatalytic hydrogen evolution Song, Ting; Zeng, Gongchang; Zhang, Piyong Journal of Materials Chemistry A, Vol. 7, Issue 2 https://doi.org/10.1039/c8ta09647c	journal	January 2019
Two-dimensional light-emitting materials: preparation, properties and applications Wang, Zhiwei; Jingjing, Qiu; Wang, Xiaoshan Chemical Society Reviews, Vol. 47, Issue 16 https://doi.org/10.1039/c8cs00332g	journal	January 2018
Ice‐Assisted Synthesis of Black Phosphorus Nanosheets as a Metal‐Free Photocatalyst: 2D/2D Heterostructure for Broadband H ₂ Evolution Zhang, Qingzhe; Huang, Shengyun; Deng, Jiujun Advanced Functional Materials, Vol. 29, Issue 28 https://doi.org/10.1002/adfm.201902486	journal	May 2019
Functionalized Hybridization of 2D Nanomaterials Guan, Guijian; Han, Ming‐Yong Advanced Science, Vol. 6, Issue 23 https://doi.org/10.1002/advs.201901837	journal	September 2019
Promise and Challenge of Phosphorus in Science, Technology, and Application Han, Xinpeng; Han, Jinpeng; Liu, Cheng Advanced Functional Materials, Vol. 28, Issue 45 https://doi.org/10.1002/adfm.201803471	journal	September 2018
Electrostatic assembly of gold nanoparticles on black phosphorus nanosheets for electrochemical aptasensing of patulin Xu, Jinqiong; Qiao, Xiujuan; Wang, Yuan Microchimica Acta, Vol. 186, Issue 4 https://doi.org/10.1007/s00604-019-3339-3	journal	March 2019
Phosphorene Co-catalyst Advancing Highly Efficient Visible-Light Photocatalytic Hydrogen Production Ran, Jingrun; Zhu, Bicheng; Qiao, Shi-Zhang Angewandte Chemie International Edition, Vol. 56, Issue 35 https://doi.org/10.1002/anie.201703827	journal	July 2017
Phosphorene Co‐catalyst Advancing Highly Efficient Visible‐Light Photocatalytic Hydrogen Production Ran, Jingrun; Zhu, Bicheng; Qiao, Shi‐Zhang Angewandte Chemie, Vol. 129, Issue 35 https://doi.org/10.1002/ange.201703827	journal	July 2017
Z-Scheme Photocatalytic Water Splitting on a 2D Heterostructure of Black Phosphorus/Bismuth Vanadate Using Visible Light Zhu, Mingshan; Sun, Zhichao; Fujitsuka, Mamoru Angewandte Chemie International Edition, Vol. 57, Issue 8 https://doi.org/10.1002/anie.201711357	journal	January 2018
Few Layer 2D Pnictogens (P & Sb) Catalyze the Alkylation of Soft Nucleophiles with Esters Lioret, Vincet; Rivero-Crespo, Miguel Angel; Vidal-Moya, Jose Alejandro Nanoscience https://doi.org/10.26434/chemrxiv.7123184.v1	preprint	September 2018
Few Layer 2D Pnictogens (P & Sb) Catalyze the Alkylation of Soft Nucleophiles with Esters Lloret, Vicent; Rivero-Crespo, Miguel Angel; Vidal-Moya, Jose Alejandro Nanoscience https://doi.org/10.26434/chemrxiv.7123184	preprint	September 2018
Black Phosphorus/Palladium Nanohybrid: Unraveling the Nature of P−Pd Interaction and Application in Selective Hydrogenation Vanni, Matteo; Serrano-Ruiz, Manuel; Telesio, Francesca Zenodo https://doi.org/10.5281/zenodo.6610716	journalarticle	January 2019

Similar Records

Probing the role of CNTs in Pt nanoparticle/CNT/graphene nanohybrids H ₂ sensors

Journal Article · Thu Aug 18 00:00:00 EDT 2022 · Nano Express · OSTI ID:1345735

Alamri, Mohammed; Liu, Bo; Berrie, Cindy L.; +2 more

Facile synthesis of size-tunable CuO/graphene composites and their high photocatalytic performance

Journal Article · Thu Jan 15 00:00:00 EST 2015 · Materials Research Bulletin · OSTI ID:1345735

Cheng, Lingli; Wang, Yujia; Huang, Dahong; +6 more

Monitoring the growth dynamics of colloidal gold-silver core-shell nanoparticles using in situ second harmonic generation and extinction spectroscopy

Journal Article · Sat Dec 14 00:00:00 EST 2019 · Journal of Chemical Physics · OSTI ID:1345735

Ranasinghe, Jeewan C.; Dikkumbura, Asela S.; Hamal, Prakash; +5 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Ag nanoparticles
black phosphorus
density functional theory
localized surface plasmon resonance
photocatalysis

Title: Bandgap- and local field-dependent photoactivity of Ag/black phosphorus nanohybrids

Citation Formats

References (73)

Cited By (29)

Similar Records

Related Subjects