Surface Pb nanoparticle aggregation, coalescence and differential capacitance in a deep eutectic solvent using a simultaneous sample-rotated small angle x-ray scattering and electrochemical methods approach [Surface Pb nanoparticle aggregation, coalescence and differential capacitance in a deep eutectic solvent using a simultaneous grazing transmission small angle x-ray scattering and electrochemical methods approach]

Hammons, Joshua A.; Ilavsky, Jan

doi:10.1016/j.electacta.2017.01.072

Title: Surface Pb nanoparticle aggregation, coalescence and differential capacitance in a deep eutectic solvent using a simultaneous sample-rotated small angle x-ray scattering and electrochemical methods approach [Surface Pb nanoparticle aggregation, coalescence and differential capacitance in a deep eutectic solvent using a simultaneous grazing transmission small angle x-ray scattering and electrochemical methods approach]

Journal Article · Wed Jan 18 00:00:00 EST 2017 · Electrochimica Acta

DOI:https://doi.org/10.1016/j.electacta.2017.01.072· OSTI ID:1342012

Hammons, Joshua A. ^[1]; Ilavsky, Jan ^[2]

Argonne National Lab. (ANL), Lemont, IL (United States); Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)

Nanoparticle electrodeposition is a simple and scalable approach to synthesizing supported nanoparticles. Used with a deep eutectic solvent (DES), surface nanoparticles can be assembled and exhibit unique surface charge separation when the DES is adsorbed on the nanoparticle surface. Key to understanding and controlling the assembly and the capacitance is a thorough understanding of surface particle mobility and charge screening, which requires an in-situ approach. In this study, Pb particle formation, size, shape and capacitance are resolved in a 1:2 choline Cl^–: urea deep eutectic solvent whilst sweeping the cell potential in the range: 0.2 V to –1.2 V (vs. Ag/AgCl). These system parameters were resolved using a complementary suite of sample-rotated small angle X-ray scattering (SR-SAXS) and electrochemical impedance spectroscopy (EIS), which are presented and discussed in detail. This approach is able to show that both particle and ion transport are impeded in the DES, as aggregation occurs over the course of 6 minutes, and dissolved Pb ions accumulate and remain near the surface after a nucleation pulse is applied. The DES-Pb interactions strongly depend on the cell potential as evidenced by the specific differential capacitance of the Pb deposit, which has a maximum value of 2.5 +/– 0.5 F g^–1 at –1.0 V vs. Ag/AgCl. Together, the SR-SAXS-EIS approach is able to characterize the unique nanoparticle capacitance, mobility and ion mobility in a DES and can be used to study a wide range of nanoparticle deposition systems in-situ.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-07NA27344; AC02-06CH11357

OSTI ID:: 1342012

Alternate ID(s):: OSTI ID: 1397632

Report Number(s):: LLNL-JRNL-701206

Journal Information:: Electrochimica Acta, Vol. 228, Issue C; ISSN 0013-4686

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 8 works

Citation information provided by
Web of Science

References (41)

Potential applications of deep eutectic solvents in nanotechnology Abo-Hamad, Ali; Hayyan, Maan; AlSaadi, Mohammed AbdulHakim Chemical Engineering Journal, Vol. 273 https://doi.org/10.1016/j.cej.2015.03.091	journal	August 2015
A Generalized Electrochemical Aggregative Growth Mechanism Ustarroz, Jon; Hammons, Joshua A.; Altantzis, Thomas Journal of the American Chemical Society, Vol. 135, Issue 31 https://doi.org/10.1021/ja402598k	journal	July 2013
Brownian Dynamics Simulation of the Growth of Metal Nanocrystal Ensembles on Electrode Surfaces from Solution. I. Instantaneous Nucleation and Diffusion-Controlled Growth Fransaer, J. L.; Penner, R. M. The Journal of Physical Chemistry B, Vol. 103, Issue 36 https://doi.org/10.1021/jp990622a	journal	September 1999
Size-Selective Electrodeposition of Mesoscale Metal Particles in the Uncoupled Limit Liu, H.; Penner, R. M. The Journal of Physical Chemistry B, Vol. 104, Issue 39 https://doi.org/10.1021/jp0017902	journal	October 2000
“Multipulse” Electrochemical/Chemical Synthesis of CdS/S Core/Shell Nanocrystals Exhibiting Ultranarrow Photoluminescence Emission Lines Gorer, S.; Penner, R. M. The Journal of Physical Chemistry B, Vol. 103, Issue 28 https://doi.org/10.1021/jp991141u	journal	July 1999
Brownian Dynamics Simulations of the Growth of Metal Nanocrystal Ensembles on Electrode Surfaces in Solution: 2. The Effect of Deposition Rate on Particle Size Dispersion ^† Penner, Reginald M. The Journal of Physical Chemistry B, Vol. 105, Issue 37 https://doi.org/10.1021/jp0112828	journal	September 2001
Shape-Controlled Synthesis of Metal Nanostructures: The Case of Palladium Xiong, Y.; Xia, Y. Advanced Materials, Vol. 19, Issue 20 https://doi.org/10.1002/adma.200701301	journal	September 2007
Multipulse electrodeposition of Ag nanoparticles on HOPG monitored by in-situ by Small-Angle X-ray Scattering Ustarroz, Jon; Hammons, Joshua A.; Van Ingelgem, Yves Electrochemistry Communications, Vol. 13, Issue 12 https://doi.org/10.1016/j.elecom.2011.07.026	journal	December 2011
The Mechanisms for Nanoparticle Surface Diffusion and Chain Self-Assembly Determined from Real-Time Nanoscale Kinetics in Liquid Woehl, Taylor J.; Prozorov, Tanya The Journal of Physical Chemistry C, Vol. 119, Issue 36 https://doi.org/10.1021/acs.jpcc.5b07164	journal	August 2015
Surface Diffusion and Coalescence of Mobile Metal Nanoparticles José-Yacamán, M.; Gutierrez-Wing, C.; Miki, M. The Journal of Physical Chemistry B, Vol. 109, Issue 19 https://doi.org/10.1021/jp0509459	journal	May 2005
The Role of Nanocluster Aggregation, Coalescence, and Recrystallization in the Electrochemical Deposition of Platinum Nanostructures Ustarroz, Jon; Altantzis, Thomas; Hammons, Joshua A. Chemistry of Materials, Vol. 26, Issue 7 https://doi.org/10.1021/cm403178b	journal	March 2014
Transition-metal nanoparticles: synthesis, stability and the leaching issue Pachón, Laura Durán; Rothenberg, Gadi Applied Organometallic Chemistry, Vol. 22, Issue 6 https://doi.org/10.1002/aoc.1382	journal	January 2008
Deep Eutectic Solvents (DESs) and Their Applications Smith, Emma L.; Abbott, Andrew P.; Ryder, Karl S. Chemical Reviews, Vol. 114, Issue 21 https://doi.org/10.1021/cr300162p	journal	October 2014
Deep eutectic solvents: syntheses, properties and applications Zhang, Qinghua; De Oliveira Vigier, Karine; Royer, Sébastien Chemical Society Reviews, Vol. 41, Issue 21 https://doi.org/10.1039/c2cs35178a	journal	January 2012
Preparation of novel, moisture-stable, Lewis-acidic ionic liquids containing quaternary ammonium salts with functional side chains Abbott, Andrew P.; Capper, Glen; Davies, David L. Chemical Communications, Issue 19 https://doi.org/10.1039/b106357j	journal	January 2001
Shape-Controlled Synthesis of Gold Nanoparticles in Deep Eutectic Solvents for Studies of Structure-Functionality Relationships in Electrocatalysis Liao, Hong-Gang; Jiang, Yan-Xia; Zhou, Zhi-You Angewandte Chemie International Edition, Vol. 47, Issue 47 https://doi.org/10.1002/anie.200803202	journal	November 2008
Unknown Aspects of Self-Assembly of PbS Microscale Superstructures Querejeta-Fernández, Ana; Hernández-Garrido, Juan C.; Yang, Hengxi ACS Nano, Vol. 6, Issue 5 https://doi.org/10.1021/nn300890s	journal	April 2012
Electrochemically shape-controlled synthesis in deep eutectic solvents of Pt nanoflowers with enhanced activity for ethanol oxidation Wei, Lu; Fan, You-Jun; Wang, Hong-Hui Electrochimica Acta, Vol. 76 https://doi.org/10.1016/j.electacta.2012.05.063	journal	August 2012
Stability, Assembly, and Particle/Solvent Interactions of Pd Nanoparticles Electrodeposited from a Deep Eutectic Solvent Hammons, Joshua A.; Muselle, Thibault; Ustarroz, Jon The Journal of Physical Chemistry C, Vol. 117, Issue 27 https://doi.org/10.1021/jp403739y	journal	June 2013
Electrocatalytic properties of in situ-generated palladium nanoparticle assemblies towards oxidation of multi-carbon alcohols and polyalcohols Renard, David; McCain, Caitlyn; Baidoun, Batoul Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 463 https://doi.org/10.1016/j.colsurfa.2014.09.027	journal	December 2014
One-Step Fabrication of Nanostructured Ni Film with Lotus Effect from Deep Eutectic Solvent Gu, Changdong; Tu, Jiangping Langmuir, Vol. 27, Issue 16 https://doi.org/10.1021/la200778a	journal	August 2011
Supported Silver Nanoparticle and Near-Interface Solution Dynamics in a Deep Eutectic Solvent Hammons, Joshua A.; Ustarroz, Jon; Muselle, Thibault The Journal of Physical Chemistry C, Vol. 120, Issue 3 https://doi.org/10.1021/acs.jpcc.5b09836	journal	January 2016
Double layer effects on metal nucleation in deep eutectic solvents Abbott, Andrew P.; Barron, John C.; Frisch, Gero Physical Chemistry Chemical Physics, Vol. 13, Issue 21 https://doi.org/10.1039/c0cp02244f	journal	January 2011
Differential capacity of a deep eutectic solvent based on choline chloride and glycerol on solid electrodes Figueiredo, Marta; Gomes, Cristiana; Costa, Renata Electrochimica Acta, Vol. 54, Issue 9 https://doi.org/10.1016/j.electacta.2008.10.074	journal	March 2009
Electrochemical double layer at the interfaces of Hg/choline chloride based solvents Costa, Renata; Figueiredo, Marta; Pereira, Carlos M. Electrochimica Acta, Vol. 55, Issue 28 https://doi.org/10.1016/j.electacta.2010.07.070	journal	December 2010
Recent advances on multi-component hybrid nanostructures for electrochemical capacitors Xiong, Pan; Zhu, Junwu; Wang, Xin Journal of Power Sources, Vol. 294 https://doi.org/10.1016/j.jpowsour.2015.06.062	journal	October 2015
A review on electrochemical double-layer capacitors Sharma, Pawan; Bhatti, T. S. Energy Conversion and Management, Vol. 51, Issue 12 https://doi.org/10.1016/j.enconman.2010.06.031	journal	December 2010
Physical Properties of a New Deep Eutectic Solvent Based on a Sulfonium Ionic Liquid as a Suitable Electrolyte for Electric Double-Layer Capacitors Baokou, Xiong; Anouti, Mérièm The Journal of Physical Chemistry C, Vol. 119, Issue 2 https://doi.org/10.1021/jp5110455	journal	December 2014
Deep Eutectic Solvents Based on N -Methylacetamide and a Lithium Salt as Electrolytes at Elevated Temperature for Activated Carbon-Based Supercapacitors Zaidi, Warda; Boisset, Aurélien; Jacquemin, Johan The Journal of Physical Chemistry C, Vol. 118, Issue 8 https://doi.org/10.1021/jp412552v	journal	February 2014
Grazing-incidence transmission X-ray scattering: surface scattering in the Born approximation Lu, Xinhui; Yager, Kevin G.; Johnston, Danvers Journal of Applied Crystallography, Vol. 46, Issue 1 https://doi.org/10.1107/S0021889812047887	journal	January 2013
Effects of ultrasound on the electrodeposition of lead dioxide on glassy carbon electrodes González-García, Jose´; Iniesta, Jesús; Aldaz, Antonio New Journal of Chemistry, Vol. 22, Issue 4 https://doi.org/10.1039/a708754c	journal	January 1998
Electrodeposition of lead on glassy carbon and mercury film electrodes from a distillable room temperature ionic liquid, DIMCARB Bhatt, Anand I.; Bond, Alan M.; Zhang, Jie Journal of Solid State Electrochemistry, Vol. 11, Issue 12 https://doi.org/10.1007/s10008-006-0198-8	journal	September 2006
Colloidal Quantum Dot Solar Cells Carey, Graham H.; Abdelhady, Ahmed L.; Ning, Zhijun Chemical Reviews, Vol. 115, Issue 23 https://doi.org/10.1021/acs.chemrev.5b00063	journal	June 2015
Co-Deposition of PbS–CuS Thin Films by Chemical Bath Technique Suárez, R.; Nair, P. K. Journal of Solid State Chemistry, Vol. 123, Issue 2 https://doi.org/10.1006/jssc.1996.0182	journal	May 1996
High-energy ultra-small-angle X-ray scattering instrument at the Advanced Photon Source Ilavsky, Jan; Allen, Andrew J.; Levine, Lyle E. Journal of Applied Crystallography, Vol. 45, Issue 6 https://doi.org/10.1107/S0021889812040022	journal	November 2012
Irena : tool suite for modeling and analysis of small-angle scattering Ilavsky, Jan; Jemian, Peter R. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889809002222	journal	February 2009
Scattering from fractals Martin, J. E.; Hurd, A. J. Journal of Applied Crystallography, Vol. 20, Issue 2 https://doi.org/10.1107/S0021889887087107	journal	April 1987
Approximations Leading to a Unified Exponential/Power-Law Approach to Small-Angle Scattering Beaucage, G. Journal of Applied Crystallography, Vol. 28, Issue 6 https://doi.org/10.1107/S0021889895005292	journal	December 1995
Determination of branch fraction and minimum dimension of mass-fractal aggregates Beaucage, G. Physical Review E, Vol. 70, Issue 3 https://doi.org/10.1103/PhysRevE.70.031401	journal	September 2004
A Deep Eutectic Solvent-based Amperometric Sensor for the Detection of Low Oxygen Contents in Gaseous Atmospheres Toniolo, Rosanna; Dossi, Nicolò; Svigelj, Rossella Electroanalysis, Vol. 28, Issue 4 https://doi.org/10.1002/elan.201500515	journal	October 2015
Energy accumulation in nanoparticle collision and coalescence processes Lehtinen, Kari E. J.; Zachariah, Michael R. Journal of Aerosol Science, Vol. 33, Issue 2 https://doi.org/10.1016/S0021-8502(01)00177-X	journal	February 2002

Cited By (1)

Water distribution at the electrified interface of deep eutectic solvents Mamme, Mesfin Haile; Moors, Samuel L. C.; Mernissi Cherigui, El Amine Nanoscale Advances, Vol. 1, Issue 8 https://doi.org/10.1039/c9na00331b	journal	January 2019

Similar Records

Manipulating meso-scale solvent structure from Pd nanoparticle deposits in deep eutectic solvents

Journal Article · Fri Aug 20 00:00:00 EDT 2021 · Journal of Chemical Physics · OSTI ID:1342012

Hammons, Joshua A.; Besford, Quinn A.; Ilavsky, Jan; +1 more

Supported Silver Nanoparticle and Near-Interface Solution Dynamics in a Deep Eutectic Solvent

Journal Article · Thu Jan 28 00:00:00 EST 2016 · Journal of Physical Chemistry. C · OSTI ID:1342012

Hammons, Joshua A.; Ustarroz, Jon; Muselle, Thibault; +4 more

Extended hierarchical solvent perturbations from curved surfaces of mesoporous silica particles in a deep eutectic solvent

Journal Article · Sat Mar 03 00:00:00 EST 2018 · Journal of Colloid and Interface Science · OSTI ID:1342012

Hammons, Joshua A.; Zhang, Fan; Ilavsky, Jan

Related Subjects

36 MATERIALS SCIENCE
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
77 NANOSCIENCE AND NANOTECHNOLOGY
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
nanoparticle
synthesis
electrodeposition
deep eutectic solvent
stability
X-ray scattering
SAXS
USAXS
impedance
electrostatic
capacitance
differential capacitance
aggregation
coalescence
Pb nanoparticles

Citation Formats

References (41)

Cited By (1)

Similar Records

Related Subjects