Synthetic control of manganese birnessite: Impact of crystallite size on Li, Na, and Mg based electrochemistry

Yin, Jiefu; Takeuchi, Esther S.; Takeuchi, Kenneth J.; Marschilok, Amy C.

doi:10.1016/j.ica.2016.08.026

Title: Synthetic control of manganese birnessite: Impact of crystallite size on Li, Na, and Mg based electrochemistry

Journal Article · Fri Aug 12 00:00:00 EDT 2016 · Inorganica Chimica Acta

DOI:https://doi.org/10.1016/j.ica.2016.08.026· OSTI ID:1341696

Yin, Jiefu ^[1]; Takeuchi, Esther S. ^[2]; Takeuchi, Kenneth J. ^[3]; Marschilok, Amy C. ^[2]

Stony Brook Univ., NY (United States). Dept. of Chemistry
Stony Brook Univ., NY (United States). Dept. of Chemistry; Stony Brook Univ., NY (United States). Dept. of Materials Science and Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States)
Stony Brook Univ., NY (United States). Dept. of Chemistry; Stony Brook Univ., NY (United States). Dept. of Materials Science and Engineering;

We demonstrated the synthesis and characterization of Mg-birnessite (Mg_xMnO₂) with different crystallite sizes, prepared though low temperature precipitation and ion exchange. The influence of crystallite size on electrochemical performance of Mg-birnessite was studied for the first time, where material with smaller crystallite size was demonstrated to have enhanced capacity and rate capability in Li ion, Na ion, and Mg ion based electrolytes. Cation diffusion using GITT type testing demonstrated the ion diffusion coefficient of Mg²⁺ was ~10× lower compared with Li⁺ and Na⁺. This work illustrates that tuning of inorganic materials properties can lead to significant enhancement of electrochemical performance in lithium, sodium as well as magnesium based batteries for materials such as Mg-birnessite and provides a deliberate approach to improve electrochemical performance.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; SC0012673; 1275961

OSTI ID:: 1341696

Alternate ID(s):: OSTI ID: 1396668

Report Number(s):: BNL-113442-2017-JA

Journal Information:: Inorganica Chimica Acta, Vol. 453, Issue C; ISSN 0020-1693

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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25 ENERGY STORAGE
36 MATERIALS SCIENCE
manganese
birnessite
crystallite
Li
Na
Mg
Electrochemistry
manganese oxide
lithium ion battery
sodium ion battery
magnesium ion battery

Title: Synthetic control of manganese birnessite: Impact of crystallite size on Li, Na, and Mg based electrochemistry

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