Ru nanoframes with an fcc structure and enhanced catalytic properties

Ye, Haihang; Wang, Qingxiao; Catalano, Massimo; Lu, Ning; Vermeylen, Joseph; Kim, Moon J.; Liu, Yuzi; Sun, Yugang; Xia, Xiaohu

doi:10.1021/acs.nanolett.6b00607

Title: Ru nanoframes with an fcc structure and enhanced catalytic properties

Journal Article · Mon Mar 21 00:00:00 EDT 2016 · Nano Letters

DOI:https://doi.org/10.1021/acs.nanolett.6b00607· OSTI ID:1339579

Ye, Haihang ^[1]; Wang, Qingxiao ^[2]; Catalano, Massimo ^[2]; Lu, Ning ^[2]; Vermeylen, Joseph ^[1]; Kim, Moon J. ^[2]; Liu, Yuzi ^[3]; Sun, Yugang ^[4]; Xia, Xiaohu ^[1]

Michigan Technological Univ., Houghton, MI (United States)
Univ. of Texas at Dallas, Richardson, TX (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Temple Univ., Philadelphia, PA (United States)

Noble-metal nanoframes are of great interest to many applications due to their unique open structures. Among various noble metals, Ru has never been made into nanoframes. In this study, we report for the first time an effective method based on seeded growth and chemical etching for the facile synthesis of Ru nanoframes with high purity. The essence of this approach is to induce the preferential growth of Ru on the corners and edges of Pd truncated octahedra as the seeds by kinetic control. The resultant Pd–Ru core–frame octahedra could be easily converted to Ru octahedral nanoframes of ~2 nm in thickness by selectively removing the Pd cores through chemical etching. Most importantly, in this approach the face-centered cubic (fcc) crystal structure of Pd seeds was faithfully replicated by Ru that usually takes an hcp structure. Furthermore, the fcc Ru nanoframes showed higher catalytic activities toward the reduction of p-nitrophenol by NaBH₄ and the dehydrogenation of ammonia borane compared with hcp Ru nanowires with roughly the same thickness.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: Michigan Technological University; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1339579

Journal Information:: Nano Letters, Vol. 16, Issue 4; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 165 works

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36 MATERIALS SCIENCE
catalysis
crystal structure
kinetic control
nanoframe
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Title: Ru nanoframes with an fcc structure and enhanced catalytic properties

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