Thermodynamics of multicaloric effects in multiferroic materials: application to metamagnetic shape-memory alloys and ferrotoroidics

Planes, Antoni; Castán, Teresa; Saxena, Avadh

doi:10.1098/rsta.2015.0304

Title: Thermodynamics of multicaloric effects in multiferroic materials: application to metamagnetic shape-memory alloys and ferrotoroidics

Journal Article · Mon Jul 11 00:00:00 EDT 2016 · Philosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciences

DOI:https://doi.org/10.1098/rsta.2015.0304· OSTI ID:1338758

^[1]; Castán, Teresa ^[1]; Saxena, Avadh ^[2]

Univ. of Barcelona (Spain). Faculty of Physics. Dept. of Structure and Constituents of Matter
Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Theoretical Division

In this paper, we develop a general thermodynamic framework to investigate multicaloric effects in multiferroic materials. This is applied to the study of both magnetostructural and magnetoelectric multiferroics. Landau models with appropriate interplay between the corresponding ferroic properties (order parameters) are proposed for metamagnetic shape-memory and ferrotoroidic materials, which, respectively, belong to the two classes of multiferroics. For each ferroic property, caloric effects are quantified by the isothermal entropy change induced by the application of the corresponding thermodynamically conjugated field. The multicaloric effect is obtained as a function of the two relevant applied fields in each class of multiferroics. It is further shown that multicaloric effects comprise the corresponding contributions from caloric effects associated with each ferroic property and the cross-contribution arising from the interplay between these ferroic properties. Finally, this article is part of the themed issue ‘Taking the temperature of phase transitions in cool materials’.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of Barcelona (Spain)

Sponsoring Organization:: USDOE; Interministerial Commission of Science and Technology (CICyT) (Spain)

Grant/Contract Number:: AC52-06NA25396; MAT2013-40590-P

OSTI ID:: 1338758

Report Number(s):: LA-UR-16-20640

Journal Information:: Philosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2074; ISSN 1364-503X

Publisher:: Royal SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 23 works

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Title: Thermodynamics of multicaloric effects in multiferroic materials: application to metamagnetic shape-memory alloys and ferrotoroidics

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