Oxidation of the Ru(0001) surface covered by weakly bound, ultrathin silicate films

Emmez, Emre; Anibal Boscoboinik, J.; Tenney, Samuel; Sutter, Peter; Shaikhutdinov, Shamil; Freund, Hans-Joachim

doi:10.1016/j.susc.2015.06.019

Title: Oxidation of the Ru(0001) surface covered by weakly bound, ultrathin silicate films

Journal Article · Tue Jun 30 00:00:00 EDT 2015 · Surface Science

DOI:https://doi.org/10.1016/j.susc.2015.06.019· OSTI ID:1336055

Emmez, Emre ^[1]; Anibal Boscoboinik, J. ^[2]; Tenney, Samuel ^[2]; Sutter, Peter ^[2]; Shaikhutdinov, Shamil ^[1]; Freund, Hans-Joachim ^[1]

Abteilung Chemische Physik, Fritz-Haber Institut der MPG, Berlin (Germany)
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)

Bilayer silicate films grown on metal substrates are weakly bound to the metal surfaces, which allows ambient gas molecules to intercalate the oxide/metal interface. In this work, we studied the interaction of oxygen with Ru(0001) supported ultrathin silicate and aluminosilicate films at elevated O₂ pressures (10^-5–10 mbar) and temperatures (450–923 K). The results show that the silicate films stay essentially intact under these conditions, and oxygen in the film does not exchange with oxygen in the ambient. O₂ molecules readily penetrate the film and dissociate on the underlying Ru surface underneath. Also, the silicate layer does however strongly passivate the Ru surface towards RuO₂(110) oxide formation that readily occurs on bare Ru(0001) under the same conditions. Lastly, the results indicate considerable spatial effects for oxidation reactions on metal surfaces in the confined space at the interface. Moreover, the aluminosilicate films completely suppress the Ru oxidation, providing some rationale for using crystalline aluminosilicates in anti-corrosion coatings.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; AC02-98CH10886

OSTI ID:: 1336055

Alternate ID(s):: OSTI ID: 1247755

Report Number(s):: BNL-107836-2016-JA; R&D Project: 16083; KC0403020

Journal Information:: Surface Science, Vol. 646; ISSN 0039-6028

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 24 works

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Wasserbildung unter dünnen Silika-Filmen: Echtzeitbeobachtung einer chemischen Reaktion in einem physikalisch eingegrenzten Raum Prieto, Mauricio J.; Klemm, Hagen W.; Xiong, Feng Angewandte Chemie, Vol. 130, Issue 28 https://doi.org/10.1002/ange.201802000	journal	June 2018
Water Formation under Silica Thin Films: Real-Time Observation of a Chemical Reaction in a Physically Confined Space Prieto, Mauricio J.; Klemm, Hagen W.; Xiong, Feng Angewandte Chemie International Edition, Vol. 57, Issue 28 https://doi.org/10.1002/anie.201802000	journal	June 2018
Ionization‐Facilitated Formation of 2D (Alumino)Silicate–Noble Gas Clathrate Compounds Zhong, Jian‐Qiang; Wang, Mengen; Akter, Nusnin Advanced Functional Materials, Vol. 29, Issue 20 https://doi.org/10.1002/adfm.201806583	journal	March 2019
Chemistry in confined space through the eyes of surface science—2D porous materials Boscoboinik, J. Anibal Journal of Physics: Condensed Matter, Vol. 31, Issue 6 https://doi.org/10.1088/1361-648x/aaf2ce	journal	December 2018
Energy Level Shifts at the Silica/Ru(0001) Heterojunction Driven by Surface and Interface Dipoles Wang, Mengen; Zhong, Jian-Qiang; Kestell, John Topics in Catalysis, Vol. 60, Issue 6-7 https://doi.org/10.1007/s11244-016-0704-x	journal	September 2016

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