Energetics of alkali and alkaline earth ion-exchanged zeolite A

Sun, Hui; Wu, Di; Liu, Kefeng; Guo, Xiaofeng; Navrotsky, Alexandra

doi:10.1021/acs.jpcc.6b04840

Title: Energetics of alkali and alkaline earth ion-exchanged zeolite A

Journal Article · Thu Jun 30 00:00:00 EDT 2016 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.6b04840· OSTI ID:1324571

Sun, Hui ^[1]; Wu, Di ^[2]; Liu, Kefeng ^[3]; Guo, Xiaofeng ^[4]; Navrotsky, Alexandra ^[5]

East China Univ. of Science and Technology, Shanghai (China); Univ. of California, Davis, CA (United States)
Univ. of California, Davis, CA (United States); Washington State Univ., Pullman, WA (United States)
East China Univ. of Science and Technology, Shanghai (China)
Univ. of California, Davis, CA (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of California, Davis, CA (United States)

Alkali and alkaline earth ion-exchanged zeolite A samples were synthesized in aqueous exchange media. They were thoroughly studied by powder X-ray diffraction (XRD), electron microprobe (EMPA), thermogravimetric analysis and differential scanning calorimetry (TG-DSC), and high temperature oxide melt solution calorimetry. The hydration energetics and enthalpies of formation of these zeolite A materials from constituent oxides were determined. Specifically, the hydration level of zeolite A has a linear dependence on the average ionic potential (Z/r) of the cation, from 0.894 (Rb-A) to 1.317 per TO₂ (Mg-A). The formation enthalpies from oxides (25 °C) range from –93.71 ± 1.77 (K-A) to –48.02 ± 1.85 kJ/mol per TO₂ (Li-A) for hydrated alkali ion-exchanged zeolite A, and from –47.99 ± 1.20 (Ba-A) to –26.41 ± 1.71 kJ/mol per TO₂ (Mg-A) for hydrated alkaline earth ion-exchanged zeolite A. As a result, the formation enthalpy from oxides generally becomes less exothermic as Z/r increases, but a distinct difference in slope is observed between the alkali and the alkaline earth series.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1324571

Report Number(s):: LA-UR-16-23501

Journal Information:: Journal of Physical Chemistry. C, Vol. 120, Issue 28; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 27 works

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