Pressure effects on magnetic ground states in cobalt doped multiferroic Mn1-xCoxWO4

Wang, Jinchen; Ye, Feng; Chi, Songxue; Fernandez-Baca, Jaime A.; Cao, Huibo; Tian, Wei; Gooch, Mellisa; Poudel, N.; Wang, Yaqi Q.; Lorenz, Bernd; Chu, C. W.

doi:10.1103/PhysRevB.93.155164

Title: Pressure effects on magnetic ground states in cobalt doped multiferroic Mn_1-xCo_xWO₄

Journal Article · Thu Apr 28 00:00:00 EDT 2016 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.93.155164· OSTI ID:1324079

Wang, Jinchen ^[1]; Ye, Feng ^[2]; Chi, Songxue ^[3]; Fernandez-Baca, Jaime A. ^[3]; Cao, Huibo ^[3]; Tian, Wei ^[3]; Gooch, Mellisa ^[4]; Poudel, N. ^[4]; Wang, Yaqi Q. ^[4]; Lorenz, Bernd ^[4]; Chu, C. W. ^[5]

Renmin Univ. of China, Beijing (China); Univ. of Kentucky, Lexington, KY (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Kentucky, Lexington, KY (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Houston, Houston, TX (United States)
Univ. of Houston, Houston, TX (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Using x-ray and high pressure neutron diffraction, we studied the pressure effect on structural and magnetic properties of multiferroic Mn_1-xCo_xWO₄ single crystals (x = 0, 0.05, 0.135 and 0.17), and compared it with the effects of doping. Both Co doping and pressure stretch the Mn-Mn chain along the c direction. At high doping level (x = 0.135 and 0.17), pressure and Co doping drive the system in a very similar way and induce a spin-flop transition for the x = 0.135 compound. In contrast, magnetic ground states at lower doping level (x = 0 and 0.05) are robust against pressure but experience a pronounced change upon Co substitution. As Co introduces both chemical pressure and magnetic anisotropy into the frustrated magnetic system, our results suggest the magnetic anisotropy is the main driving force for the Co induced phase transitions at low doping level, and chemical pressure plays a more significant role at higher Co concentrations.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). High Flux Isotope Reactor (HFIR); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1324079

Alternate ID(s):: OSTI ID: 1249887

Journal Information:: Physical Review B, Vol. 93; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 3 works

Citation information provided by
Web of Science

References (47)

Magnetic control of ferroelectric polarization Kimura, T.; Goto, T.; Shintani, H. Nature, Vol. 426, Issue 6962 https://doi.org/10.1038/nature02018	journal	November 2003
Multiferroics: Different ways to combine magnetism and ferroelectricity Khomskii, D. I. Journal of Magnetism and Magnetic Materials, Vol. 306, Issue 1 https://doi.org/10.1016/j.jmmm.2006.01.238	journal	November 2006
Multiferroics: a magnetic twist for ferroelectricity Cheong, Sang-Wook; Mostovoy, Maxim Nature Materials, Vol. 6, Issue 1 https://doi.org/10.1038/nmat1804	journal	January 2007
Multiferroics progress and prospects in thin films Ramesh, R.; Spaldin, Nicola A. Nature Materials, Vol. 6, Issue 1, p. 21-29 https://doi.org/10.1038/nmat1805	journal	January 2007
Multiferroics—toward strong coupling between magnetization and polarization in a solid Tokura, Y. Journal of Magnetism and Magnetic Materials, Vol. 310, Issue 2 https://doi.org/10.1016/j.jmmm.2006.11.198	journal	March 2007
Multiferroics of spin origin Tokura, Yoshinori; Seki, Shinichiro; Nagaosa, Naoto Reports on Progress in Physics, Vol. 77, Issue 7 https://doi.org/10.1088/0034-4885/77/7/076501	journal	July 2014
Spin Current and Magnetoelectric Effect in Noncollinear Magnets Katsura, Hosho; Nagaosa, Naoto; Balatsky, Alexander V. Physical Review Letters, Vol. 95, Issue 5 https://doi.org/10.1103/PhysRevLett.95.057205	journal	July 2005
Role of the Dzyaloshinskii-Moriya interaction in multiferroic perovskites Sergienko, I. A.; Dagotto, E. Physical Review B, Vol. 73, Issue 9 https://doi.org/10.1103/PhysRevB.73.094434	journal	March 2006
Ferroelectricity in Spiral Magnets Mostovoy, Maxim Physical Review Letters, Vol. 96, Issue 6 https://doi.org/10.1103/PhysRevLett.96.067601	journal	February 2006
Electric polarization reversal and memory in a multiferroic material induced by magnetic fields Hur, N.; Park, S.; Sharma, P. A. Nature, Vol. 429, Issue 6990 https://doi.org/10.1038/nature02572	journal	May 2004
Bond electronic polarization induced by spin Jia, Chenglong; Onoda, Shigeki; Nagaosa, Naoto Physical Review B, Vol. 74, Issue 22 https://doi.org/10.1103/PhysRevB.74.224444	journal	December 2006
Microscopic theory of spin-polarization coupling in multiferroic transition metal oxides Jia, Chenglong; Onoda, Shigeki; Nagaosa, Naoto Physical Review B, Vol. 76, Issue 14 https://doi.org/10.1103/PhysRevB.76.144424	journal	October 2007
Ferroelectric Polarization Flop in a Frustrated Magnet ${MnWO}_{4}$ Induced by a Magnetic Field Taniguchi, K.; Abe, N.; Takenobu, T. Physical Review Letters, Vol. 97, Issue 9 https://doi.org/10.1103/PhysRevLett.97.097203	journal	August 2006
Ferroelectricity in the cycloidal spiral magnetic phase of $Mn W O_{4}$ Arkenbout, A. H.; Palstra, T. T. M.; Siegrist, T. Physical Review B, Vol. 74, Issue 18 https://doi.org/10.1103/PhysRevB.74.184431	journal	November 2006
A new multiferroic material: MnWO ₄ Heyer, O.; Hollmann, N.; Klassen, I. Journal of Physics: Condensed Matter, Vol. 18, Issue 39 https://doi.org/10.1088/0953-8984/18/39/L01	journal	September 2006
Magnetic phase transitions of ${MnWO}_{4}$ studied by the use of neutron diffraction Lautenschläger, G.; Weitzel, H.; Vogt, T. Physical Review B, Vol. 48, Issue 9 https://doi.org/10.1103/PhysRevB.48.6087	journal	September 1993
Incommensurate magnetic structures of multiferroic MnWO $_{4}$ studied within the superspace formalism Urcelay-Olabarria, I.; Perez-Mato, J. M.; Ribeiro, J. L. Physical Review B, Vol. 87, Issue 1 https://doi.org/10.1103/PhysRevB.87.014419	journal	January 2013
Magnon dispersion in Ehrenberg, H.; Weitzel, H.; Fuess, H. Journal of Physics: Condensed Matter, Vol. 11, Issue 12 https://doi.org/10.1088/0953-8984/11/12/019	journal	January 1999
Long-range magnetic interactions in the multiferroic antiferromagnet MnWO $_{4}$ Ye, Feng; Fishman, Randy S.; Fernandez-Baca, Jaime A. Physical Review B, Vol. 83, Issue 14 https://doi.org/10.1103/PhysRevB.83.140401	journal	April 2011
Magnetic structure and ferroelectric polarization of ${MnWO}_{4}$ investigated by density functional calculations and classical spin analysis Tian, Chuan; Lee, Changhoon; Xiang, Hongjun Physical Review B, Vol. 80, Issue 10 https://doi.org/10.1103/PhysRevB.80.104426	journal	September 2009
Landau theory for the phase diagram of multiferroic Mn $_{1 - x}$ (Fe,Zn,Mg) $_{x}$ WO $_{4}$ Matityahu, Shlomi; Aharony, Amnon; Entin-Wohlman, Ora Physical Review B, Vol. 85, Issue 17 https://doi.org/10.1103/PhysRevB.85.174408	journal	May 2012
Magnetic-field dependence of the ferroelectric polarization and spin-lattice coupling in multiferroic $Mn W O_{4}$ Taniguchi, K.; Abe, N.; Sagayama, H. Physical Review B, Vol. 77, Issue 6 https://doi.org/10.1103/PhysRevB.77.064408	journal	February 2008
Multiferroicity on the Zigzag-Chain Antiferromagnet MnWO ₄ in High Magnetic Fields Mitamura, Hiroyuki; Sakakibara, Toshiro; Nakamura, Hiroyuki Journal of the Physical Society of Japan, Vol. 81, Issue 5 https://doi.org/10.1143/JPSJ.81.054705	journal	May 2012
X phase of ${MnWO}_{4}$ Urcelay-Olabarria, I.; Ressouche, E.; Mukhin, A. A. Physical Review B, Vol. 90, Issue 2 https://doi.org/10.1103/PhysRevB.90.024408	journal	July 2014
Field effects with $H ∥ b$ on the incommensurate magnetic structures of multiferroic $MnW O_{4}$ studied within the superspace formalism Urcelay-Olabarria, I.; García-Muñoz, J. L.; Mukhin, A. A. Physical Review B, Vol. 91, Issue 10 https://doi.org/10.1103/PhysRevB.91.104429	journal	March 2015
Magnetic switching and phase competition in the multiferroic antiferromagnet ${Mn}_{1 - x} {Fe}_{x} {WO}_{4}$ Ye, F.; Ren, Y.; Fernandez-Baca, J. A. Physical Review B, Vol. 78, Issue 19 https://doi.org/10.1103/PhysRevB.78.193101	journal	November 2008
Effect of Nonmagnetic Substituents Mg and Zn on the Phase Competition in the Multiferroic Antiferromagnet MnWO ₄ Meddar, Lynda; Josse, Michael; Deniard, Philippe Chemistry of Materials, Vol. 21, Issue 21 https://doi.org/10.1021/cm9021358	journal	November 2009
Robust ferroelectric state in multiferroic ${Mn}_{1 - x} {Zn}_{x} {WO}_{4}$ Chaudhury, R. P.; Ye, F.; Fernandez-Baca, J. A. Physical Review B, Vol. 83, Issue 1 https://doi.org/10.1103/PhysRevB.83.014401	journal	January 2011
Stabilized helical spin order and multiferroic phase coexistence in MnWO $_{4}$ : Consequence of $4 d$ Ru substitution of Mn Yu, H. W.; Liu, M. F.; Li, X. Physical Review B, Vol. 87, Issue 10 https://doi.org/10.1103/PhysRevB.87.104404	journal	March 2013
Observation of spontaneous ferroelectric polarization reversal in multiferroic Mn1−xNixWO4 (x ≈ 0.16) Song, Young-Sang; Chung, Jae-Ho; Woo Shin, Kwang Applied Physics Letters, Vol. 104, Issue 25 https://doi.org/10.1063/1.4885392	journal	June 2014
Crystal structure, incommensurate magnetic order, and ferroelectricity in ${Mn}_{1 - x} {Cu}_{x} WO_{4} (0 \leq x \leq 0.19)$ Kumar, C. M. N.; Xiao, Y.; Lunkenheimer, P. Physical Review B, Vol. 91, Issue 23 https://doi.org/10.1103/PhysRevB.91.235149	journal	June 2015
Stabilization of the elliptical spiral phase and the spin-flop transition in multiferroic ${Mn}_{1 - x} {Co}_{x} {WO}_{4}$ Song, Y. -S.; Chung, J. -H.; Park, J. M. S. Physical Review B, Vol. 79, Issue 22 https://doi.org/10.1103/PhysRevB.79.224415	journal	June 2009
Chemical doping-induced flop of ferroelectric polarization in multiferroic ${Mn}_{0.9} {Co}_{0.1} {WO}_{4}$ Song, Y. -S.; Yan, Li Qin; Lee, Bumsung Physical Review B, Vol. 82, Issue 21 https://doi.org/10.1103/PhysRevB.82.214418	journal	December 2010
Magnetic and multiferroic phases of single-crystalline ${Mn}_{0.85} {Co}_{0.15} {WO}_{4}$ Chaudhury, R. P.; Ye, F.; Fernandez-Baca, J. A. Physical Review B, Vol. 82, Issue 18 https://doi.org/10.1103/PhysRevB.82.184422	journal	November 2010
Magnetic order and spin-flop transitions in the cobalt-doped multiferroic Mn $_{1 - x}$ Co $_{x}$ WO $_{4}$ Ye, Feng; Chi, Songxue; Fernandez-Baca, Jaime A. Physical Review B, Vol. 86, Issue 9 https://doi.org/10.1103/PhysRevB.86.094429	journal	September 2012
Conical antiferromagnetic order in the ferroelectric phase of Mn $_{0.8}$ Co $_{0.2}$ WO $_{4}$ resulting from the competition between collinear and cycloidal structures Urcelay-Olabarria, I.; Ressouche, E.; Mukhin, A. A. Physical Review B, Vol. 85, Issue 22 https://doi.org/10.1103/PhysRevB.85.224419	journal	June 2012
Neutron diffraction, magnetic, and magnetoelectric studies of phase transitions in multiferroic Mn $_{0.90}$ Co $_{0.10}$ WO $_{4}$ Urcelay-Olabarria, I.; Ressouche, E.; Mukhin, A. A. Physical Review B, Vol. 85, Issue 9 https://doi.org/10.1103/PhysRevB.85.094436	journal	March 2012
Magnetic-field-induced spontaneous polarization reversal in multiferroic ${Mn}_{0.85}$ ${Co}_{0.15}$ ${WO}_{4}$ Poudel, N.; Liang, K. -C.; Wang, Y. -Q. Physical Review B, Vol. 89, Issue 5 https://doi.org/10.1103/PhysRevB.89.054414	journal	February 2014
The complex multiferroic phase diagram of Mn _{1− x} Co _x WO ₄ Liang, K-C; Wang, Y-Q; Sun, Y. Y. New Journal of Physics, Vol. 14, Issue 7 https://doi.org/10.1088/1367-2630/14/7/073028	journal	July 2012
Local symmetry and magnetic anisotropy in multiferroic ${MnWO}_{4}$ and antiferromagnetic ${CoWO}_{4}$ studied by soft x-ray absorption spectroscopy Hollmann, N.; Hu, Z.; Willers, T. Physical Review B, Vol. 82, Issue 18 https://doi.org/10.1103/PhysRevB.82.184429	journal	November 2010
Competing Magnetic Anisotropy Fields and Double Polarization Flops in Multiferroic Mn _{1- x} Co _x WO ₄ Song, Young-Sang; Chung, Jae-Ho; Hwan Chun, Sae Journal of the Physical Society of Japan, Vol. 82, Issue 12 https://doi.org/10.7566/JPSJ.82.124716	journal	December 2013
Pressure effects on the electronic and optical properties of $A$ WO $_{4}$ wolframites ( $A$ $=$ Cd, Mg, Mn, and Zn): The distinctive behavior of multiferroic MnWO $_{4}$ Ruiz-Fuertes, J.; López-Moreno, S.; López-Solano, J. Physical Review B, Vol. 86, Issue 12 https://doi.org/10.1103/PhysRevB.86.125202	journal	September 2012
Pressure and temperature dependence of Raman scattering of MnWO4 Dai, R. C.; Ding, X.; Wang, Z. P. Chemical Physics Letters, Vol. 586 https://doi.org/10.1016/j.cplett.2013.09.035	journal	October 2013
Room-temperature vibrational properties of multiferroic MnWO ₄ under quasi-hydrostatic compression up to 39 GPa Ruiz-Fuertes, J.; Errandonea, D.; Gomis, O. Journal of Applied Physics, Vol. 115, Issue 4 https://doi.org/10.1063/1.4863236	journal	January 2014
High-pressure structural phase transition in ${MnWO}_{4}$ Ruiz-Fuertes, J.; Friedrich, A.; Gomis, O. Physical Review B, Vol. 91, Issue 10 https://doi.org/10.1103/PhysRevB.91.104109	journal	March 2015
Origin of multiferroicity in MnWO $_{4}$ Solovyev, I. V. Physical Review B, Vol. 87, Issue 14 https://doi.org/10.1103/PhysRevB.87.144403	journal	April 2013
Direct observation of noncollinear order of Co and Mn moments in multiferroic $M n_{0.85} C o_{0.15} W O_{4}$ Herrero-Martín, J.; Dobrynin, A. N.; Mazzoli, C. Physical Review B, Vol. 91, Issue 22 https://doi.org/10.1103/PhysRevB.91.220403	journal	June 2015

Cited By (1)

A Brief Review of the Effects of Pressure on Wolframite-Type Oxides Errandonea, Daniel; Ruiz-Fuertes, Javier Crystals, Vol. 8, Issue 2 https://doi.org/10.3390/cryst8020071	journal	January 2018

Similar Records

Magnetic orders and spin-flop transitions in the cobalt doped multiferroic $\rm Mn_{1-x}Co_{x}WO_4$

Journal Article · Sun Jan 01 00:00:00 EST 2012 · Physical Review B · OSTI ID:1324079

Chi, Songxue; Fernandez-Baca, Jaime A; Cao, Huibo; +4 more

HT-solution growth and characterisation of In{sub x}Na{sub x}Mn{sub 1-2x}WO{sub 4} (0

Journal Article · Thu Dec 15 00:00:00 EST 2016 · Journal of Solid State Chemistry · OSTI ID:1324079

Gattermann, U.; Paulmann, C.; Benka, G.; +1 more

Comprehensive inelastic neutron scattering study of the multiferroic

{Mn}_{1 - x} {Co}_{x} {WO}_{4}

Journal Article · Fri Dec 14 00:00:00 EST 2018 · Physical Review B · OSTI ID:1324079

Wang, Jinchen; Fishman, Randy Scott; Qiu, Yiming; +7 more

Related Subjects

36 MATERIALS SCIENCE

Title: Pressure effects on magnetic ground states in cobalt doped multiferroic Mn1-xCoxWO4

Citation Formats

References (47)

Cited By (1)

Similar Records

Related Subjects

Title: Pressure effects on magnetic ground states in cobalt doped multiferroic Mn_1-xCo_xWO₄