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Title: Oxidation of manganese in an ancient aquifer, Kimberley formation, Gale crater, Mars

Journal Article · · Geophysical Research Letters
DOI:https://doi.org/10.1002/2016GL069109· OSTI ID:1304809
 [1];  [1];  [2];  [3];  [4];  [5];  [4];  [6];  [6];  [7];  [8];  [9];  [10];  [11];  [12];  [11];  [5];  [1];  [13];  [14] more »;  [15];  [16];  [13];  [17];  [18];  [9];  [12];  [13];  [19];  [14];  [19];  [20];  [13];  [21];  [7];  [22];  [1];  [23];  [13];  [24];  [25];  [5];  [26];  [27] « less
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  2. Washington Univ., St. Louis, MO (United States). Dept. of Earth and Planetary Sciences
  3. Space Science Inst., Boulder, CO (United States)
  4. California Inst. of Technology (CalTech), Pasadena, CA (United States)
  5. Univ. of Guelph, ON (Canada)
  6. Stony Brook Univ., NY (United States). Dept. of Geosciences
  7. NASA Johnson Space Center, Houston, TX (United States)
  8. Western Washington Univ., Bellingham, WA (United States). Geology Dept.
  9. Arizona State Univ., Tempe, AZ (United States). School of Earth and Space Exploration
  10. Univ. of Western Ontario, London, ON (Canada). Dept. of Earth Sciences
  11. California Inst. of Technology (CalTech), La Canada Flintridge, CA (United States). Jet Propulsion Lab.
  12. Johns Hopkins Univ., Baltimore, MD (United States). Applied Physics Lab.
  13. Univ. Toulouse III - Paul Sabatier (UPS), Toulouse (France). Observatoire Midi-Pyrenees (OMP), Inst. for Research in Astrophysics and Planetology (IRAP)
  14. Malin Space Science Systems, San Diego, CA (United States)
  15. Univ. de Lorraine, Nancy (France). GeoRessources Lab.
  16. Oregon State Univ., Corvallis, OR (United States). College of Earth, Ocean, and Atmospheric Sciences
  17. Univ. of Copenhagen (Denmark). The Niels Bohr Inst.
  18. U.S. Naval Academy, Annapolis Maryland (United States). Aerospace Engineering
  19. Univ. de Nantes, Nantes (France)
  20. Lulea Univ. of Technology, Kiruna (Sweden). Dept. of Computer Science, Electrical and Space Engineering; Univ. of Granada (Spain). Andalusian Inst. of Earth Sciences (CSIC-UGR)
  21. Purdue Univ., West Lafayette, IN (United States). Earth, Atmospheric, and Planetary Science
  22. Univ. of New Mexico, Albuquerque, NM (United States). Inst. of Meteoritics
  23. Natural History Museum ( IMPMC), Paris (France).
  24. Univ. of New Brunswick, Fredericton NB (Canada). Planetary and Space Science Centre
  25. Lunar and Planetary Inst., Houston Texas (United States)
  26. Planetary Science Inst., Tucson, AZ (United States)
  27. Lulea Univ. of Technology, Kiruna (Sweden). Dept. of Computer Science, Electrical and Space Engineering; Centro de Astrobiologia (CAB), Madrid (Spain)
+ Show Author Affiliations

We report that the Curiosity rover observed high Mn abundances (>25 wt % MnO) in fracture-filling materials that crosscut sandstones in the Kimberley region of Gale crater, Mars. The correlation between Mn and trace metal abundances plus the lack of correlation between Mn and elements such as S, Cl, and C, reveals that these deposits are Mn oxides rather than evaporites or other salts. On Earth, environments that concentrate Mn and deposit Mn minerals require water and highly oxidizing conditions; hence, these findings suggest that similar processes occurred on Mars. In conclusion, based on the strong association between Mn-oxide deposition and evolving atmospheric dioxygen levels on Earth, the presence of these Mn phases on Mars suggests that there was more abundant molecular oxygen within the atmosphere and some groundwaters of ancient Mars than in the present day.

Research Organization:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
National Aeronautics and Space Administration (NASA); USDOE
Grant/Contract Number:
AC52-06NA25396
OSTI ID:
1304809
Report Number(s):
LA-UR-15-20086
Journal Information:
Geophysical Research Letters, Vol. 43, Issue 14; ISSN 0094-8276
Publisher:
American Geophysical UnionCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 86 works
Citation information provided by
Web of Science

References (43)

Organic molecules in the Sheepbed Mudstone, Gale Crater, Mars: Detection of organics in martian sample journal March 2015
The Chemistry of Manganese Ores through Time: A Signal of Increasing Diversity of Earth-Surface Environments journal May 2010
Chemistry and texture of the rocks at Rocknest, Gale Crater: Evidence for sedimentary origin and diagenetic alteration: ROCKNEST CHEMISTRY AND TEXTURE journal September 2014
Coordinated analyses of orbital and Spirit Rover data to characterize surface materials on the cratered plains of Gusev Crater, Mars journal January 2007
Mineralogy of a Mudstone at Yellowknife Bay, Gale Crater, Mars journal December 2013
Coupled biotic–abiotic Mn(II) oxidation pathway mediates the formation and structural evolution of biogenic Mn oxides journal October 2011
A review of the formation of tectonic veins and their microstructures journal October 2012
Volatile and Organic Compositions of Sedimentary Rocks in Yellowknife Bay, Gale Crater, Mars journal December 2013
Sequence of infilling events in Gale Crater, Mars: Results from morphology, stratigraphy, and mineralogy: SEDIMENTARY INFILLING IN GALE CRATER journal December 2013
Elemental Geochemistry of Sedimentary Rocks at Yellowknife Bay, Gale Crater, Mars journal December 2013
Mineral evolution journal November 2008
Manganese oxide minerals: Crystal structures and economic and environmental significance journal March 1999
Pre-flight calibration and initial data processing for the ChemCam laser-induced breakdown spectroscopy instrument on the Mars Science Laboratory rover journal April 2013
Mass-Independent Fractionation of Sulfur Isotopes in Archean Sediments: Strong Evidence for an Anoxic Archean Atmosphere journal March 2002
Manganese mineralogy and diagenesis in the sedimentary rock record journal January 2016
The nature of coarse-grained crystalline hematite and its implications for the early environment of Mars journal October 2003
Observation of > 5 wt % zinc at the Kimberley outcrop, Gale crater, Mars: ZN DETECTION AT KIMBERLEY WITH CHEMCAM journal March 2016
Evidence for perchlorates and the origin of chlorinated hydrocarbons detected by SAM at the Rocknest aeolian deposit in Gale Crater: EVIDENCE FOR PERCHLORATES AT ROCKNEST journal October 2013
Paleoproterozoic snowball Earth: Extreme climatic and geochemical global change and its biological consequences journal February 2000
Deposition, exhumation, and paleoclimate of an ancient lake deposit, Gale crater, Mars journal October 2015
Understanding the signature of rock coatings in laser-induced breakdown spectroscopy data journal March 2015
Comparing orbiter and rover image-based mapping of an ancient sedimentary environment, Aeolis Palus, Gale crater, Mars journal December 2016
High concentrations of manganese and sulfur in deposits on Murray Ridge, Endeavour Crater, Mars journal June 2016
The Role of One- and Two-Electron Transfer Reactions in Forming Thermodynamically Unstable Intermediates as Barriers in Multi-Electron Redox Reactions journal December 2009
Rapid photo-oxidation of Mn(II) mediated by humic substances journal December 2002
The role of fluids in syntectonic mass transport, and the localization of metamorphic vein-type ore deposists journal May 1987
Shallow breathing: bacterial life at low O2 journal February 2013
Mineralogy, provenance, and diagenesis of a potassic basaltic sandstone on Mars: CheMin X-ray diffraction of the Windjana sample (Kimberley area, Gale Crater): CHEMIN: WINDJANA journal January 2016
Collecting Samples in Gale Crater, Mars; an Overview of the Mars Science Laboratory Sample Acquisition, Sample Processing and Handling System journal June 2012
Natural speciation of Ni, Zn, Ba, and As in ferromanganese coatings on quartz using X-ray fluorescence, absorption, and diffraction journal January 2007
Origin of acidic surface waters and the evolution of atmospheric chemistry on early Mars journal April 2010
Volatile, Isotope, and Organic Analysis of Martian Fines with the Mars Curiosity Rover journal September 2013
Abundance and Isotopic Composition of Gases in the Martian Atmosphere from the Curiosity Rover journal July 2013
Curiosity at Gale Crater, Mars: Characterization and Analysis of the Rocknest Sand Shadow journal September 2013
Transport-driven formation of a polar ozone layer on Mars journal September 2013
Manganese-oxidizing photosynthesis before the rise of cyanobacteria journal June 2013
High manganese concentrations in rocks at Gale crater, Mars journal August 2014
Mineralogical record of the redox conditions on early Mars journal June 2016
Volcanism on Mars controlled by early oxidation of the upper mantle journal June 2013
Evidence for direct molecular oxygen production in CO 2 photodissociation journal October 2014
Atmosphere-Surface Interactions on Mars: 17O Measurements of Carbonate from ALH 84001  journal June 1998
ChemCam passive reflectance spectroscopy of surface materials at the Curiosity landing site, Mars journal March 2015
The potassic sedimentary rocks in Gale Crater, Mars, as seen by ChemCam on board Curiosity : Potassic Sedimentary Rocks, Gale Crater journal May 2016

Cited By (11)

Diverse Lithologies and Alteration Events on the Rim of Noachian-Aged Endeavour Crater, Meridiani Planum, Mars: In Situ Compositional Evidence journal May 2018
Solar Models with Dynamic Screening and Early Mass Loss Tested by Helioseismic, Astrophysical, and Planetary Constraints journal July 2018
Highly Oxidizing Aqueous Environments on Early Mars Inferred From Scavenging Pattern of Trace Metals on Manganese Oxides journal May 2019
The next frontier for planetary and human exploration journal January 2019
Insights into microbial involvement in desert varnish formation retrieved from metagenomic analysis: The desert varnish microbiome journal March 2018
Oxygen isotope analysis of bacterial and fungal manganese oxidation journal April 2018
The potential science and engineering value of samples delivered to Earth by Mars sample return: International MSR Objectives and Samples Team (iMOST) journal March 2019
The origin of life as a planetary phenomenon journal February 2020
The potential science and engineering value of samples delivered to Earth by Mars sample return journal March 2019
The potential science and engineering value of samples delivered to Earth by Mars sample return text January 2019
Solar Models with dynamic screening and early mass loss tested by helioseismic, astrophysical, and planetary constraints text January 2018

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Related Subjects

36 MATERIALS SCIENCE
79 ASTRONOMY AND ASTROPHYSICS
Planetary Sciences
Mars
ChemCam
manganese
oxygen
MSL