skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Methods for synthesizing metal oxide nanowires

Patent ·
OSTI ID:1289951

A method of synthesizing a metal oxide nanowire includes the steps of: combining an amount of a transition metal or a transition metal oxide with an amount of an alkali metal compound to produce a mixture; activating a plasma discharge reactor to create a plasma discharge; exposing the mixture to the plasma discharge for a first predetermined time period such that transition metal oxide nanowires are formed; contacting the transition metal oxide nanowires with an acid solution such that an alkali metal ion is exchanged for a hydrogen ion on each of the transition metal oxide nanowires; and exposing the transition metal oxide nanowires to the plasma discharge for a second predetermined time period to thermally anneal the transition metal oxide nanowires. Transition metal oxide nanowires produced using the synthesis methods described herein are also provided.

Research Organization:
University of Louisville Research Foundation, Louisville, KY (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
EE0003206; FG36-05GO85013
Assignee:
University of Louisville Research Foundation (Louisville, KY)
Patent Number(s):
9,409,141
Application Number:
13/183,191
OSTI ID:
1289951
Resource Relation:
Patent File Date: 2011 Jul 14
Country of Publication:
United States
Language:
English

References (47)

Composite of TiO2 nanowires and Nafion as humidity sensor material journal May 2006
Monolithic high aspect ratio nano-size scanning probe microscope (SPM) tip formed by nanowire growth patent August 2009
Characterization of h-WO3 nanorods synthesized by hydrothermal process journal May 2010
Crystallographically Oriented Mesoporous WO3 Films:  Synthesis, Characterization, and Applications
  • Santato, Clara; Odziemkowski, Marek; Ulmann, Martine
  • Journal of the American Chemical Society, Vol. 123, Issue 43, p. 10639-10649 https://doi.org/10.1021/ja011315x
journal October 2001
Surface tensions of molten alkali-metal halides journal March 1990
Direct Synthesis of Gallium Oxide Tubes, Nanowires, and Nanopaintbrushes journal October 2002
Bulk synthesis of silicon nanowires using a low-temperature vapor–liquid–solid method journal September 2001
Large-Scale, Hot-Filament-Assisted Synthesis of Tungsten Oxide and Related Transition Metal Oxide Nanowires journal May 2007
Structural Features of Nanotubes Synthesized from NaOH Treatment on TiO 2 with Different Post-Treatments journal January 2006
Controlled Growth and Field-Emission Properties of Cobalt Oxide Nanowalls journal July 2005
Interfacial interaction and mechanical properties of nylon 6-potassium titanate composites prepared by in-situ polymerization journal June 1997
Electrochemical capacitance study on Co3O4 nanowires for super capacitors application journal August 2010
Large aspect ratio titanate nanowire prepared by monodispersed titania submicron sphere via simple wet-chemical reactions journal March 2007
Synthesis and characterization of large scale potassium titanate nanowires with good Li-intercalation performance journal April 2005
Preparation of Smooth Single-Crystal Mn3O4 Nanowires journal June 2002
Fabrication and photoluminescence characteristics of single crystalline In2O3 nanowires journal May 2003
Characterization and catalytic activity for the NO decomposition and reduction by CO of nanosized Co3O4 journal April 2005
Catalytic growth of Ga2O3 nanowires by physical evaporation and their photoluminescence properties journal April 2003
Hydrothermal synthesis and photoluminescence of TiO2 nanowires journal October 2002
Synthesis of large-scaled MoO2 nanowire arrays journal December 2003
Nanowires and 1D arrays fabrication: An overview journal January 2006
Highly Efficient Dye-Sensitized Solar Cells with a Titania Thin-Film Electrode Composed of a Network Structure of Single-Crystal-like TiO 2 Nanowires Made by the “Oriented Attachment” Mechanism journal November 2004
TiO2(B) Nanowires as an Improved Anode Material for Lithium-Ion Batteries Containing LiFePO4 or LiNi0.5Mn1.5O4 Cathodes and a Polymer Electrolyte journal October 2006
Controlled Growth and Characterization of Tungsten Oxide Nanowires Using Thermal Evaporation of WO 3 Powder journal December 2006
Templated Nanocrystal-Based Porous TiO2 Films for Next-Generation Electrochemical Capacitors journal February 2009
A continuous and clean one-step synthesis of nano-particulate Ce1−xZrxO2 solid solutions in near-critical water journal January 2000
Synthesis and characterization of Mn3O4 nanoparticles journal March 2004
Rationalization of Nanowire Synthesis Using Low-Melting Point Metals journal September 2006
Bulk-quantity synthesis and self-catalytic VLS growth of SnO2 nanowires by lower-temperature evaporation journal February 2003
Long K-Doped Titania and Titanate Nanowires on Ti Foil and FTO/Quartz Substrates for Solar-Cell Applications journal March 2007
Rapid Synthesis of Titania Nanowires by Microwave-Assisted Hydrothermal Treatments journal April 2008
Spontaneous Growth of Superstructure α -Fe 2 O 3 Nanowire and Nanobelt Arrays in Reactive Oxygen Plasma journal October 2008
Bicrystalline zinc oxide nanowires journal June 2003
Infrared and Raman study of WO3 tungsten trioxides and WO3, xH2O tungsten trioxide tydrates journal April 1987
Examination of Neumann's Equation-of-State for Interfacial Tensions journal October 1994
Potassium titanate nanowires:  Structure, growth, and optical properties journal January 2003
Facile and large-scale synthesis of single-crystalline manganese oxyhydroxide/oxide nanostructures journal September 2007
TiO2 nanowires array fabrication and gas sensing properties journal March 2008
A comparison study on Raman scattering properties of α- and β-MnO2 journal August 2009
Large-scale synthesis of single-crystal hexagonal tungsten trioxide nanowires and electrochemical lithium intercalation into the nanocrystals journal January 2007
Band-Edge Engineered Hybrid Structures for Dye-Sensitized Solar Cells Based on SnO 2 Nanowires journal August 2008
Gas-phase synthesis of nitrogen-doped TiO2 nanorods by microwave plasma torch at atmospheric pressure journal November 2005
A hierarchical nanostructure consisting of amorphous MnO2, Mn3O4 nanocrystallites, and single-crystalline MnOOH nanowires for supercapacitors journal January 2011
Ultraviolet photoconductance of a single hexagonal WO3 nanowire journal March 2010
Synthesis of TiO2 nanowires and their photocatalytic activity for hydrogen evolution journal March 2008
Nanophase materials by a novel microwave-hydrothermal process journal January 2002
Co3O4 Nanomaterials in Lithium-Ion Batteries and Gas Sensors journal May 2005

Similar Records

Nanowire CdS-CdTe solar cells with molybdenum oxide as contact
Journal Article · Tue Oct 06 00:00:00 EDT 2015 · Scientific Reports · OSTI ID:1289951

Transition metal oxide nanowires synthesized by heating metal substrates
Journal Article · Tue Nov 15 00:00:00 EST 2011 · Materials Research Bulletin · OSTI ID:1289951

Thermal annealing synthesis of titanium-dioxide nanowire-nanoparticle hetero-structures
Journal Article · Fri Oct 15 00:00:00 EDT 2010 · Journal of Solid State Chemistry · OSTI ID:1289951