Nanoporous ionic organic networks: stablizing and supporting gold nanoparticles for catalysis

Zhang, Pengfei; Qiao, Zhen-An; Jiang, Xueguang; Veith, Gabriel M.; Dai, Sheng

doi:10.1021/nl504780j

Title: Nanoporous ionic organic networks: stablizing and supporting gold nanoparticles for catalysis

Journal Article · Tue Jan 27 00:00:00 EST 2015 · Nano Letters

DOI:https://doi.org/10.1021/nl504780j· OSTI ID:1265360

Zhang, Pengfei ^[1]; Qiao, Zhen-An ^[1]; Jiang, Xueguang ^[2]; Veith, Gabriel M. ^[3]; Dai, Sheng ^[4]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Univ. of Tennessee, Knoxville, TN (United States). Department of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Department of Chemistry

In this article, nanoporous ionic organic networks (PIONs) with a high ionic density (three cation–anion pairs per unit) have been synthesized by a facile S_N2 nucleophilic substitution reaction. Owing to the electrostatic and steric effect, those ionic networks with porous channels can stabilize and support gold (Au) nanoparticles (NPs) in 1–2 nm. We find the Au@PION hybrid materials used as a heterogeneous catalyst are highly active, selective, and stable in the aerobic oxidation of saturated alcohols.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1265360

Journal Information:: Nano Letters, Vol. 15, Issue 2; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 124 works

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