Preparation of porous Si and TiO2 nanofibres using a sulphur-templating method for lithium storage

McCormac, Kathleen; Byrd, Ian; Brannen, Rodney; Seymour, Bryan; Li, Jianlin; Wu, Ji

doi:10.1002/pssa.201431834

Title: Preparation of porous Si and TiO₂ nanofibres using a sulphur-templating method for lithium storage

Journal Article · Tue Feb 03 00:00:00 EST 2015 · Physica Status Solidi. A, Applications and Materials Science

DOI:https://doi.org/10.1002/pssa.201431834· OSTI ID:1261427

McCormac, Kathleen ^[1]; Byrd, Ian ^[1]; Brannen, Rodney ^[1]; Seymour, Bryan ^[1]; Li, Jianlin ^[2]; Wu, Ji ^[1]

Georgia Southern Univ., Statesboro, GA (United States) Dept. of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy and Transportation Science Division

In this paper, highly porous Si/TiO₂ composite nanofibres were prepared using a unique sulphur-templating method combined with electrospinning. The structure, morphology, surface area, phase and composition of these nanofibres were characterized using Raman spectroscopy, scanning electron microscopy, powder X-ray diffraction, surface area analyser and thermogravimetric analyser. Finally, the specific surface area of Si/TiO₂ porous NFs is as large as 387 m² g^-1, whose silicon capacity can be maintained above 1580 mAh g^-1 in 180 cycles.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Contributing Organization:: Georgia Southern Univ., Statesboro, GA (United States)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1261427

Alternate ID(s):: OSTI ID: 1286743

Journal Information:: Physica Status Solidi. A, Applications and Materials Science, Vol. 212, Issue 4; ISSN 1862-6300

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 18 works

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Natural Cellulose Derived Nanocomposites as Anodic Materials for Lithium‐Ion Batteries Lin, Zehao; Li, Shun; Huang, Jianguo The Chemical Record https://doi.org/10.1002/tcr.201900030	journal	July 2019
Electrospun porous nanofibers for electrochemical energy storage Li, Zhi; Zhang, Ji-wei; Yu, Lai-gui Journal of Materials Science, Vol. 52, Issue 11 https://doi.org/10.1007/s10853-017-0794-2	journal	January 2017
Toward Low-Cost, High-Energy Density, and High-Power Density Lithium-Ion Batteries Li, Jianlin; Du, Zhijia; Ruther, Rose E. JOM, Vol. 69, Issue 9 https://doi.org/10.1007/s11837-017-2404-9	journal	June 2017
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Title: Preparation of porous Si and TiO2 nanofibres using a sulphur-templating method for lithium storage

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References (21)

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Title: Preparation of porous Si and TiO₂ nanofibres using a sulphur-templating method for lithium storage