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Title: Method for characterization of the rate of movement of an oxidation front in cementitious materials

Patent ·
OSTI ID:1240733

Disclosed are methods for determining the redox condition of cementitious materials. The methods are leaching methods that utilize a redox active transition metal indicator that is present in the cementitious material and exhibits variable solubility depending upon the oxidation state of the indicator. When the leaching process is carried out under anaerobic conditions, the presence or absence of the indicator in the leachate can be utilized to determine the redox condition of and location of the oxidation front in the material that has been subjected to the leaching process.

Research Organization:
Savannah River Site (SRS), Aiken, SC (United States). Savannah River Technology Center (SRTC)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC09-08SR22470
Assignee:
Savannah River Nuclear Solutions, LLC (Aiken, SC)
Patent Number(s):
9,274,093
Application Number:
13/973,567
OSTI ID:
1240733
Resource Relation:
Patent File Date: 2013 Aug 22
Country of Publication:
United States
Language:
English

References (8)

Method Evaluation And Field Sample Measurements For The Rate Of Movement Of The Oxidation Front In Saltstone report August 2012
The usefulness of UV–visible and fluorescence spectroscopies to study the chemical nature of humic substances from soils and composts journal December 2006
Characterization of Predominant Reductants in an Anaerobic Leachate-Contaminated Aquifer by Nitroaromatic Probe Compounds journal January 1998
Landfill Management, Leachate Generation, and Leach Testing of Solid Wastes in Australia and Overseas journal March 2005
Leaching of Saltstone journal January 1984
Slag-Based Saltstone Formulations journal January 1987
Effect of Redox Potential on Leaching from Stabilized/Solidified Waste Materials journal January 1992
In situ anaerobic bioremediation of earth and sold waste contaminants using organic/water emulsions patent September 2004