Comparing highly ordered monolayers of nanoparticles fabricated using electrophoretic deposition: Cobalt ferrite nanoparticles versus iron oxide nanoparticles

Dickerson, James H.; Krejci, Alex J.; Garcia, Adriana -Mendoza; Sun, Shouheng; Pham, Viet Hung

doi:10.1149/2.0171511jes

Title: Comparing highly ordered monolayers of nanoparticles fabricated using electrophoretic deposition: Cobalt ferrite nanoparticles versus iron oxide nanoparticles

Journal Article · Sat Aug 01 00:00:00 EDT 2015 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0171511jes· OSTI ID:1235850

Dickerson, James H. ^[1]; Krejci, Alex J. ^[2]; Garcia, Adriana -Mendoza ^[3]; Sun, Shouheng ^[3]; Pham, Viet Hung ^[4]

Brookhaven National Lab. (BNL), Upton, NY (United States); Brown Univ., Providence, RI (United States)
SUNY Korea, Incheon (South Korea); Stony Brook Univ., Stony Brook, NY (United States)
Brown Univ., Providence, RI (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Ordered assemblies of nanoparticles remain challenging to fabricate, yet could open the door to many potential applications of nanomaterials. Here, we demonstrate that locally ordered arrays of nanoparticles, using electrophoretic deposition, can be extended to produce long-range order among the constituents. Voronoi tessellations along with multiple statistical analyses show dramatic increases in order compared with previously reported assemblies formed through electric field-assisted assembly. As a result, based on subsequent physical measurements of the nanoparticles and the deposition system, the underlying mechanisms that generate increased order are inferred.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1235850

Report Number(s):: BNL-108608-2015-JA; KC0403020

Journal Information:: Journal of the Electrochemical Society, Vol. 162, Issue 11; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 4 works

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Title: Comparing highly ordered monolayers of nanoparticles fabricated using electrophoretic deposition: Cobalt ferrite nanoparticles versus iron oxide nanoparticles

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