Mesoscale Particle-Based Model of Electrophoresis

Giera, Brian; Zepeda-Ruiz, Luis A.; Pascall, Andrew J.; Kuntz, Joshua D.; Spadaccini, Christopher M.; Weisgraber, Todd H.

doi:10.1149/2.0161511jes

Title: Mesoscale Particle-Based Model of Electrophoresis

Journal Article · Fri Jul 31 00:00:00 EDT 2015 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0161511jes· OSTI ID:1234595

Giera, Brian ^[1]; Zepeda-Ruiz, Luis A. ^[1]; Pascall, Andrew J. ^[1]; Kuntz, Joshua D. ^[1]; Spadaccini, Christopher M. ^[1]; Weisgraber, Todd H. ^[1]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States). Center for Micro- and Nano-Technology

Here, we develop and evaluate a semi-empirical particle-based model of electrophoresis using extensive mesoscale simulations. We parameterize the model using only measurable quantities from a broad set of colloidal suspensions with properties that span the experimentally relevant regime. With sufficient sampling, simulated diffusivities and electrophoretic velocities match predictions of the ubiquitous Stokes-Einstein and Henry equations, respectively. This agreement holds for non-polar and aqueous solvents or ionic liquid colloidal suspensions under a wide range of applied electric fields.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 1234595

Report Number(s):: LLNL-JRNL-669534

Journal Information:: Journal of the Electrochemical Society, Vol. 162, Issue 11; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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References (33)

Electrophoretic Deposition (EPD): Mechanisms, Kinetics, and Application to Ceramics Sarkar, Partho; Nicholson, Patrick S. Journal of the American Ceramic Society, Vol. 79, Issue 8 https://doi.org/10.1111/j.1151-2916.1996.tb08929.x	journal	August 1996
Electrophoretic deposition of carbon nanotubes Boccaccini, Aldo R.; Cho, Johann; Roether, Judith A. Carbon, Vol. 44, Issue 15 https://doi.org/10.1016/j.carbon.2006.06.021	journal	December 2006
Preparation of ordered colloid monolayers by electrophoretic deposition Giersig, Michael; Mulvaney, Paul Langmuir, Vol. 9, Issue 12 https://doi.org/10.1021/la00036a014	journal	December 1993
On-Demand and Location Selective Particle Assembly via Electrophoretic Deposition for Fabricating Structures with Particle-to-Particle Precision Qian, Fang; Pascall, Andrew J.; Bora, Mihail Langmuir, Vol. 31, Issue 12 https://doi.org/10.1021/la502724n	journal	October 2014
Electrophoretic deposition of biomaterials Boccaccini, A. R.; Keim, S.; Ma, R. Journal of The Royal Society Interface, Vol. 7, Issue suppl_5 https://doi.org/10.1098/rsif.2010.0156.focus	journal	May 2010
Toward Dynamic Control over TiO ₂ Nanocrystal Monolayer-by-Monolayer Film Formation by Electrophoretic Deposition in Nonpolar Solvents Gonzalo-Juan, I.; Krejci, Alex J.; Dickerson, J. H. Langmuir, Vol. 28, Issue 11 https://doi.org/10.1021/la205124s	journal	March 2012
Electric Field Controlled Columnar and Planar Patterning of Cholesteric Colloids D’Adamo, G.; Marenduzzo, D.; Micheletti, C. Physical Review Letters, Vol. 114, Issue 17 https://doi.org/10.1103/PhysRevLett.114.177801	journal	April 2015
Application of Ionic Liquids in the Electrophoretic Deposition of Oxide Layers Grosse-Brauckmann, Jana; Lair, Virginie; Argirusis, Christos Key Engineering Materials, Vol. 412 https://doi.org/10.4028/www.scientific.net/KEM.412.27	journal	June 2009
Light-Directed Electrophoretic Deposition: A New Additive Manufacturing Technique for Arbitrarily Patterned 3D Composites Pascall, Andrew J.; Qian, Fang; Wang, Gongming Advanced Materials, Vol. 26, Issue 14, p. 2252-2256 https://doi.org/10.1002/adma.201304953	journal	February 2014
Electrophoretic deposition as rapid prototyping method Nold, A.; Zeiner, J.; Assion, T. Journal of the European Ceramic Society, Vol. 30, Issue 5 https://doi.org/10.1016/j.jeurceramsoc.2009.03.021	journal	March 2010
Local Electrophoretic Deposition with Coaxial Electrodes Nold, Alexander; Assion, Thomas; Zeiner, Johannes Key Engineering Materials, Vol. 412 https://doi.org/10.4028/www.scientific.net/KEM.412.307	journal	June 2009
A review on fundamentals and applications of electrophoretic deposition (EPD) Besra, Laxmidhar; Liu, Meilin Progress in Materials Science, Vol. 52, Issue 1, p. 1-61 https://doi.org/10.1016/j.pmatsci.2006.07.001	journal	January 2007
Direct Numerical Simulations of Electrophoretic Deposition of Charged Colloidal Suspensions Park, Jae Sung; Saintillan, David Key Engineering Materials, Vol. 507 https://doi.org/10.4028/www.scientific.net/KEM.507.47	journal	March 2012
EPD kinetics: A review Ferrari, Begoña; Moreno, Rodrigo Journal of the European Ceramic Society, Vol. 30, Issue 5 https://doi.org/10.1016/j.jeurceramsoc.2009.08.022	journal	March 2010
Formation of a deposit by electrophoresis Hamaker, H. C. Transactions of the Faraday Society, Vol. 35 https://doi.org/10.1039/tf9403500279	journal	January 1940
A Resistivity Model for Electrophoretic Deposition Ferrari, Begoña; Moreno, Rodrigo; Cuesta, Jose A. Key Engineering Materials, Vol. 314 https://doi.org/10.4028/www.scientific.net/KEM.314.175	journal	July 2006
Modeling constant voltage electrophoretic deposition from a stirred suspension González-Cuenca, Mercedes; Biesheuvel, P. Maarten; Verweij, Henk AIChE Journal, Vol. 46, Issue 3 https://doi.org/10.1002/aic.690460321	journal	March 2000
Morphology of Electrophoretically Deposited Films on Electrode Strips Pascall, Andrew J.; Sullivan, Kyle T.; Kuntz, Joshua D. The Journal of Physical Chemistry B, Vol. 117, Issue 6 https://doi.org/10.1021/jp306447n	journal	August 2012
Discrete element modeling of solid formation during electrophoretic deposition Cordelair, J.; Greil, P. Journal of Materials Science, Vol. 39, Issue 3 https://doi.org/10.1023/B:JMSC.0000012935.48724.7f	journal	February 2004
Über die von der molekularkinetischen Theorie der Wärme geforderte Bewegung von in ruhenden Flüssigkeiten suspendierten Teilchen Einstein, A. Annalen der Physik, Vol. 322, Issue 8 https://doi.org/10.1002/andp.19053220806	journal	January 1905
Electrophoresis of a particle of arbitrary shape Morrison, F. A. Journal of Colloid and Interface Science, Vol. 34, Issue 2 https://doi.org/10.1016/0021-9797(70)90171-2	journal	October 1970
Dissipative particle dynamics: Bridging the gap between atomistic and mesoscopic simulation Groot, Robert D.; Warren, Patrick B. The Journal of Chemical Physics, Vol. 107, Issue 11 https://doi.org/10.1063/1.474784	journal	September 1997
Computation of shear viscosity of colloidal suspensions by SRD-MD Laganapan, A. M. K.; Videcoq, A.; Bienia, M. The Journal of Chemical Physics, Vol. 142, Issue 14 https://doi.org/10.1063/1.4917039	journal	April 2015
Performance of mesoscale modeling methods for predicting rheological properties of charged polystyrene/water suspensions Schunk, P. R.; Pierce, F.; Lechman, J. B. Journal of Rheology, Vol. 56, Issue 2 https://doi.org/10.1122/1.3690105	journal	March 2012
Particle dynamics modeling methods for colloid suspensions Bolintineanu, Dan S.; Grest, Gary S.; Lechman, Jeremy B. Computational Particle Mechanics, Vol. 1, Issue 3 https://doi.org/10.1007/s40571-014-0007-6	journal	May 2014
Fast Parallel Algorithms for Short-Range Molecular Dynamics Plimpton, Steve Journal of Computational Physics, Vol. 117, Issue 1 https://doi.org/10.1006/jcph.1995.1039	journal	March 1995
A simulation technique for many spheres in quasi-static motion under frame-invariant pair drag and Brownian forces Ball, R. C.; Melrose, J. R. Physica A: Statistical Mechanics and its Applications, Vol. 247, Issue 1-4 https://doi.org/10.1016/S0378-4371(97)00412-3	journal	December 1997
Origins of the anomalous stress behavior in charged colloidal suspensions under shear Kumar, Amit; Higdon, Jonathan J. L. Physical Review E, Vol. 82, Issue 5, Article No. 051401 https://doi.org/10.1103/PhysRevE.82.051401	journal	November 2010
Interaction potentials for soft and hard ellipsoids Everaers, R.; Ejtehadi, M. R. Physical Review E, Vol. 67, Issue 4 https://doi.org/10.1103/PhysRevE.67.041710	journal	April 2003
Measurement and interpretation of electrokinetic phenomena Delgado, A. V.; González-Caballero, F.; Hunter, R. J. Journal of Colloid and Interface Science, Vol. 309, Issue 2 https://doi.org/10.1016/j.jcis.2006.12.075	journal	May 2007
Macroscale description of electrokinetic flows at large zeta potentials: Nonlinear surface conduction Schnitzer, Ory; Yariv, Ehud Physical Review E, Vol. 86, Issue 2 https://doi.org/10.1103/PhysRevE.86.021503	journal	August 2012
Ion steric effects on electrophoresis of a colloidal particle Khair, Aditya S.; Squires, Todd M. Journal of Fluid Mechanics, Vol. 640 https://doi.org/10.1017/S0022112009991728	journal	November 2009
Hydrodynamic interactions in electrophoresis Reed, L. D.; Morrison, F. A. Journal of Colloid and Interface Science, Vol. 54, Issue 1 https://doi.org/10.1016/0021-9797(76)90291-5	journal	January 1976

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