Substrate interactions with suspended and supported monolayer MoS2: Angle-resolved photoemission spectroscopy

Jin, Wencan; Yeh, Po -Chun; Zaki, Nader; Zhang, Datong; Liou, Jonathan T.; Dadap, Jerry I.; Barinov, Alexey; Yablonskikh, Mikhail; Sadowski, Jerzy T.; Sutter, Peter; Herman, Irving P.; Osgood, Jr., Richard M.

doi:10.1103/PhysRevB.91.121409

Title: Substrate interactions with suspended and supported monolayer MoS₂: Angle-resolved photoemission spectroscopy

Journal Article · Tue Mar 17 00:00:00 EDT 2015 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.91.121409· OSTI ID:1182523

Jin, Wencan ^[1]; Yeh, Po -Chun ^[1]; Zaki, Nader ^[1]; Zhang, Datong ^[1]; Liou, Jonathan T. ^[1]; Dadap, Jerry I. ^[1]; Barinov, Alexey ^[2]; Yablonskikh, Mikhail ^[2]; Sadowski, Jerzy T. ^[3]; Sutter, Peter ^[3]; Herman, Irving P. ^[1]; Osgood, Jr., Richard M. ^[1]

Columbia Univ., New York, NY (United States)
Elettra Sincrotrone Trieste, Trieste (Italy)
Brookhaven National Lab. (BNL), Upton, NY (United States)

We report the directly measured electronic structure of exfoliated monolayer molybdenum disulfide (MoS₂) using micrometer-scale angle-resolved photoemission spectroscopy. Measurements of both suspended and supported monolayer MoS₂ elucidate the effects of interaction with a substrate. Thus, a suggested relaxation of the in-plane lattice constant is found for both suspended and supported monolayer MoS₂ crystals. For suspended MoS₂, a careful investigation of the measured uppermost valence band gives an effective mass at Γ¯ and Κ¯ of 2.00m₀ and 0.43m₀, respectively. We also measure an increase in the band linewidth from the midpoint of Γ¯Κ¯ to the vicinity of Κ¯ and briefly discuss its possible origin.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Re-Defining Photovoltaic Efficiency Through Molecule Scale Control (RPEMSC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; SC0001085; FG 02-04-ER-46157; AC02-98CH10886

OSTI ID:: 1182523

Alternate ID(s):: OSTI ID: 1180547

Report Number(s):: BNL-107531-2015-JA; PRBMDO; R&D Project: 16083/16083; KC0403020

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Vol. 91, Issue 12; ISSN 1098-0121

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 51 works

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