Catalysts for the production of hydrocarbons from carbon monoxide and water
Patent
·
OSTI ID:1176566
A method of converting low H2/CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200° to 350°C. in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinium, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: and for olefinic hydrocarbons: where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.
- Research Organization:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC02-76CH00016
- Assignee:
- The United States of America as represented by the United States Department of Energy (Washington, DC)
- Patent Number(s):
- H000243
- Application Number:
- 06/797509
- OSTI ID:
- 1176566
- Resource Relation:
- Patent File Date: 1985 Nov 06
- Country of Publication:
- United States
- Language:
- English
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