Nanocomposite of graphene and metal oxide materials

Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon; Wang, Donghai; Yang, Zhenguo

Title: Nanocomposite of graphene and metal oxide materials

Patent · Tue Sep 04 00:00:00 EDT 2012

OSTI ID:1078299

Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon; Wang, Donghai; Yang, Zhenguo

Nanocomposite materials comprising a metal oxide bonded to at least one graphene material. The nanocomposite materials exhibit a specific capacity of at least twice that of the metal oxide material without the graphene at a charge/discharge rate greater than about 10C.

View Patent

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC06-76RL01830

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Number(s):: 8,257,867

Application Number:: 12/460,993

OSTI ID:: 1078299

Country of Publication:: United States

Language:: English

References (82)

Oriented Nanostructures for Energy Conversion and Storage Liu, Jun; Cao, Guozhong; Yang, Zhenguo ChemSusChem, Vol. 1, Issue 8-9, p. 676-697 https://doi.org/10.1002/cssc.200800087	journal	September 2008
Templating of Mesoporous Molecular Sieves by Nonionic Polyethylene Oxide Surfactants Bagshaw, S. A.; Prouzet, E.; Pinnavaia, T. J. Science, Vol. 269, Issue 5228 https://doi.org/10.1126/science.269.5228.1242	journal	September 1995
Nanoionics: ion transport and electrochemical storage in confined systems Maier, J. Nature Materials, Vol. 4, Issue 11, p. 805-815 https://doi.org/10.1038/nmat1513	journal	November 2005
Improved electrochemical performance of a LiFePO₄-based composite cathode Prosini, Pier Paolo; Zane, Daniela; Pasquali, Mauro Electrochimica Acta, Vol. 46, Issue 23, p. 3517-3523 https://doi.org/10.1016/S0013-4686(01)00631-4	journal	August 2001
Self-Healing of Surfactant Surface Micelles on Millisecond Time Scales Schniepp, Hannes C.; Saville, Dudley A.; Aksay, Ilhan A. Journal of the American Chemical Society, Vol. 128, Issue 38 https://doi.org/10.1021/ja0624826	journal	September 2006
Magnetically directed self-assembly of submicron spheres with a Fe3O4 nanoparticle shell Bizdoaca, E. L.; Spasova, M.; Farle, M. Journal of Magnetism and Magnetic Materials, Vol. 240, Issue 1-3 https://doi.org/10.1016/S0304-8853(01)00724-7	journal	February 2002
Supramolecular Self-Assembly of Lipid Derivatives on Carbon Nanotubes Richard, C. Science, Vol. 300, Issue 5620 https://doi.org/10.1126/science.1080848	journal	May 2003
Sonochemical Synthesis of Nanostructured Molybdenum Sulfide Mdleleni, Millan M.; Hyeon, Taeghwan; Suslick, Kenneth S. Journal of the American Chemical Society, Vol. 120, Issue 24 https://doi.org/10.1021/ja9800333	journal	June 1998
Structural, electronic and magnetic properties of manganese doping in the upper layer of bilayer graphene Mao, Yuliang; Zhong, Jianxin Nanotechnology, Vol. 19, Issue 20 https://doi.org/10.1088/0957-4484/19/20/205708	journal	April 2008
Organization of Organic Molecules with Inorganic Molecular Species into Nanocomposite Biphase Arrays Huo, Qisheng; Margolese, David I.; Ciesla, Ulrike Chemistry of Materials, Vol. 6, Issue 8 https://doi.org/10.1021/cm00044a016	journal	August 1994
Electrochemical Lithium Intercalation into a Polyaniline/V[sub 2]O[sub 5] Nanocomposite Leroux, F. Journal of The Electrochemical Society, Vol. 143, Issue 9 https://doi.org/10.1149/1.1837078	journal	January 1996
Improved Electrode Performance of Porous LiFePO₄ Using RuO₂ as an Oxidic Nanoscale Interconnect Hu, Y.-S.; Guo, Y.-G.; Dominko, R. Advanced Materials, Vol. 19, Issue 15, p. 1963-1966 https://doi.org/10.1002/adma.200700697	journal	August 2007
Periodic mesoporous organosilicas with organic groups inside the channel walls Asefa, Tewodros; MacLachlan, Mark J.; Coombs, Neil Nature, Vol. 402, Issue 6764 https://doi.org/10.1038/47229	journal	December 1999
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Electronic Transport Properties of Individual Chemically Reduced Graphene Oxide Sheets Gomez-Navarro, Cristina; Weitz, R. Thomas; Bittner, Alexander M. Nano Letters, Vol. 7, Issue 11, p. 3499-3503 https://doi.org/10.1021/nl072090c	journal	November 2007
Low-Temperature Synthesis of Tunable Mesoporous Crystalline Transition Metal Oxides and Applications as Au Catalyst Supports Wang, Donghai; Ma, Zhen; Dai, Sheng The Journal of Physical Chemistry C, Vol. 112, Issue 35 https://doi.org/10.1021/jp804250f	journal	August 2008
Room temperature synthesis and Li insertion into nanocrystalline rutile TiO₂ Reddy, M. Anji; Kishore, M. Satya; Pralong, V. Electrochemistry Communications, Vol. 8, Issue 8, p. 1299-1303 https://doi.org/10.1016/j.elecom.2006.05.021	journal	August 2006
Electronic Confinement and Coherence in Patterned Epitaxial Graphene Berger, C. Science, Vol. 312, Issue 5777 https://doi.org/10.1126/science.1125925	journal	May 2006
Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites Decher, G. Science, Vol. 277, Issue 5330 https://doi.org/10.1126/science.277.5330.1232	journal	August 1997
Reducing Carbon in LiFePO[sub 4]/C Composite Electrodes to Maximize Specific Energy, Volumetric Energy, and Tap Density Chen, Zhaohui; Dahn, J. R. Journal of The Electrochemical Society, Vol. 149, Issue 9 https://doi.org/10.1149/1.1498255	journal	January 2002
Molecular self-assembly and nanochemistry: a chemical strategy for the synthesis of nanostructures Whitesides, G.; Mathias, J.; Seto, C. Science, Vol. 254, Issue 5036 https://doi.org/10.1126/science.1962191	journal	November 1991
Sonochemical synthesis of amorphous iron Suslick, Kenneth S.; Choe, Seok-Burm; Cichowlas, Andrzej A. Nature, Vol. 353, Issue 6343 https://doi.org/10.1038/353414a0	journal	October 1991
Microemulsion Syntheses of Sn and SnO[sub 2]-Graphite Nanocomposite Anodes for Li-Ion Batteries Wang, Yong; Lee, Jim Yang; Chen, Bing-Hung Journal of The Electrochemical Society, Vol. 151, Issue 4 https://doi.org/10.1149/1.1647571	journal	January 2004
Nano-network electronic conduction in iron and nickel olivine phosphates Herle, P. Subramanya; Ellis, B.; Coombs, N. Nature Materials, Vol. 3, Issue 3 https://doi.org/10.1038/nmat1063	journal	February 2004
Semiconducting superlattices templated by molecular assemblies Braun, Paul V.; Osenar, Paul; Stupp, Samuel I. Nature, Vol. 380, Issue 6572 https://doi.org/10.1038/380325a0	journal	March 1996
Graphite Oxide-Intercalated Anionic Clay and Its Decomposition to Graphene−Inorganic Material Nanocomposites Nethravathi, C.; Rajamathi, Jacqueline T.; Ravishankar, N. Langmuir, Vol. 24, Issue 15 https://doi.org/10.1021/la8000027	journal	August 2008
Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores Zhao, Dongyuan; Feng, Jianglin; Huo, Qisheng Science, Vol. 279, Issue 5350, p. 548-552 https://doi.org/10.1126/science.279.5350.548	journal	January 1998
Pseudocapacitive Lithium Storage in TiO₂(B) Zukalová, Markéta; Kalbáč, Martin; Kavan, Ladislav Chemistry of Materials, Vol. 17, Issue 5, p. 1248-1255 https://doi.org/10.1021/cm048249t	journal	March 2005
Lithium Insertion into TiO[sub 2] Nanotube Prepared by the Hydrothermal Process Zhou, Ying-ke; Cao, Lin; Zhang, Fei-bao Journal of The Electrochemical Society, Vol. 150, Issue 9 https://doi.org/10.1149/1.1597883	journal	January 2003
H–T phase diagram and the nature of vortex-glass phase in a quasi-two-dimensional superconductor: Sn-metal layer sandwiched between graphene sheets Suzuki, Masatsugu; Suzuki, Itsuko S.; Walter, Jürgen Physica C: Superconductivity, Vol. 402, Issue 3 https://doi.org/10.1016/j.physc.2003.10.001	journal	February 2004
Atomic Layer Deposition of Metal Oxides on Pristine and Functionalized Graphene Wang, Xinran; Tabakman, Scott M.; Dai, Hongjie Journal of the American Chemical Society, Vol. 130, Issue 26 https://doi.org/10.1021/ja8023059	journal	July 2008
Mesoporous Platinum Films from Lyotropic Liquid Crystalline Phases Attard, G. S. Science, Vol. 278, Issue 5339 https://doi.org/10.1126/science.278.5339.838	journal	October 1997
Assembly of chemically modified graphene: methods and applications Xu, Yuxi; Shi, Gaoquan J. Mater. Chem., Vol. 21, Issue 10 https://doi.org/10.1039/C0JM02319A	journal	January 2011
Graphene-Based Ultracapacitors Stoller, Meryl D.; Park, Sungjin; Zhu, Yanwu Nano Letters, Vol. 8, Issue 10 https://doi.org/10.1021/nl802558y	journal	October 2008
Characteristics of graphene-layer encapsulated nanoparticles fabricated using laser ablation method Ou, Q.; Tanaka, T.; Mesko, M. Diamond and Related Materials, Vol. 17, Issue 4-5, p. 664-668 https://doi.org/10.1016/j.diamond.2007.10.023	journal	April 2008
SnO₂-carbon composites for lithium-ion battery anodes Read, J.; Foster, D.; Wolfenstine, J. Journal of Power Sources, Vol. 96, Issue 2, p. 277-281 https://doi.org/10.1016/S0378-7753(00)00569-3	journal	June 2001
TiO₂(B) Nanowires as an Improved Anode Material for Lithium-Ion Batteries Containing LiFePO₄ or LiNi_0.5Mn_1.5O₄ Cathodes and a Polymer Electrolyte Armstrong, G.; Armstrong, A. R.; Bruce, P. G. Advanced Materials, Vol. 18, Issue 19, p. 2597-2600 https://doi.org/10.1002/adma.200601232	journal	October 2006
Low-Temperature Solution Processing of Graphene−Carbon Nanotube Hybrid Materials for High-Performance Transparent Conductors Tung, Vincent C.; Chen, Li-Min; Allen, Matthew J. Nano Letters, Vol. 9, Issue 5 https://doi.org/10.1021/nl9001525	journal	May 2009
Preparation and characterization of graphene oxide paper Dikin, Dmitriy A.; Stankovich, Sasha; Zimney, Eric J. Nature, Vol. 448, Issue 7152, p. 457-460 https://doi.org/10.1038/nature06016	journal	July 2007
Mechanically Strong, Electrically Conductive, and Biocompatible Graphene Paper Chen, Haiqun; Müller, Marc B.; Gilmore, Kerry J. Advanced Materials, Vol. 20, Issue 18, p. 3557-3561 https://doi.org/10.1002/adma.200800757	journal	July 2008
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism Kresge, C. T.; Leonowicz, M. E.; Roth, W. J. Nature, Vol. 359, Issue 6397, p. 710-712 https://doi.org/10.1038/359710a0	journal	October 1992
Surface-Mediated Growth of Transparent, Oriented, and Well-Defined Nanocrystalline Anatase Titania Films Wang, Donghai; Liu, Jun; Huo, Qisheng Journal of the American Chemical Society, Vol. 128, Issue 42 https://doi.org/10.1021/ja0655993	journal	October 2006
Functionalized Single Graphene Sheets Derived from Splitting Graphite Oxide Schniepp, Hannes C.; Li, Je-Luen; McAllister, Michael J. The Journal of Physical Chemistry B, Vol. 110, Issue 17 https://doi.org/10.1021/jp060936f	journal	May 2006
Self-Assembled TiO ₂ –Graphene Hybrid Nanostructures for Enhanced Li-Ion Insertion Wang, Donghai; Choi, Daiwon; Li, Juan ACS Nano, Vol. 3, Issue 4, p. 907-914 https://doi.org/10.1021/nn900150y	journal	March 2009
Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks Yang, Peidong; Zhao, Dongyuan; Margolese, David I. Nature, Vol. 396, Issue 6707 https://doi.org/10.1038/24132	journal	November 1998
Tin Nanoparticle Loaded Graphite Anodes for Li-Ion Battery Applications Wang, Yong; Lee, Jim Y.; Deivaraj, Theivanayagam C. Journal of The Electrochemical Society, Vol. 151, Issue 11 https://doi.org/10.1149/1.1799491	journal	January 2004
Solution Properties of Graphite and Graphene Niyogi, Sandip; Bekyarova, Elena; Itkis, Mikhail E. Journal of the American Chemical Society, Vol. 128, Issue 24 https://doi.org/10.1021/ja060680r	journal	June 2006
Functionalized graphene sheets for polymer nanocomposites Ramanathan, T.; Abdala, A. A.; Stankovich, S. Nature Nanotechnology, Vol. 3, Issue 6, p. 327-331 https://doi.org/10.1038/nnano.2008.96	journal	May 2008
Carbon-coated mesoporous silica with hydrophobicity and electrical conductivity Nishihara, Hirotomo; Fukura, Yu; Inde, Kouta Carbon, Vol. 46, Issue 1, p. 48-53 https://doi.org/10.1016/j.carbon.2007.10.024	journal	January 2008
Enhanced Cyclic Performance and Lithium Storage Capacity of SnO ₂ /Graphene Nanoporous Electrodes with Three-Dimensionally Delaminated Flexible Structure Paek, Seung-Min; Yoo, EunJoo; Honma, Itaru Nano Letters, Vol. 9, Issue 1 https://doi.org/10.1021/nl802484w	journal	January 2009
RuO₂-wired high-rate nanoparticulate TiO₂ (anatase): Suppression of particle growth using silica Erjavec, B.; Dominko, R.; Umek, P. Electrochemistry Communications, Vol. 10, Issue 6, p. 926-929 https://doi.org/10.1016/j.elecom.2008.04.006	journal	June 2008
Assembly and Properties of Nanoparticles Ribeiro, Caue; Leite, Edson R. Nanostructured Materials for Electrochemical Energy Production and Storage https://doi.org/10.1007/978-0-387-49323-7_2	book	January 2009
Template-Free Synthesis of SnO₂ Hollow Nanostructures with High Lithium Storage Capacity Lou, X. W.; Wang, Y.; Yuan, C. Advanced Materials, Vol. 18, Issue 17, p. 2325-2329 https://doi.org/10.1002/adma.200600733	journal	September 2006
Nanocrystalline Rutile TiO[sub 2] Electrode for High-Capacity and High-Rate Lithium Storage Jiang, Chunhai; Honma, Itaru; Kudo, Tetsuichi Electrochemical and Solid-State Letters, Vol. 10, Issue 5 https://doi.org/10.1149/1.2712041	journal	January 2007
Self-Assembly of a Nonionic Surfactant at the Graphite/Ionic Liquid Interface Atkin, Rob; Warr, Gregory G. Journal of the American Chemical Society, Vol. 127, Issue 34 https://doi.org/10.1021/ja053904z	journal	August 2005
Structural evolution during the reaction of Li with nano-sized rutile type TiO₂ at room temperature Baudrin, E.; Cassaignon, S.; Koelsch, M. Electrochemistry Communications, Vol. 9, Issue 2, p. 337-342 https://doi.org/10.1016/j.elecom.2006.09.022	journal	February 2007
Purification and size-selection of carbon nanotubes Bonard, Jean-Marc; Stora, Thierry; Salvetat, Jean-Paul Advanced Materials, Vol. 9, Issue 10, p. 827-831 https://doi.org/10.1002/adma.19970091014	journal	January 1997
Nanocrystalline TiO[sub 2] (Anatase) Electrodes: Surface Morphology, Adsorption, and Electrochemical Properties Kavan, L. Journal of The Electrochemical Society, Vol. 143, Issue 2 https://doi.org/10.1149/1.1836455	journal	January 1996
Nanostructured materials for advanced energy conversion and storage devices Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno Nature Materials, Vol. 4, Issue 5, p. 366-377 https://doi.org/10.1038/nmat1368	journal	May 2005
Self-organizing high-density single-walled carbon nanotube arrays from surfactant suspensions Huang, Limin; Cui, Xiaodong; Dukovic, Gordana Nanotechnology, Vol. 15, Issue 11, p. 1450-1454 https://doi.org/10.1088/0957-4484/15/11/012	journal	August 2004
Biomimetic Pathways for Assembling Inorganic Thin Films Aksay, I. A.; Trau, M.; Manne, S. Science, Vol. 273, Issue 5277 https://doi.org/10.1126/science.273.5277.892	journal	August 1996
High Lithium Electroactivity of Nanometer-Sized Rutile TiO₂ Hu, Y.-S.; Kienle, L.; Guo, Y.-G. Advanced Materials, Vol. 18, Issue 11, p. 1421-1426 https://doi.org/10.1002/adma.200502723	journal	June 2006
Flexible Graphene Films via the Filtration of Water-Soluble Noncovalent Functionalized Graphene Sheets Xu, Yuxi; Bai, Hua; Lu, Gewu Journal of the American Chemical Society, Vol. 130, Issue 18 https://doi.org/10.1021/ja800745y	journal	May 2008
Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries Yoo, EunJoo; Kim, Jedeok; Hosono, Eiji Nano Letters, Vol. 8, Issue 8, p. 2277-2282 https://doi.org/10.1021/nl800957b	journal	August 2008
Crystal Phase Control for Titanium Dioxide Films by Direct Deposition in Aqueous Solutions Yamabi, Satoshi; Imai, Hiroaki Chemistry of Materials, Vol. 14, Issue 2 https://doi.org/10.1021/cm010559d	journal	February 2002
Synthesis of Water Soluble Graphene Si, Yongchao; Samulski, Edward T. Nano Letters, Vol. 8, Issue 6 https://doi.org/10.1021/nl080604h	journal	June 2008
Graphene-based composite materials Stankovich, Sasha; Dikin, Dmitriy A.; Dommett, Geoffrey H. B. Nature, Vol. 442, Issue 7100, p. 282-286 https://doi.org/10.1038/nature04969	journal	July 2006
TiO ₂ -Graphene Nanocomposites. UV-Assisted Photocatalytic Reduction of Graphene Oxide Williams, Graeme; Seger, Brian; Kamat, Prashant V. ACS Nano, Vol. 2, Issue 7 https://doi.org/10.1021/nn800251f	journal	July 2008
Specific surface area of carbon nanotubes and bundles of carbon nanotubes Peigney, A.; Laurent, Ch.; Flahaut, E. Carbon, Vol. 39, Issue 4, p. 507-514 https://doi.org/10.1016/S0008-6223(00)00155-X	journal	April 2001
Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate) Stankovich, Sasha; Piner, Richard D.; Chen, Xinqi J. Mater. Chem., Vol. 16, Issue 2 https://doi.org/10.1039/B512799H	journal	January 2006
Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite McAllister, Michael J.; Li, Je-Luen; Adamson, Douglas H. Chemistry of Materials, Vol. 19, Issue 18, p. 4396-4404 https://doi.org/10.1021/cm0630800	journal	September 2007
Electric Field Effect in Atomically Thin Carbon Films Novoselov, K. S. Science, Vol. 306, Issue 5696, p. 666-669 https://doi.org/10.1126/science.1102896	journal	October 2004
Citrate-Derived Carbon Nanocoatings for Poorly Conducting Cathode Moskon, J.; Dominko, R.; Gaberscek, M. Journal of The Electrochemical Society, Vol. 153, Issue 10 https://doi.org/10.1149/1.2221864	journal	January 2006
A Mesoporous Nanocomposite of TiO₂ and Carbon Nanotubes as a High-Rate Li-Intercalation Electrode Material Moriguchi, I.; Hidaka, R.; Yamada, H. Advanced Materials, Vol. 18, Issue 1, p. 69-73 https://doi.org/10.1002/adma.200501366	journal	January 2006
Hierarchical battery electrodes based on inverted opal structures Sakamoto, Jeffrey S.; Dunn, Bruce Journal of Materials Chemistry, Vol. 12, Issue 10 https://doi.org/10.1039/b205634h	journal	August 2002
Synthesis and Li-Ion Insertion Properties of Highly Crystalline Mesoporous Rutile TiO ₂ Wang, Donghai; Choi, Daiwon; Yang, Zhenguo Chemistry of Materials, Vol. 20, Issue 10 https://doi.org/10.1021/cm8002589	journal	May 2008
Impact of the Carbon Coating Thickness on the Electrochemical Performance of LiFePO[sub 4]/C Composites Dominko, R.; Bele, M.; Gaberscek, M. Journal of The Electrochemical Society, Vol. 152, Issue 3 https://doi.org/10.1149/1.1860492	journal	January 2005
Superior Electrode Performance of Nanostructured Mesoporous TiO₂ (Anatase) through Efficient Hierarchical Mixed Conducting Networks Guo, Y.-G.; Hu, Y.-S.; Sigle, W. Advanced Materials, Vol. 19, Issue 16, p. 2087-2091 https://doi.org/10.1002/adma.200602828	journal	August 2007
Optimized Lithium Iron Phosphate for High-Rate Electrochemical Applications Franger, S.; Bourbon, C.; Le Cras, F. Journal of The Electrochemical Society, Vol. 151, Issue 7 https://doi.org/10.1149/1.1758721	journal	January 2004
TiO₂-B Nanowires Armstrong, A. Robert; Armstrong, Graham; Canales, Jesús Angewandte Chemie International Edition, Vol. 43, Issue 17, p. 2286-2288 https://doi.org/10.1002/anie.200353571	journal	April 2004
Molecular Dynamics Simulations of Surfactant Self-Organization at a Solid−Liquid Interface Srinivas, Goundla; Nielsen, Steven O.; Moore, Preston B. Journal of the American Chemical Society, Vol. 128, Issue 3 https://doi.org/10.1021/ja054846k	journal	January 2006
Processable aqueous dispersions of graphene nanosheets Li, Dan; Müller, Marc B.; Gilje, Scott Nature Nanotechnology, Vol. 3, Issue 2 https://doi.org/10.1038/nnano.2007.451	journal	January 2008

Similar Records

Nanocomposite of graphene and metal oxide materials

Patent · Tue Oct 15 00:00:00 EDT 2013 · OSTI ID:1078299

Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon; +2 more

Nanocomposite of graphene and metal oxide materials

Patent · Tue Jun 30 00:00:00 EDT 2015 · OSTI ID:1078299

Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon; +2 more

Lithium ion batteries with titania/graphene anodes

Patent · Tue May 28 00:00:00 EDT 2013 · OSTI ID:1078299

Liu, Jun; Choi, Daiwon; Yang, Zhenguo; +7 more

Related Subjects

36 MATERIALS SCIENCE

Title: Nanocomposite of graphene and metal oxide materials

Citation Formats

References (82)

Similar Records

Related Subjects