Dual Layer Monolith ATR of Pyrolysis Oil for Distributed Synthesis Gas Production
- Stevens Institute of Technology, Castle Point Hoboken NJ 07030
We have successfully demonstrated a novel reactor technology, based on BASF dual layer monolith catalyst, for miniaturizing the autothermal reforming of pyrolysis oil to syngas, the second and most critical of the three steps for thermochemically converting biomass waste to liquid transportation fuel. The technology was applied to aged as well as fresh samples of pyrolysis oil derived from five different biomass feedstocks, namely switch-grass, sawdust, hardwood/softwood, golden rod and maple. Optimization of process conditions in conjunction with innovative reactor system design enabled the minimization of carbon deposit and control of the H2/CO ratio of the product gas. A comprehensive techno-economic analysis of the integrated process using in part, experimental data from the project, indicates (1) net energy recovery of 49% accounting for all losses and external energy input, (2) weight of diesel oil produced as a percent of the biomass to be ~14%, and (3) for a demonstration size biomass to Fischer-Tropsch liquid plant of ~ 2000 daily barrels of diesel, the price of the diesel produced is ~$3.30 per gallon, ex. tax. However, the extension of catalyst life is critical to the realization of the projected economics. Catalyst deactivation was observed and the modes of deactivation, both reversible and irreversible were identified. An effective catalyst regeneration strategy was successfully demonstrated for reversible catalyst deactivation while a catalyst preservation strategy was proposed for preventing irreversible catalyst deactivation. Future work should therefore be focused on extending the catalyst life, and a successful demonstration of an extended (> 500 on-stream hours) catalyst life would affirm the commercial viability of the process.
- Research Organization:
- Stevens Institute of Technology, Castle Point Hoboken NJ 07030
- Sponsoring Organization:
- USDOE; USDOE EE Office of Biomass (EE-2E)
- Contributing Organization:
- BASF Catalysts LLC
- DOE Contract Number:
- FG36-08GO18162
- OSTI ID:
- 1076999
- Report Number(s):
- DOE/GO/18162-1
- Country of Publication:
- United States
- Language:
- English
Similar Records
Feedstock and Catalyst Impact on Bio-Oil Production and FCC Co-Processing to Fuels
The role of catalytic iron in enhancing volumetric sugar productivity during autothermal pyrolysis of woody biomass