Special features in the electroreduction of oxidic molybdenum(VI) forms in tungstate melt

Journal Article · Fri Jan 01 00:00:00 EST 1988 · Sov. Electrochem. (Engl. Transl.); (United States)

OSTI ID:6479017

Shapoval, V I; Baraboshkin, A N; Kushkhov, K B; Malyshev, V V

The electrochemical behavior of oxidic molybdenum in tungstate melt was studied under equilibrium and nonequilibrium conditions. Chronovoltammetry and transient polarization was used. The current-voltage curves were recorded with a pulse potentiostat and the experiments were performed in a quartz reactor with platinum and molybdenum electrodes and a platinum crucible served as the melt container and anode. The end product of the oxidic molybdenum forms were shown to depend on the acid-base properties of the melt which allows for choosing the properties and controlling the electrode process.

• Research Organization: Institute of General and Inorganic Chemistry, Kiev (USSR)
• OSTI ID: 6479017
• Journal Information: Sov. Electrochem. (Engl. Transl.); (United States), Vol. 23:7; Other Information: Translated from Elektrokhimiya; 23: No. 7, 942-946(Jul 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
MOLYBDENUM OXIDES
REDUCTION
SODIUM TUNGSTATES
REDOX POTENTIAL
CHEMICAL REACTION KINETICS
DIFFUSION
ELECTROCHEMISTRY
ELECTRODES
ELECTROLYSIS
EQUILIBRIUM
MATHEMATICAL MODELS
MOLYBDATES
MOLYBDENUM
OXYGEN COMPOUNDS
PH VALUE
PROCESS CONTROL
PRODUCTION
VALENCE
ALKALI METAL COMPOUNDS
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMISTRY
CONTROL
ELEMENTS
KINETICS
LYSIS
METALS
MOLYBDENUM COMPOUNDS
OXIDES
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
SODIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
TUNGSTATES
400400* - Electrochemistry