Oxidation of ultrathin GaSe

Brumbach, Michael T.; McDonald, Anthony E.; Howell, Stephen W.; Ohta, Taisuke; Kowalski, Brian M.; Pask, Jesse A.; Kalugin, Nikolai G.; Spataru, Catalin D.

doi:10.1063/1.4934592

Title: Oxidation of ultrathin GaSe

Journal Article · Mon Oct 26 00:00:00 EDT 2015 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.4934592· OSTI ID:22485972

Brumbach, Michael T.; McDonald, Anthony E.; Howell, Stephen W.; Ohta, Taisuke ^[1]; Kowalski, Brian M.; Pask, Jesse A.; Kalugin, Nikolai G. ^[2]; Spataru, Catalin D. ^[3]

Sandia National Laboratories, Albuquerque, New Mexico 87123 (United States)
Department of Materials and Metallurgical Engineering, New Mexico Tech., Socorro, New Mexico 87801 (United States)
Sandia National Laboratories, Livermore, California 94551 (United States)

Oxidation of exfoliated gallium selenide (GaSe) is investigated through Raman, photoluminescence, Auger, and X-ray photoelectron spectroscopies. Photoluminescence and Raman intensity reductions associated with spectral features of GaSe are shown to coincide with the emergence of signatures emanating from the by-products of the oxidation reaction, namely, Ga{sub 2}Se{sub 3} and amorphous Se. Photoinduced oxidation is initiated over a portion of a flake highlighting the potential for laser based patterning of two-dimensional heterostructures via selective oxidation.

Cite

Export

Save

OSTI ID:: 22485972

Journal Information:: Applied Physics Letters, Vol. 107, Issue 17; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951

Country of Publication:: United States

Language:: English

References (35)

Rapid Characterization of Ultrathin Layers of Chalcogenides on SiO2/Si Substrates Late, Dattatray J.; Liu, Bin; Matte, H. S. S. Ramakrishna Advanced Functional Materials, Vol. 22, Issue 9 https://doi.org/10.1002/adfm.201102913	journal	February 2012
GaS and GaSe Ultrathin Layer Transistors Late, Dattatray J.; Liu, Bin; Luo, Jiajun Advanced Materials, Vol. 24, Issue 26 https://doi.org/10.1002/adma.201201361	journal	June 2012
Epitaxial single-crystal of GaSe epilayers grown on a c-sapphire substrate by molecular beam epitaxy: Epitaxial single-crystal of GaSe epilayers grown on c-sapphire Wu, Chia-Hsin; Yang, Chu-Shou; Wang, Yen-Chi physica status solidi (a), Vol. 212, Issue 10 https://doi.org/10.1002/pssa.201532367	journal	June 2015
Critical-point analysis of the two-phonon Raman spectrum of silicon Uchinokura, K.; Sekine, T.; Matsuura, E. Journal of Physics and Chemistry of Solids, Vol. 35, Issue 2 https://doi.org/10.1016/0022-3697(74)90031-6	journal	January 1974
Identification of the fundamental vibrational modes of trigonal, α - monoclinic and amorphous selenium Lucovsky, G.; Mooradian, A.; Taylor, W. Solid State Communications, Vol. 5, Issue 2 https://doi.org/10.1016/0038-1098(67)90006-3	journal	February 1967
Raman Scattering of amorphous selenium films Carroll, P. J.; Lannin, J. S. Solid State Communications, Vol. 40, Issue 1 https://doi.org/10.1016/0038-1098(81)90716-x	journal	October 1981
Investigation of Se capping of epitaxial Ga 2 Se 3 layers Märkl, A.; von der Emde, M.; Nowak, C. Surface Science, Vol. 331-333 https://doi.org/10.1016/0039-6028(95)00356-8	journal	July 1995
Thermodynamic study of AIIIBVI compounds oxidation Balitskii, O. A.; Savchyn, V. P. Materials Science in Semiconductor Processing, Vol. 7, Issue 1-2 https://doi.org/10.1016/j.mssp.2004.03.002	journal	February 2004
Thermal oxidation of amorphous GaSe thin films Siciliano, T.; Tepore, M.; Genga, A. Vacuum, Vol. 92 https://doi.org/10.1016/j.vacuum.2012.12.001	journal	June 2013
Photoelectric properties of heterostructures based on thermo-oxidated GaSe and InSe crystals Savchyn, V. P.; Kytsai, V. B. Thin Solid Films, Vol. 361-362 https://doi.org/10.1016/s0040-6090(99)00796-8	journal	February 2000
Characteristics of phase formation during gase oxidation Berchenko, N. N.; Balitskii, O. A.; Lutsiv, R. V. Materials Chemistry and Physics, Vol. 51, Issue 2 https://doi.org/10.1016/s0254-0584(97)80280-5	journal	November 1997
Arrayed van der Waals Vertical Heterostructures Based on 2D GaSe Grown by Molecular Beam Epitaxy Yuan, Xiang; Tang, Lei; Liu, Shanshan Nano Letters, Vol. 15, Issue 5 https://doi.org/10.1021/acs.nanolett.5b01058	journal	April 2015
Synthesis and Photoresponse of Large GaSe Atomic Layers Lei, Sidong; Ge, Liehui; Liu, Zheng Nano Letters, Vol. 13, Issue 6 https://doi.org/10.1021/nl4010089	journal	May 2013
Two-Dimensional Metal–Chalcogenide Films in Tunable Optical Microcavities Schwarz, S.; Dufferwiel, S.; Walker, P. M. Nano Letters, Vol. 14, Issue 12 https://doi.org/10.1021/nl503312x	journal	November 2014
Self-Limiting Layer-by-Layer Oxidation of Atomically Thin WSe ₂ Yamamoto, Mahito; Dutta, Sudipta; Aikawa, Shinya Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/nl5049753	journal	February 2015
Synthesis of Few-Layer GaSe Nanosheets for High Performance Photodetectors Hu, PingAn; Wen, Zhenzhong; Wang, Lifeng ACS Nano, Vol. 6, Issue 7 https://doi.org/10.1021/nn300889c	journal	June 2012
Stability and Exfoliation of Germanane: A Germanium Graphane Analogue Bianco, Elisabeth; Butler, Sheneve; Jiang, Shishi ACS Nano, Vol. 7, Issue 5 https://doi.org/10.1021/nn4009406	journal	March 2013
Epitaxy and Photoresponse of Two-Dimensional GaSe Crystals on Flexible Transparent Mica Sheets Zhou, Yubing; Nie, Yufeng; Liu, Yujing ACS Nano, Vol. 8, Issue 2 https://doi.org/10.1021/nn405529r	journal	January 2014
Photooxidation and quantum confinement effects in exfoliated black phosphorus Favron, Alexandre; Gaufrès, Etienne; Fossard, Frédéric Nature Materials, Vol. 14, Issue 8 https://doi.org/10.1038/nmat4299	journal	May 2015
Photoluminescence frequency up-conversion in GaSe single crystals as studied by confocal microscopy Fan, Y.; Bauer, M.; Kador, L. Journal of Applied Physics, Vol. 91, Issue 3 https://doi.org/10.1063/1.1421215	journal	February 2002
A monochromatic and high-power terahertz source tunable in the ranges of 2.7–38.4 and 58.2–3540 μm for variety of potential applications Shi, Wei; Ding, Yujie J. Applied Physics Letters, Vol. 84, Issue 10 https://doi.org/10.1063/1.1649802	journal	March 2004
On photoinduced volume change in amorphous selenium: Quantum chemical calculation and Raman spectroscopy Lukács, R.; Veres, M.; Shimakawa, K. Journal of Applied Physics, Vol. 107, Issue 7 https://doi.org/10.1063/1.3371813	journal	April 2010
Photoluminescence of two-dimensional GaTe and GaSe films Pozo-Zamudio, O. Del; Schwarz, S.; Sich, M. 2D Materials, Vol. 2, Issue 3 https://doi.org/10.1088/2053-1583/2/3/035010	journal	July 2015
Photoconductivity of Gallium Selenide Crystals Bube, Richard H.; Lind, Edward L. Physical Review, Vol. 115, Issue 5 https://doi.org/10.1103/physrev.115.1159	journal	September 1959
Lattice dynamics of tetrahedrally bonded semiconductors containing ordered vacant sites Finkman, E.; Tauc, J.; Kershaw, R. Physical Review B, Vol. 11, Issue 10 https://doi.org/10.1103/physrevb.11.3785	journal	May 1975
Size-induced effects in gallium selenide electronic structure: The influence of interlayer interactions Rybkovskiy, D. V.; Arutyunyan, N. R.; Orekhov, A. S. Physical Review B, Vol. 84, Issue 8 https://doi.org/10.1103/physrevb.84.085314	journal	August 2011
Selective Raman modes and strong photoluminescence of gallium selenide flakes on sp ² carbon Rodriguez, Raul D.; Müller, Susanne; Sheremet, Evgeniya Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 32, Issue 4 https://doi.org/10.1116/1.4881995	journal	July 2014
Epitaxial Ga2Se3 layers grown on GaAs(100) using a heterovalent exchange reaction Zahn, D. R. T. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 10, Issue 4 https://doi.org/10.1116/1.586321	journal	July 1992
Structure of oxidized and unoxidized end faces of GaSe layered crystals Katerynchuk, V. N.; Kudrynskyi, Z. R.; Kovalyuk, Z. D. Inorganic Materials, Vol. 50, Issue 4 https://doi.org/10.1134/s0020168514040062	journal	March 2014
Effective nonlinear GaSe crystal. Optical properties and applications Allakhverdiev, K. R.; Yetis, M. Ö.; Özbek, S. Laser Physics, Vol. 19, Issue 5 https://doi.org/10.1134/s1054660x09050375	journal	May 2009
Native oxide emerging of the cleavage surface of gallium selenide due to prolonged storage Drapak, S. I.; Gavrylyuk, S. V.; Kovalyuk, Z. D. Semiconductors, Vol. 42, Issue 4 https://doi.org/10.1134/s1063782608040088	journal	April 2008
Raman Scattering in GaSe Hoff, R. M.; Irwin, J. C.; Lieth, R. M. A. Canadian Journal of Physics, Vol. 53, Issue 17 https://doi.org/10.1139/p75-203	journal	September 1975
Raman Study of Epitaxial Ga ₂ Se ₃ Films Grown by Molecular Beam Epitaxy Yamada, Akira; Kojima, Nobuaki; Takahashi, Kiyoshi Japanese Journal of Applied Physics, Vol. 31, Issue Part 2, No. 2B https://doi.org/10.1143/jjap.31.l186	journal	February 1992
Photoinduced Oxidation of Epitaxial Ga ₂ Se ₃ Grown by Molecular Beam Epitaxy Kojima, Nobuaki; Yamada, Akira; Takahashi, Kiyoshi Japanese Journal of Applied Physics, Vol. 32, Issue Part 2, No. 7A https://doi.org/10.1143/jjap.32.l887	journal	July 1993
Introductory remarks: A demographic frame for reintroductions Sarrazin, François Ecoscience, Vol. 14, Issue 4 https://doi.org/10.2980/1195-6860(2007)14[iv:ir]2.0.co;2	journal	December 2007

Cited By (13)

Toward Air Stability of Thin GaSe Devices: Avoiding Environmental and Laser-Induced Degradation by Encapsulation Zhao, Qinghua; Frisenda, Riccardo; Gant, Patricia Advanced Functional Materials, Vol. 28, Issue 47 https://doi.org/10.1002/adfm.201805304	journal	October 2018
Solution‐Processed GaSe Nanoflake‐Based Films for Photoelectrochemical Water Splitting and Photoelectrochemical‐Type Photodetectors Zappia, Marilena Isabella; Bianca, Gabriele; Bellani, Sebastiano Advanced Functional Materials, Vol. 30, Issue 10 https://doi.org/10.1002/adfm.201909572	journal	January 2020
Monolayer group-III monochalcogenides by oxygen functionalization: a promising class of two-dimensional topological insulators Zhou, Si; Liu, Cheng-Cheng; Zhao, Jijun npj Quantum Materials, Vol. 3, Issue 1 https://doi.org/10.1038/s41535-018-0089-0	journal	March 2018
Oxygen-functionalized TlTe buckled honeycomb from first-principles study Lu, Qing; Wen, Yi-Ming; Zeng, Zhao-Yi Physical Chemistry Chemical Physics, Vol. 21, Issue 10 https://doi.org/10.1039/c8cp07246a	journal	January 2019
Prediction of high-temperature Chern insulator with half-metallic edge states in asymmetry-functionalized stanene Zhang, Meng-han; Zhang, Chang-wen; Wang, Pei-ji Nanoscale, Vol. 10, Issue 43 https://doi.org/10.1039/c8nr07503d	journal	January 2018
Shear-force exfoliation of indium and gallium chalcogenides for selective gas sensing applications Marvan, Petr; Mazánek, Vlastimil; Sofer, Zdeněk Nanoscale, Vol. 11, Issue 10 https://doi.org/10.1039/c8nr09294j	journal	January 2019
Crystal quality of two-dimensional gallium telluride and gallium selenide using Raman fingerprint Susoma, Jannatul; Lahtinen, Jouko; Kim, Maria AIP Advances, Vol. 7, Issue 1 https://doi.org/10.1063/1.4973918	journal	January 2017
Strong modulation of optical properties in rippled 2D GaSe via strain engineering Maeso, David; Pakdel, Sahar; Santos, Hernán Nanotechnology, Vol. 30, Issue 24 https://doi.org/10.1088/1361-6528/ab0bc1	journal	March 2019
GaSe oxidation in air: from bulk to monolayers Rahaman, Mahfujur; Rodriguez, Raul D.; Monecke, Manuel Semiconductor Science and Technology, Vol. 32, Issue 10 https://doi.org/10.1088/1361-6641/aa8441	journal	September 2017
Infrared-to-violet tunable optical activity in atomic films of GaSe, InSe, and their heterostructures Terry, Daniel J.; Zólyomi, Viktor; Hamer, Matthew 2D Materials, Vol. 5, Issue 4 https://doi.org/10.1088/2053-1583/aadfc3	journal	September 2018
Role of humidity in oxidation of ultrathin GaSe Kowalski, Brian M.; Manz, Noah; Bethke, Donald Materials Research Express, Vol. 6, Issue 8 https://doi.org/10.1088/2053-1591/ab1dd2	journal	May 2019
Molecular-Beam Epitaxy of Two-Dimensional GaSe Layers on GaAs(001) and GaAs(112) Substrates: Structural and Optical Properties Sorokin, S. V.; Avdienko, P. S.; Sedova, I. V. Semiconductors, Vol. 53, Issue 8 https://doi.org/10.1134/s1063782619080189	journal	August 2019
Solution-processed GaSe nanoflake-based films for photoelectrochemical water splitting and photoelectrochemical-type photodetectors Zappia, Marilena Isabella; Bianca, Gabriele; Bellani, Sebastiano arXiv https://doi.org/10.48550/arxiv.2004.10034	text	January 2020

Similar Records

Oxidation of ultrathin GaSe

Journal Article · Mon Oct 26 00:00:00 EDT 2015 · Applied Physics Letters · OSTI ID:22485972

McDonald, Anthony E.; Ohta, Taisuke; Howell, Stephen W.; +5 more

Role of humidity in oxidation of ultrathin GaSe

Journal Article · Fri May 10 00:00:00 EDT 2019 · Materials Research Express (Online) · OSTI ID:22485972

Kowalski, Brian M.; Manz, Noah; Bethke, Donald; +3 more

Van der Waals epitaxial growth of two-dimensional single-crystalline GaSe domains on graphene

Journal Article · Wed Jul 22 00:00:00 EDT 2015 · ACS Nano · OSTI ID:22485972

Li, Xufan; Basile, Leonardo; Huang, Bing; +12 more

Related Subjects

36 MATERIALS SCIENCE
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
BY-PRODUCTS
GALLIUM SELENIDES
LASERS
OXIDATION
PHOTOLUMINESCENCE
TWO-DIMENSIONAL SYSTEMS
X-RAY PHOTOELECTRON SPECTROSCOPY

Title: Oxidation of ultrathin GaSe

Citation Formats

References (35)

Cited By (13)

Similar Records

Related Subjects