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Title: H irradiation effects on the GaAs-like Raman modes in GaAs{sub 1-x}N{sub x}/GaAs{sub 1-x}N{sub x}:H planar heterostructures

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.4905097· OSTI ID:22399189
; ;  [1]; ; ;  [2];  [3];  [3]
  1. Dipartimento di Fisica, Università degli studi di Pavia, Via Bassi 6, I-27100 Pavia (Italy)
  2. Dipartimento di Fisica, Sapienza Università di Roma, Piazzale A. Moro 2, I-00185 Roma (Italy)
  3. Laboratorio Nazionale TASC-IOM-CNR, Area Science Park, S.S. 14, Km. 163.5, 34149 Trieste (Italy)

The GaAs-like longitudinal optical phonon frequency in two hydrogenated GaAs{sub 1-x}N{sub x}/GaAs{sub 1-x}N{sub x}:H microwire heterostructures—with similar N concentration, but different H dose and implantation conditions—has been investigated by micro-Raman mapping. In the case of GaAs{sub 0.991}N{sub 0.009} wires embedded in barriers where GaAs-like properties are recovered through H irradiation, the phonon frequency in the barriers undergoes a blue shift with respect to the wires. In GaAs{sub 0.992}N{sub 0.008} wires embedded in less hydrogenated barriers, the phonon frequency exhibits an opposite behavior (red shift). Strain, disorder, phonon localization effects induced by H-irradiation on the GaAs-like phonon frequency are discussed and related to different types of N-H complexes formed in the hydrogenated barriers. It is shown that the red (blue) character of the frequency shift is related to the dominant N-2H (N-3H) type of complexes. Moreover, for specific experimental conditions, an all-optical determination of the uniaxial strain field is obtained. This may improve the design of recently presented devices that exploit the correlation between uniaxial stress and the degree of polarization of photoluminescence.

OSTI ID:
22399189
Journal Information:
Journal of Applied Physics, Vol. 116, Issue 24; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0021-8979
Country of Publication:
United States
Language:
English