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Title: Morphological effects on the electrochemical performance of lithium-rich layered oxide cathodes, prepared by electrospinning technique, for lithium-ion battery applications

Li-rich Li{sub 1.2}Ni{sub 0.17}Co{sub 0.17}Mn{sub 0.5}O{sub 2} cathode materials were synthesized by electrospinning technique with different polymers, and their structural, morphological, and electrochemical performances were investigated. It was found that the electrospinning process leads to the formation of a fiber and flower-like morphology, by using different polymers and heat treatment conditions. The nanostructured morphology provided these materials with high initial discharge capacity. The cycling stability was improved with agglomerated nano-particles, as compared with porous materials. - Highlights: • Fiber and flower-like Li-rich cathode was synthesized by simple electrospinning. • Polymer dependent morphology and electrochemical performance was investigated. • Well-organized porous structure facilitates the diffusion of lithium ions. • Technique could be applicable to other cathode materials as well.
Authors:
; ; ;
Publication Date:
OSTI Identifier:
22340371
Resource Type:
Journal Article
Resource Relation:
Journal Name: Materials Characterization; Journal Volume: 92; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; CATHODES; DIFFUSION; HEAT TREATMENTS; LITHIUM; LITHIUM ION BATTERIES; LITHIUM IONS; NANOSTRUCTURES; OXIDES; PARTICLES; POLYMERS; POROUS MATERIALS; STABILITY