Synchrotron X-Ray Characterization of Alkali Elements at Grain Boundaries in Cu(In, Ga)Se2 Solar Cells
It is well known that the addition of alkali elements such as Na and K during and after growth of Cu(In, Ga)Se2 (CIGS) has beneficial effects on the electronic properties of bulk material, improving device performance significantly. While the device level effects have been measured and reported, a direct observations of the localization of Na including its chemical nature are missing, and the impact of Na on elemental and phase segregation during CIGS growth is not fully understood. We investigate these aspects to shine light on the role of Na in CIGS solar cells with the ultimate goal of increasing their conversion efficiency. Utilizing a suite of synchrotron based x-ray characterization techniques, we discuss the challenges and advantages of these techniques for investigating segregation of main constituents of CIGS, Na distribution, chemical bonding of Na, and collection efficiency in CIGS as well as their correlations.
- Research Organization:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Organization:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- DOE Contract Number:
- AC36-08GO28308
- OSTI ID:
- 1344220
- Report Number(s):
- NREL/CP-5K00-67991
- Resource Relation:
- Conference: Presented at the 2016 IEEE 43rd Photovoltaic Specialists Conference (PVSC), 5-10 June 2016, Portland, Oregon
- Country of Publication:
- United States
- Language:
- English
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