Electron Beam Curing of Composite Positive Electrode for Li-Ion Battery

Du, Zhijia; Janke, C. J.; Li, Jianlin; Daniel, C.; Wood, D. L.

doi:10.1149/2.1171613jes

Title: Electron Beam Curing of Composite Positive Electrode for Li-Ion Battery

Journal Article · Wed Oct 12 00:00:00 EDT 2016 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.1171613jes· OSTI ID:1329741

Du, Zhijia ^[1]; Janke, C. J. ^[2]; Li, Jianlin ^[1]; Daniel, C. ^[1]; Wood, D. L. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy and Transportation Science Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division

We have successfully used electron beam cured acrylated polyurethanes as novel binders for positive electrodes for Li-ion batteries. Furthermore, the cross-linked polymer after electron beam curing coheres active materials and carbon black together onto Al foil. Electrochemical tests demonstrate the stability of the polymer at a potential window of 2.0 V–4.6 V. The electrode is found to have similar voltage profiles and charge-transfer resistance compared to the conventional electrode using polyvinylidene fluoride as the binder. Finally, when the electrode is tested in full Li-ion cells, they exhibit excellent cycling performance, indicating promising use for this new type of binder in commercial Li-ion batteries in the future.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1329741

Journal Information:: Journal of the Electrochemical Society, Vol. 163, Issue 13; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 17 works

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Toward Low-Cost, High-Energy Density, and High-Power Density Lithium-Ion Batteries Li, Jianlin; Du, Zhijia; Ruther, Rose E. JOM, Vol. 69, Issue 9 https://doi.org/10.1007/s11837-017-2404-9	journal	June 2017

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