Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2

Xia, Ming; Li, Bo; Yin, Kuibo; Capellini, Giovanni; Niu, Gang; Gong, Yongji; Zhou, Wu; Ajayan, Pulickel M.; Xie, Ya -Hong

doi:10.1021/acsnano.5b05474

Title: Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS₂

Journal Article · Wed Nov 04 00:00:00 EST 2015 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.5b05474· OSTI ID:1252727

Xia, Ming ^[1]; Li, Bo ^[2]; Yin, Kuibo ^[3]; Capellini, Giovanni ^[4]; Niu, Gang ^[4]; Gong, Yongji ^[2]; Zhou, Wu ^[5]; Ajayan, Pulickel M. ^[2]; Xie, Ya -Hong ^[1]

Univ. of California, Los Angeles, CA (United States)
Rice Univ., Houston, TX (United States)
Southeast Univ., Nanjing (China). School of Energy and Environment; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Innovations for High Performance (IHP), Frankfurt (Germany)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

We report prominent resonance Raman and photoluminescence spectroscopic differences between AA' and AB stacked bilayer molybdenum disulfide (MoS2) grown by chemical vapor deposition. Bilayer MoS2 islands consisting of the two stacking orders were obtained under identical growth conditions. Resonance Moreover, Raman and photoluminescence spectra of AA' and AB stacked bilayer MoS2 were obtained on Au nanopyramid surfaces under strong plasmon resonance. Both resonance Raman and photoluminescence spectra show distinct features indicating clear differences in interlayer interaction between these two phases. Finally, the implication of these findings on device applications based on spin and valley degrees of freedom will be discussed.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Univ. of California, Los Angeles, CA (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: W-7405-ENG-26; AC05-00OR22725

OSTI ID:: 1252727

Alternate ID(s):: OSTI ID: 1286946

Journal Information:: ACS Nano, Vol. 9, Issue 12; ISSN 1936-0851

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 86 works

Citation information provided by
Web of Science

References (41)

Atomically Thin ${MoS}_{2}$ A New Direct-Gap Semiconductor Mak, Kin Fai; Lee, Changgu; Hone, James Physical Review Letters, Vol. 105, Issue 13, Article No.136805 https://doi.org/10.1103/PhysRevLett.105.136805	journal	September 2010
Photoluminescence from Chemically Exfoliated MoS₂ Eda, Goki; Yamaguchi, Hisato; Voiry, Damien Nano Letters, Vol. 11, Issue 12, p. 5111-5116 https://doi.org/10.1021/nl201874w	journal	December 2011
Emerging Photoluminescence in Monolayer MoS₂ Splendiani, Andrea; Sun, Liang; Zhang, Yuanbo Nano Letters, Vol. 10, Issue 4, p. 1271-1275 https://doi.org/10.1021/nl903868w	journal	April 2010
Coupled Spin and Valley Physics in Monolayers of ${MoS}_{2}$ and Other Group-VI Dichalcogenides Xiao, Di; Liu, Gui-Bin; Feng, Wanxiang Physical Review Letters, Vol. 108, Issue 19 https://doi.org/10.1103/PhysRevLett.108.196802	journal	May 2012
Giant spin-orbit-induced spin splitting in two-dimensional transition-metal dichalcogenide semiconductors Zhu, Z. Y.; Cheng, Y. C.; Schwingenschlögl, U. Physical Review B, Vol. 84, Issue 15 https://doi.org/10.1103/PhysRevB.84.153402	journal	October 2011
Valley-dependent spin polarization in bulk MoS2 with broken inversion symmetry Suzuki, R.; Sakano, M.; Zhang, Y. J. Nature Nanotechnology, Vol. 9, Issue 8 https://doi.org/10.1038/nnano.2014.148	journal	July 2014
Valley polarization in MoS2 monolayers by optical pumping Zeng, Hualing; Dai, Junfeng; Yao, Wang Nature Nanotechnology, Vol. 7, Issue 8 https://doi.org/10.1038/nnano.2012.95	journal	June 2012
Control of valley polarization in monolayer MoS2 by optical helicity Mak, Kin Fai; He, Keliang; Shan, Jie Nature Nanotechnology, Vol. 7, Issue 8 https://doi.org/10.1038/nnano.2012.96	journal	June 2012
Stacking effects on the electronic and optical properties of bilayer transition metal dichalcogenides ${MoS}_{2}$ , ${MoSe}_{2}$ , ${WS}_{2}$ , and ${WSe}_{2}$ He, Jiangang; Hummer, Kerstin; Franchini, Cesare Physical Review B, Vol. 89, Issue 7 https://doi.org/10.1103/PhysRevB.89.075409	journal	February 2014
From Bulk to Monolayer MoS2: Evolution of Raman Scattering Li, Hong; Zhang, Qing; Yap, Chin Chong Ray Advanced Functional Materials, Vol. 22, Issue 7 https://doi.org/10.1002/adfm.201102111	journal	January 2012
Electrical tuning of valley magnetic moment through symmetry control in bilayer MoS2 Wu, Sanfeng; Ross, Jason S.; Liu, Gui-Bin Nature Physics, Vol. 9, Issue 3 https://doi.org/10.1038/nphys2524	journal	January 2013
Optical signature of symmetry variations and spin-valley coupling in atomically thin tungsten dichalcogenides Zeng, Hualing; Liu, Gui-Bin; Dai, Junfeng Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep01608	journal	April 2013
Magnetoelectric effects and valley-controlled spin quantum gates in transition metal dichalcogenide bilayers Gong, Zhirui; Liu, Gui-Bin; Yu, Hongyi Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3053	journal	June 2013
Spin and pseudospins in layered transition metal dichalcogenides Xu, Xiaodong; Yao, Wang; Xiao, Di Nature Physics, Vol. 10, Issue 5 https://doi.org/10.1038/nphys2942	journal	April 2014
Vapour phase growth and grain boundary structure of molybdenum disulphide atomic layers Najmaei, Sina; Liu, Zheng; Zhou, Wu Nature Materials, Vol. 12, Issue 8, p. 754-759 https://doi.org/10.1038/nmat3673	journal	June 2013
Valley and band structure engineering of folded MoS2 bilayers Jiang, Tao; Liu, Hengrui; Huang, Di Nature Nanotechnology, Vol. 9, Issue 10 https://doi.org/10.1038/nnano.2014.176	journal	August 2014
Tailoring the Electronic Structure in Bilayer Molybdenum Disulfide via Interlayer Twist van der Zande, Arend M.; Kunstmann, Jens; Chernikov, Alexey Nano Letters, Vol. 14, Issue 7 https://doi.org/10.1021/nl501077m	journal	June 2014
Probing the Interlayer Coupling of Twisted Bilayer MoS ₂ Using Photoluminescence Spectroscopy Huang, Shengxi; Ling, Xi; Liang, Liangbo Nano Letters, Vol. 14, Issue 10 https://doi.org/10.1021/nl5014597	journal	September 2014
Evolution of interlayer coupling in twisted molybdenum disulfide bilayers Liu, Kaihui; Zhang, Liming; Cao, Ting Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5966	journal	September 2014
Giant Optical Response from Graphene–Plasmonic System Wang, Pu; Zhang, Wei; Liang, Owen ACS Nano, Vol. 6, Issue 7 https://doi.org/10.1021/nn301694m	journal	June 2012
Ultra-Sensitive Graphene-Plasmonic Hybrid Platform for Label-Free Detection Wang, Pu; Liang, Owen; Zhang, Wei Advanced Materials, Vol. 25, Issue 35 https://doi.org/10.1002/adma.201300635	journal	August 2013
Vapor Phase Growth and Imaging Stacking Order of Bilayer Molybdenum Disulfide Yang, Shengxue; Kang, Jun; Yue, Qu The Journal of Physical Chemistry C, Vol. 118, Issue 17 https://doi.org/10.1021/jp500050r	journal	April 2014
Atomically localized plasmon enhancement in monolayer graphene Zhou, Wu; Lee, Jaekwang; Nanda, Jagjit Nature Nanotechnology, Vol. 7, Issue 3 https://doi.org/10.1038/nnano.2011.252	journal	January 2012
Anomalous Lattice Vibrations of Single- and Few-Layer MoS ₂ Lee, Changgu; Yan, Hugen; Brus, Louis E. ACS Nano, Vol. 4, Issue 5 https://doi.org/10.1021/nn1003937	journal	March 2010
Layer-dependent resonant Raman scattering of a few layer MoS ₂ : Raman scattering of a few layer MoS Chakraborty, Biswanath; Matte, H. S. S. Ramakrishna; Sood, A. K. Journal of Raman Spectroscopy, Vol. 44, Issue 1 https://doi.org/10.1002/jrs.4147	journal	September 2012
Dispersive Raman Mode of Layered Compound 2H-MoS ₂ under the Resonant Condition Sekine, Tomoyuki; Uchinokura, Kunimitsu; Nakashizu, Tsuneo Journal of the Physical Society of Japan, Vol. 53, Issue 2 https://doi.org/10.1143/JPSJ.53.811	journal	February 1984
Resonant Raman scattering at exciton states tuned by pressure and temperature in $2 H {-MoS}_{2}$ Livneh, Tsachi; Sterer, Eran Physical Review B, Vol. 81, Issue 19 https://doi.org/10.1103/PhysRevB.81.195209	journal	May 2010
Multiphonon resonant Raman scattering in MoS ₂ Gołasa, K.; Grzeszczyk, M.; Leszczyński, P. Applied Physics Letters, Vol. 104, Issue 9 https://doi.org/10.1063/1.4867502	journal	March 2014
An intelligent background-correction algorithm for highly fluorescent samples in Raman spectroscopy Zhang, Zhi-Min; Chen, Shan; Liang, Yi-Zeng Journal of Raman Spectroscopy, Vol. 41, Issue 6 https://doi.org/10.1002/jrs.2500	journal	October 2009
Tightly bound trions in monolayer MoS2 Mak, Kin Fai; He, Keliang; Lee, Changgu Nature Materials, Vol. 12, Issue 3 https://doi.org/10.1038/nmat3505	journal	December 2012
Anisotropic mean-square displacements (MSD) in single-crystals of 2 H - and 3 R -MoS ₂ Schönfeld, B.; Huang, J. J.; Moss, S. C. Acta Crystallographica Section B Structural Science, Vol. 39, Issue 4 https://doi.org/10.1107/S0108768183002645	journal	August 1983
Binding Energies in Atomic Negative Ions: III Andersen, T.; Haugen, H. K.; Hotop, H. Journal of Physical and Chemical Reference Data, Vol. 28, Issue 6 https://doi.org/10.1063/1.556047	journal	November 1999
Band-gap transition induced by interlayer van der Waals interaction in MoS $_{2}$ Han, S. W.; Kwon, Hyuksang; Kim, Seong Keun Physical Review B, Vol. 84, Issue 4 https://doi.org/10.1103/PhysRevB.84.045409	journal	July 2011
Controlled charge trapping by molybdenum disulphide and graphene in ultrathin heterostructured memory devices Sup Choi, Min; Lee, Gwan-Hyoung; Yu, Young-Jun Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2652	journal	March 2013
High Performance Multilayer MoS₂Transistors with Scandium Contacts Das, Saptarshi; Chen, Hong-Yan; Penumatcha, Ashish Verma Nano Letters, Vol. 13, Issue 1, p. 100-105 https://doi.org/10.1021/nl303583v	journal	December 2012
Electron-hole transport and photovoltaic effect in gated MoS2 Schottky junctions Fontana, Marcio; Deppe, Tristan; Boyd, Anthony K. Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep01634	journal	April 2013
Tuning Electronic Structure of Bilayer MoS ₂ by Vertical Electric Field: A First-Principles Investigation Liu, Qihang; Li, Linze; Li, Yafei The Journal of Physical Chemistry C, Vol. 116, Issue 40 https://doi.org/10.1021/jp307124d	journal	September 2012
Tunable band gaps in bilayer transition-metal dichalcogenides Ramasubramaniam, Ashwin; Naveh, Doron; Towe, Elias Physical Review B, Vol. 84, Issue 20 https://doi.org/10.1103/PhysRevB.84.205325	journal	November 2011
Experimental Demonstration of Continuous Electronic Structure Tuning via Strain in Atomically Thin MoS ₂ He, Keliang; Poole, Charles; Mak, Kin Fai Nano Letters, Vol. 13, Issue 6 https://doi.org/10.1021/nl4013166	journal	May 2013
Bandgap Engineering of Strained Monolayer and Bilayer MoS₂ Conley, Hiram J.; Wang, Bin; Ziegler, Jed I. Nano Letters, Vol. 13, Issue 8, p. 3626-3630 https://doi.org/10.1021/nl4014748	journal	July 2013
New Route for Stabilization of 1T-WS ₂ and MoS ₂ Phases Enyashin, Andrey N.; Yadgarov, Lena; Houben, Lothar The Journal of Physical Chemistry C, Vol. 115, Issue 50 https://doi.org/10.1021/jp2076325	journal	November 2011

Cited By (23)

Atomic-Scale Structural Modification of 2D Materials Xiao, Yao; Zhou, Mengyue; Zeng, Mengqi Advanced Science, Vol. 6, Issue 5 https://doi.org/10.1002/advs.201801501	journal	January 2019
Stacking-controllable interlayer coupling and symmetric configuration of multilayered MoS2 Shinde, Sachin M.; Dhakal, Krishna P.; Chen, Xiang NPG Asia Materials, Vol. 10, Issue 2 https://doi.org/10.1038/am.2017.226	journal	February 2018
Controllable growth and electrostatic properties of Bernal stacked bilayer MoS ₂ Hao, Song; Yang, Bingchu; Gao, Yongli Journal of Applied Physics, Vol. 120, Issue 12 https://doi.org/10.1063/1.4963345	journal	September 2016
Thermally driven homonuclear-stacking phase of MoS ₂ through desulfurization Hwang, Young Hun; Yun, Won Seok; Cha, Gi-Beom Nanoscale, Vol. 11, Issue 23 https://doi.org/10.1039/c9nr01369e	journal	January 2019
Interface Characterization and Control of 2D Materials and Heterostructures Liu, Xiaolong; Hersam, Mark C. Advanced Materials, Vol. 30, Issue 39 https://doi.org/10.1002/adma.201801586	journal	July 2018
Modeling the vertical growth of van der Waals stacked 2D materials using the diffuse domain method Guo, Zhenlin; Price, Christopher; Shenoy, Vivek B. Modelling and Simulation in Materials Science and Engineering, Vol. 28, Issue 2 https://doi.org/10.1088/1361-651x/ab5e9a	journal	January 2020
Hydrothermal synthesis of two-dimensional MoS2 and its applications Zhang, Xiaoyan; Ma, Guoqing; Wang, Jun Tungsten, Vol. 1, Issue 1 https://doi.org/10.1007/s42864-019-00014-9	journal	March 2019
A Review on Applications of Two-Dimensional Materials in Surface-Enhanced Raman Spectroscopy Xia, Ming International Journal of Spectroscopy, Vol. 2018 https://doi.org/10.1155/2018/4861472	journal	January 2018
2D Materials-Coated Plasmonic Structures for SERS Applications Xia, Ming Coatings, Vol. 8, Issue 4 https://doi.org/10.3390/coatings8040137	journal	April 2018
Growth of 2H stacked WSe ₂ bilayers on sapphire Han, Ali; Aljarb, Areej; Liu, Sheng Nanoscale Horizons, Vol. 4, Issue 6 https://doi.org/10.1039/c9nh00260j	journal	January 2019
Origin of Structural Transformation in Mono- and Bi-Layered Molybdenum Disulfide Sun, Xiaoli; Wang, Zhiguo; Li, Zhijie Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep26666	journal	May 2016
Distinctive optoelectronic properties of nanostructured ${MoS}_{2}$ bilayers Mlinar, Vladan Physical Review B, Vol. 100, Issue 8 https://doi.org/10.1103/physrevb.100.085411	journal	August 2019
In situ atomic level studies of thermally controlled interlayer stacking shifts in 2D transition metal dichalcogenide bilayers Zhou, Si; Chen, Jun; Warner, Jamie H. Journal of Materials Research, Vol. 35, Issue 11 https://doi.org/10.1557/jmr.2019.399	journal	January 2020
Restoring the intrinsic optical properties of CVD-grown MoS ₂ monolayers and their heterostructures Kojima, Kana; Lim, Hong En; Liu, Zheng Nanoscale, Vol. 11, Issue 27 https://doi.org/10.1039/c9nr01481k	journal	January 2019
Controlled Vapor Growth and Nonlinear Optical Applications of Large-Area 3R Phase WS ₂ and WSe ₂ Atomic Layers Zeng, Zhouxiaosong; Sun, Xingxia; Zhang, Danliang Advanced Functional Materials, Vol. 29, Issue 11 https://doi.org/10.1002/adfm.201806874	journal	January 2019
Thickness and Stacking Sequence Determination of Exfoliated Dichalcogenides (1T-TaS ₂ , 2H-MoS ₂ ) Using Scanning Transmission Electron Microscopy Hovden, Robert; Liu, Pengzi; Schnitzer, Noah Microscopy and Microanalysis, Vol. 24, Issue 4 https://doi.org/10.1017/s1431927618012436	journal	August 2018
Analysis of photoluminescence behavior of high-quality single-layer MoS2 Xu, Lu; Zhao, Liyun; Wang, Yunsong Nano Research, Vol. 12, Issue 7 https://doi.org/10.1007/s12274-019-2401-0	journal	April 2019
High-Mobility Multilayered MoS ₂ Flakes with Low Contact Resistance Grown by Chemical Vapor Deposition Zheng, Jingying; Yan, Xingxu; Lu, Zhixing Advanced Materials, Vol. 29, Issue 13 https://doi.org/10.1002/adma.201604540	journal	February 2017
High degree of circular polarization in WS2 spiral nanostructures induced by broken symmetry Barman, Prahalad Kanti; Sarma, Prasad V.; Shaijumon, M. M. Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-39246-7	journal	February 2019
Carrier dynamics and spin–valley–layer effects in bilayer transition metal dichalcogenides Ciccarino, Christopher J.; Chakraborty, Chitraleema; Englund, Dirk R. Faraday Discussions, Vol. 214 https://doi.org/10.1039/c8fd00159f	journal	January 2019
Transition metal dichalcogenides bilayer single crystals by reverse-flow chemical vapor epitaxy Zhang, Xiumei; Nan, Haiyan; Xiao, Shaoqing Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08468-8	journal	February 2019
Mapping of Low-Frequency Raman Modes in CVD-Grown Transition Metal Dichalcogenides: Layer Number, Stacking Orientation and Resonant Effects O’Brien, Maria; McEvoy, Niall; Hanlon, Damien Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep19476	journal	January 2016
Davydov splitting and polytypism in few-layer MoS ₂ Na, Woongki; Kim, Kangwon; Lee, Jae-Ung 2D Materials, Vol. 6, Issue 1 https://doi.org/10.1088/2053-1583/aae61c	journal	October 2018

Similar Records

Stacking-dependent interlayer coupling in trilayer MoS₂ with broken inversion symmetry

Journal Article · Fri Nov 13 00:00:00 EST 2015 · Nano Letters · OSTI ID:1252727

Yan, Jiaxu; Wang, Xingli; Tay, Beng Kang; +7 more

Electric-field-induced plasmon in AA-stacked bilayer graphene

Journal Article · Sun Dec 15 00:00:00 EST 2013 · Annals of Physics (New York) · OSTI ID:1252727

Twisted MoSe₂ bilayers with variable local stacking and interlayer coupling revealed by low-frequency Raman spectroscopy

Journal Article · Thu Jan 14 00:00:00 EST 2016 · ACS Nano · OSTI ID:1252727

Puretzky, Alexander A.; Liang, Liangbo; Li, Xufan; +4 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
molybdenum disulfide
bilayer stacking
Au nanopyramids
photoluminescence
resonance Raman
36 MATERIALS SCIENCE

Title: Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2

Citation Formats

References (41)

Cited By (23)

Similar Records

Related Subjects

Title: Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS₂